Dergiler / Turkish Journal of Chemistry / 2021 / Cilt: 45 - Sayı: 3

Scalable activated carbon/graphene based supercapacitors with improved capacitance retention at high current densities

Sayfa
927–941
Yayın Tarihi
2022-11-01
DOI
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Yapay Zeka Hızlı Bakış & Çıkarımlar

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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The pouch cell had a gravimetric capacitance of 85 F/g and exhibited as good performance as the coin cell in the organic electrolyte.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Scalable, highly stable supercapacitor electrodes were developed from the mixture of a tea factory waste based activated carbon (AC) and a low-cost electrochemical exfoliated graphene (EEG).
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Temel Bulgular & Veri:The AC sample was prepared by chemical method and exposed to a further heat treatment to enhance electrochemical performance.
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Sonuç & Katkı:The pouch cell had a gravimetric capacitance of 85 F/g and exhibited as good performance as the coin cell in the organic electrolyte.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

Scalable, highly stable supercapacitor electrodes were developed from the mixture of a tea factory waste based activated carbon (AC) and a low-cost electrochemical exfoliated graphene (EEG). The hybrid electrodes showed notably enhanced stability at high current densities. The AC sample was prepared by chemical method and exposed to a further heat treatment to enhance electrochemical performance. Graphene used in the preparation of hybrid electrodes was obtained by direct electrochemical exfoliation of graphite in an aqueous solution. Detailed structural characterization of AC, EEG, and hybrid material was performed. The original electrochemical performances of AC and EEG were examined in button size cells using an aqueous electrolyte. The hybrid materials were prepared by mixing AC and EEG at different mass percentage ratios, and tested as supercapacitor electrodes under the same conditions. Capacitance stability of the electrodes developed from AC:EEG (70:30) at high currents increased by about 45% compared to the original AC. The highest gravimetric capacitance (110 F/g) was achieved by this hybrid electrode. The hybrid electrode was scaled up to the pouch size and tested using an organic electrolyte. The organic electrolyte was preferred for scaling up due to its wider voltage ranges. The pouch cell had a gravimetric capacitance of 85 F/g and exhibited as good performance as the coin cell in the organic electrolyte.

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Bu Makaleye Atıf Yap

İNAL, İ. I. G. (2022). Scalable activated carbon/graphene based supercapacitors with improved capacitance retention at high current densities. Turkish Journal of Chemistry, Cilt: 45 - Sayı: 3, 927–941. https://ajindex.com/articles/602261

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Kaynakça (13)

  1. Kötz R, Carlen M. Principles and applications of electrochemical capacitors. Electrochimica Acta 2000
  2. 45 (15-16): 2483-2498. doi: 10.1016/ s0013-4686(00)00354-6 2. Frackowiak E, Béguin F. Carbon materials for the electrochemical storage of energy in capacitors. Carbon 2001
  3. 39 (6): 937-950. doi: 10.1016/ s0008-6223(00)00183-4 3. Pandolfo A, Hollenkamp A. Carbon properties and their role in supercapacitors. Journal of Power Sources 2006
  4. 157 (1): 11-27. doi: 10.1016/j. jpowsour.2006.02.065 4. Béguin F, Frackowiak E. Carbons For Electrochemical Energy Storage And Conversion Systems. Boca Raton, Florida: Taylor & Francis, 2010. 5. Wei L, Yushin G. Nanostructured activated carbons from natural precursors for electrical double layer capacitors. Nano Energy 2012
  5. 1 (4): 552-565. doi: 10.1016/j.nanoen.2012.05.002 6. Zhang L, Zhao X. Carbon-based materials as supercapacitor electrodes. Chemical Society Reviews 2009
  6. 38 (9): 2520-2531. doi: 10.1039/ b813846j 7. Burke A. Ultracapacitors: why, how, and where is the technology. Journal of Power Sources 2000
  7. 91 (1): 37-50. doi: 10.1016/s0378- 7753(00)00485-7 8. Chen H, Wang F, Tong S, Guo S, Pan X. Porous carbon with tailored pore size for electric double layer capacitors application. Applied Surface Sciences 2012
  8. 258 (16): 6097-6102. doi: 10.1016/j.apsusc.2012.03.009 9. Li Y, Shang T, Gao J, Jin X. Nitrogen-doped activated carbon/graphene composites as high-performance supercapacitor electrodes. RSC Advances 2017
  9. 7 (31): 19098-19105. doi: 10.1039/c7ra00132k 10. Hayashi J, Kazehaya A, Muroyama K, Watkinson A. Preparation of activated carbon from lignin by chemical activation. Carbon 2000
  10. 38 (13): 1873-1878. doi: 10.1016/s0008-6223(00)00027-0 11. Linares-Solano A, Martın-Gullon I, Salinas-Martınez de Lecea C, Serrano-Talavera B. Activated carbons from bituminous coal: effect of mineral matter content. Fuel 2000
  11. 79 (6): 635-643. doi: 10.1016/s0016-2361(99)00184-2 12. Hayashi J, Uchibayashi M, Horikawa T, Muroyama K, Gomes V. Synthesizing activated carbons from resins by chemical activation with $K_2CO_3$. Carbon 2002
  12. 40 (15): 2747-2752. doi: 10.1016/s0008-6223(02)00151-3 13. Yagmur E, Ozmak M, Aktas Z. A novel method for production of activated carbon from waste tea by chemical activation with microwave energy. Fuel 2008
  13. 87 (15-16): 3278-3285. doi: 10.1016/j.fuel.2008.05.005 14. Elmouwahidi A, Zapata-Benabithe Z, Carrasco-Marín F, Moreno-Castilla C. Activated carbons from KOH-activation of argan (Argania spin