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Dergiler / Turkish Journal of Chemistry / 2011 / Cilt: 35 - Sayı: 1

Reaction of cycloheptatriene derivatives with 1,3-diketones in the presence of $Mn(OAc)_3$

Mustafa ZENGİN
Metin BALCI
Hayriye GENC
Mahir Burak SÜDEMEN
Sayfa
1–11
Yayın Tarihi
2022-11-05
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The formation mechanism of the products as well as the role of the substituent attached to cycloheptatriene is discussed.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:The reactions of some 1,3-dicarbonyl compounds with cycloheptatriene derivatives in the presence of $Mn(OAc)_3$ were examined.
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Temel Bulgular & Veri:Cycloheptatriene forms mainly [2+3] and [6+3] dihydrofuran addition products derived from cycloheptatriene.
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Sonuç & Katkı:The formation mechanism of the products as well as the role of the substituent attached to cycloheptatriene is discussed.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

The reactions of some 1,3-dicarbonyl compounds with cycloheptatriene derivatives in the presence of $Mn(OAc)_3$ were examined. Cycloheptatriene forms mainly [2+3] and [6+3] dihydrofuran addition products derived from cycloheptatriene. However, the reaction of acetylacetone with cycloheptatriene substituted with an electron withdrawing group exclusively gave products derived from the norcaradiene structure. The formation mechanism of the products as well as the role of the substituent attached to cycloheptatriene is discussed.

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Bu Makaleye Atıf Yap

ZENGİN, M., BALCI, M., GENC, H., SÜDEMEN, M. B. (2022). Reaction of cycloheptatriene derivatives with 1,3-diketones in the presence of $Mn(OAc)_3$. Turkish Journal of Chemistry, Cilt: 35 - Sayı: 1, 1–11. https://ajindex.com/articles/602097

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