Dergiler / Turkish Journal of Chemistry / 2021 / Cilt: 45 - Sayı: 6

Reductant free green synthesis of magnetically recyclable $MnFe_2O_4@SiO_2-Ag$ coreshell nanocatalyst for the direct reduction of organic dye pollutants

Sayfa
1968–1979
Yayın Tarihi
2022-11-03
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Overall, this work demonstrates a simple and practical green synthetic route for the preparation of magnetic recyclable core-shell nanocatalyst that can be a good candidate for the treatment of organic contaminants in wastewater adhering to green chemistry principles for the environmental pollution concerns.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:The present paper describes in situ green immobilization of silver nanoparticles on $MnFe_2O_4@SiO_2$ nanospheres using Epilobium parviflorum (EP) without using any other toxic chemicals and reducing or stabilizing agents.
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Temel Bulgular & Veri:The morphology, composition, and magnetic properties of the resulting $MnFe_2O_4@SiO_2-Ag$ core-shell nanocatalyst were characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR).
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Sonuç & Katkı:Overall, this work demonstrates a simple and practical green synthetic route for the preparation of magnetic recyclable core-shell nanocatalyst that can be a good candidate for the treatment of organic contaminants in wastewater adhering to green chemistry principles for the environmental pollution concerns.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

The present paper describes in situ green immobilization of silver nanoparticles on $MnFe_2O_4@SiO_2$ nanospheres using Epilobium parviflorum (EP) without using any other toxic chemicals and reducing or stabilizing agents. The morphology, composition, and magnetic properties of the resulting $MnFe_2O_4@SiO_2-Ag$ core-shell nanocatalyst were characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). The catalytic performance of the synthesized $MnFe_2O_4@SiO_2-Ag$ was employed on the organic pollutants dyes such as rhodamine B (RhB) and methylene blue (MB). The results revealed significant reduction performances for the MB (116.28 s–1 g–1) and RhB (27.12 s–1 g–1) over the existing literature. Furthermore, the $MnFe_2O_4@SiO_2-Ag$ exhibited high stability for the completion of the reduction of RhB between the reaction times of 13.1 (first) and 19.8 min (final) with the 100% decolorization efficiency even after several cycles with an excellent magnetic separation. Overall, this work demonstrates a simple and practical green synthetic route for the preparation of magnetic recyclable core-shell nanocatalyst that can be a good candidate for the treatment of organic contaminants in wastewater adhering to green chemistry principles for the environmental pollution concerns.

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Bu Makaleye Atıf Yap

ELMACI, G., ERTÜRK, A. S., GÜRBÜZ, M. U. (2022). Reductant free green synthesis of magnetically recyclable $MnFe_2O_4@SiO_2-Ag$ coreshell nanocatalyst for the direct reduction of organic dye pollutants. Turkish Journal of Chemistry, Cilt: 45 - Sayı: 6, 1968–1979. https://ajindex.com/articles/602263

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Kaynakça (12)

  1. Mani S, Chowdhary P, Bharagava RN. Textile wastewater dyes: Toxicity profile and treatment approaches. Emerging and eco-friendly approaches for waste management 2018
  2. doi: 10.1007/978-981-10-8669-4_11 2. Mondal P, Baksi S, Bose D. Study of Environmental Issues in Textile Industries and Recent Wastewater Treatment Technology. World Scientific News 2017
  3. Crini G. Studies on adsorption of dyes on beta-cyclodextrin polymer. Bioresource Technology 2003
  4. 90 (2): 193–198. doi: 10.1016/S0960-8524(03)00111-1 4. Wijetunga S, Li X-F, Jian C. Effect of organic load on decolourization of textile wastewater containing acid dyes in upflow anaerobic sludge blanket reactor. Journal of Hazardous Materials 2010
  5. 177 (1-3): 792–798. doi: 10.1016/j.jhazmat.2009.12.103 5. Kavimani T, Senthilkumar PL. Anaerobic Treatment of Dye Wastewater using Upflow Anaerobic Sludge Blanket Reactor. International Journal of Innovative Technology and Exploring Engineering 2019
  6. 8 (12): 3178–3181. doi: 10.35940/ijitee.L3044.1081219 6. Ertürk AS. PAMAM dendrimer-enhanced removal of cobalt ions based on multiple-response optimization using response surface methodology. Journal of the Iranian Chemical Society 2018
  7. 15 (8): 1685–1698. doi: 10.1007/s13738-018-1366-3 7. Ambashta RD, Sillanpää M. Water purification using magnetic assistance: A review. Journal of Hazardous Materials 2010
  8. 180 (1-3): 38– 49. doi: 10.1016/j.jhazmat.2010.04.105 8. Chan SHS, Yeong Wu T, Juan JC, Teh CY. Recent developments of metal oxide semiconductors as photocatalysts in advanced oxidation processes (AOPs) for treatment of dye waste-water. Journal of Chemical Technology & Biotechnology 2011
  9. 86 (9): 1130–1158. doi: 10.1002/jctb.2636 9. Burakov AE, Galunin EV, Burakova IV, Kucherova AE, Agarwal S et al. Adsorption of heavy metals on conventional and nanostructured materials for wastewater treatment purposes: A review. Ecotoxicology and Environmental Safety 2018
  10. 702–712. doi: 10.1016/j.ecoenv.2017.11.034 10. Jana NR, Wang ZL, Pal T. Redox Catalytic Properties of Palladium Nanoparticles: Surfactant and Electron Donor−Acceptor Effects. Langmuir 2000
  11. 16 (6): 2457–2463. doi: 10.1021/la990507r 11. Jana NR, Pal T. Redox Catalytic Property of Still-Growing and Final Palladium Particles: A Comparative Study. Langmuir 1999
  12. 15 (10): 3458–3463. doi: 10.1021/la981512i 12. Shimizu K, Sawabe K, Satsuma A. Unique catalytic features of Ag nanoclusters for selective NOx reduction and green chemical reactio