KaydedilenlerDerginizi ekleyin

Dergiler / Turkish Journal of Chemistry / 2002 / Cilt: 26 - Sayı: 6

Poly (methacrylic) acid and $gamma$ -methacryloxypropyltrimethoxy silane/clay nanocomposites prepared by in-situ polymerization

Yunus ÖNAL
Ahmet GÜLTEK
M. Galip İÇDUYGU
Turgay SEÇKİN
Sayfa
925–937
Yayın Tarihi
2022-11-04
DOI
—
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The nanocomposites were quantified by both X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA), and differential thermal analysis (DTA).

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:Poly(methacrylic acid) and poly(acrylic acid) nanocomposites were prepared by in-situ polymerization of $gamma$-methacryloxypropyltrimethoxysilane (A174)/clay nanocomposites in which the macromonomer was generated by grafting A-174 onto activated clay samples via hydroxyl groups or via intercalation.
📊
Temel Bulgular & Veri:In- situ polymerization was carried out in the presence of an initiator.
💡
Sonuç & Katkı:The nanocomposites were quantified by both X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA), and differential thermal analysis (DTA).
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

Poly(methacrylic acid) and poly(acrylic acid) nanocomposites were prepared by in-situ polymerization of $gamma$-methacryloxypropyltrimethoxysilane (A174)/clay nanocomposites in which the macromonomer was generated by grafting A-174 onto activated clay samples via hydroxyl groups or via intercalation. In- situ polymerization was carried out in the presence of an initiator. It was found that the structural affinity between the methacrylic or acrylic acid monomers and the amount of clay played an important role in the hybrid structure. The nanocomposites were quantified by both X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA), and differential thermal analysis (DTA).

🔖

Bu Makaleye Atıf Yap

ÖNAL, Y., GÜLTEK, A., İÇDUYGU, M. G., SEÇKİN, T. (2022). Poly (methacrylic) acid and $gamma$ -methacryloxypropyltrimethoxy silane/clay nanocomposites prepared by in-situ polymerization. Turkish Journal of Chemistry, Cilt: 26 - Sayı: 6, 925–937. https://ajindex.com/articles/602340

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (35)

  1. A. Usuki, M. Kawasumi, Y. Kojima, A. Okada, T. Kurauchi et al., J. Mater. Res. 8, 1174 (1993)
  2. A. Usuki, Y. Kojima, M. Kawasumi, A. Okada, Y. Fukushime, T. Kurauchi, J. Mater. Res., 8, 1180 (1993)
  3. Y. Kojima, A. Usuki, M. Kawasumi, A. Okada, Y. Fukushima, T. Karauchi, J. Mater. Res., 8, 1185, (1993)
  4. K.G. Fournaris, M.A. Karakassides, D. Petridis, Chem. Mater., 11, 2372 (1999)
  5. B.K. Theng, Formation and Properties of Clay-Polymer Complexes, Elsevier, Amsterdam, 1979
  6. T. Lan, T. Pinnavaia, J. Mater. Chem., 6, 2216 (1994)
  7. R. Vaia, H. Ishii, E.D. Giannelis, Chem. Mater., 51, 115 (1992)
  8. E.D. Giannelis, Adv. Mater., 8, 29 (1996)
  9. Z. Wang, T. Pinnavaia, Chem. Mater., 8, 2200 (1997)
  10. Z. Wang, T. Pinnavaia, Chem. Mater. 101820 (1998)
  11. P. Messersmith, E.P. Giannelis, Chem. Mater., 6, 1719 (1994)
  12. M. Alexandre, P. Dubois, Mater. Sci.Eng., R28, 1-63 (2000)
  13. A. Akelah, A. Moet, J. Mater. Sci., 31, 31589 (1996)
  14. J. Zhu, C.A. Wilkie, Poly. Intern., 48, 1158 (2000)
  15. X. Fu, S. Qutubuddin, Mater. Lett., 42, 12 (2000)
  16. M. Noh, D.C. Lee, Poly.Bull., 42, 619 (1999)
  17. D. Lee, L.W. Jang, J. Appl. Poly. Sci., 61, 117 (1996)
  18. M. Okamato, S. Moritaa, H. Tagushi, Y.H. Kim, T. Kataka, et al., Polymer, 41, 3887 (2000)
  19. B. Hu, R.M. Ottenbrite, J.A. Siddiqui, ACS Poly. Pre., 41(1), 266 (2000)
  20. A.K. Banthia, A.P. Gupta, ACS Poly. Pre., 41(1), 277 (2000)
  21. F. Dietsche, Y. Thomann, R. Thomann, T. M¨ulhaupt, J.App.Poly.Sci., 75, 396 (2000)
  22. M. Whan, D.C. Lee, Poly. Bull., 42, 619 (1999)
  23. M.W. Meimer, H. Chen, E.P. Giannelis, D.J. Sogah, J. Am. Chem. Soc., 121, 1615 (1999)
  24. M. Zbik, R.C. Smart, Clays and Clay Min., 46(2), 153 (1998)
  25. R. Forst, J. Kristof, G.N. Paroz, J.T. Klopprogge, Phys. Chem. Min., 26, 257 (1999)
  26. K. Sonobe, K. Kikuta, K. Takagi, Chem. Mater., 11, 1089 (1999)
  27. M.Ogawa, A.Ishikiva, J. Mater. Chem., 8, 463 (1998)
  28. H. Usami, T. Nakamura, T. Makino, J. Chem. Soc. Faraday Trans., 94, 83(1998)
  29. Y.S. Han, H. Matsumoto S. Yamanaka, Chem. Mater., 9, 2013 (1997)
  30. A. Hild, J.M. Sequaris, H.D. Narres, M. Schuwuger, Coll. and Surf. Sci., 123, 515 (1997)
  31. X. Huang, W. Brittain, J. Poly.Pre. (Am. Chem. Soc. Div. Poly. Chem.), 41, 521 (2000)
  32. D. Eberl, R. Nuesch, V. Sucha, S. Tsipurks, Clays and Clay Min., 46(1), 89 (1998)
  33. I. Atobe, T. Takata, T. Endo, Macromolecules, 24, 5046 (1991)
  34. L. Michot, T.J. Pinnavaia, Clays and Clay Min., 39(6), 634 (1991)
  35. S.A. B