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Dergiler / Turkish Journal of Chemistry / 2018 / Cilt: 42 - Sayı: 1

Synthesis and some optical results of long chain substituted phthalocyanines

İdris SORAR
İbrahim ÖZÇEŞMECİ
Sayfa
21–28
Yayın Tarihi
2022-11-05
DOI
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Transmittance spectra of the phthalocyanines synthesized using different metal ions showed a variation of about 8% and 15% in transmittance spectra of the Q band region was obtained by mixing the two metal phthalocyanine (indium and zinc) solutions.

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Amaç & Hipotez:Four metallo (zinc, copper, vanadyl, and indium) phthalocyanine derivatives bearing four aliphatic (hexylthio) groups were prepared from corresponding phthalonitrile compounds.
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Temel Bulgular & Veri:The metallophthalocyanines were characterized with ultraviolet{visible spectroscopy (UV-Vis), proton nuclear magnetic resonance ( 1 H NMR), Fourier transform-infrared spectroscopy (FT-IR), and mass and elemental analyses techniques.
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Sonuç & Katkı:Transmittance spectra of the phthalocyanines synthesized using different metal ions showed a variation of about 8% and 15% in transmittance spectra of the Q band region was obtained by mixing the two metal phthalocyanine (indium and zinc) solutions.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

Four metallo (zinc, copper, vanadyl, and indium) phthalocyanine derivatives bearing four aliphatic (hexylthio) groups were prepared from corresponding phthalonitrile compounds. The metallophthalocyanines were characterized with ultraviolet{visible spectroscopy (UV-Vis), proton nuclear magnetic resonance ( 1 H NMR), Fourier transform-infrared spectroscopy (FT-IR), and mass and elemental analyses techniques. Aggregation properties of metallophthalocyanines in solution were studied in varied concentration ranges. Thin lms of metallophthalocyanines were obtained by spin coating technique. Optical measurements showed that transmittance values of metallophthalocyanine thin lms obviously changed with respect to the metal ion in the phthalocyanines. Transmittance spectra of the phthalocyanines synthesized using different metal ions showed a variation of about 8% and 15% in transmittance spectra of the Q band region was obtained by mixing the two metal phthalocyanine (indium and zinc) solutions.

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Bu Makaleye Atıf Yap

SORAR, İ., ÖZÇEŞMECİ, İ. (2022). Synthesis and some optical results of long chain substituted phthalocyanines. Turkish Journal of Chemistry, Cilt: 42 - Sayı: 1, 21–28. https://ajindex.com/articles/601760

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