Dergiler / Turkish Journal of Chemistry / 2020 / Cilt: 44 - Sayı: 5

A novel molecular imprinting polymer for the selective adsorption of D-arabinitol from spiked urine

Sayfa
1265–1277
Yayın Tarihi
2022-11-01
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The extraction efficiency of the MIPs against D-arabinitol was 88.98%.

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Amaç & Hipotez:In this research, molecular imprinting polymers (MIPs) for D-arabinitol were synthesized using a bulk polymerization method through a noncovalent approach.
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Temel Bulgular & Veri:Batch rebinding test results revealed that MIPsF3 with a molar ratio of the template: monomer and crosslinker ratio respectively (1: 4: 25) had the highest binding capacity at 1.56 $mgg ^{−1}$.
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Sonuç & Katkı:The extraction efficiency of the MIPs against D-arabinitol was 88.98%.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

In this research, molecular imprinting polymers (MIPs) for D-arabinitol were synthesized using a bulk polymerization method through a noncovalent approach. The MIPs were prepared by using D-arabinitol as a template, acrylamide as a functional monomer, ethylene glycol dimethacrylateas cross-linker, benzoyl peroxide as an initiator and dimethyl sulfoxideas a porogen. MIPS was synthesized in several formulas with a different molar ratio of template to functional monomers and cross-linker. Fourier-transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM) were used to characterize the MIPs produced. A batch rebinding assay was used to test the binding efficiency of each formula. Batch rebinding test results revealed that MIPsF3 with a molar ratio of the template: monomer and crosslinker ratio respectively (1: 4: 25) had the highest binding capacity at 1.56 $mgg ^{−1}$. The results of isotherm adsorption showed that the MIPs produced followed the Freundlich equation with an R-value of 0.97. The MIPs produced was also selective toward its isomeric compounds (i.e. L-arabinitol, adonitol, xylitol, and glucose). The extraction efficiency of the MIPs against D-arabinitol was 88.98%.

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Bu Makaleye Atıf Yap

SISWODIHARDJO, S., RETNANINGTYAS, Y., SUPRIYANTO, G., PUSPANINGSIH, N. N. T., IRAWAN, R. (2022). A novel molecular imprinting polymer for the selective adsorption of D-arabinitol from spiked urine. Turkish Journal of Chemistry, Cilt: 44 - Sayı: 5, 1265–1277. https://ajindex.com/articles/601606

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Kaynakça (12)

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