KaydedilenlerDerginizi ekleyin

Dergiler / Turkish Journal of Chemistry / 2020 / Cilt: 44 - Sayı: 1

Synthesis, optical, and structural properties of bisphenol-bridged aromatic cyclic phosphazenes

Burcu TOPALOĞLU AKSOY
Süreyya Oğuz TÜMAY
Bünyemin ÇOŞUT
Serkan YEŞİLOT
Ahmet ŞENOCAK
Sayfa
48–63
Yayın Tarihi
2022-11-04
DOI
—
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Furthermore, the excimer emissions through intramolecular interactions in solution and in solid statewere investigated by fluorescence spectroscopy and the theoretical calculations were performed in detail using DFT.

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:Phenoxy- and naphthoxy-substituted bisphenol-bridged cyclic phosphazenes were synthesized in 2 steps andtheir thermal, photophysical, and electrochemical properties were investigated.
📊
Temel Bulgular & Veri:The structures of the cyclic phosphazenecompounds were determined by ESI-MS mass spectrometry and 1 H, 13 C, and 31P NMR spectroscopies.
💡
Sonuç & Katkı:Furthermore, the excimer emissions through intramolecular interactions in solution and in solid statewere investigated by fluorescence spectroscopy and the theoretical calculations were performed in detail using DFT.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

Phenoxy- and naphthoxy-substituted bisphenol-bridged cyclic phosphazenes were synthesized in 2 steps andtheir thermal, photophysical, and electrochemical properties were investigated. The structures of the cyclic phosphazenecompounds were determined by ESI-MS mass spectrometry and 1 H, 13 C, and 31P NMR spectroscopies. The photophysical studies of phenoxy- and naphthoxy-substituted bridged cyclophosphazenes were investigated by means of absorptionand fluorescence spectroscopies in different solvents. Thermal and electrochemical properties of the target compoundswere also studied. Furthermore, the excimer emissions through intramolecular interactions in solution and in solid statewere investigated by fluorescence spectroscopy and the theoretical calculations were performed in detail using DFT.

🔖

Bu Makaleye Atıf Yap

AKSOY, B. T., TÜMAY, S. O., ÇOŞUT, B., YEŞİLOT, S., ŞENOCAK, A. (2022). Synthesis, optical, and structural properties of bisphenol-bridged aromatic cyclic phosphazenes. Turkish Journal of Chemistry, Cilt: 44 - Sayı: 1, 48–63. https://ajindex.com/articles/601599

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (1)

  1. Astruc D, Boisselier E, Ornelas C. Dendrimers designed for functions: from physical, photophysical, and supramolecular properties to applications in sensing, catalysis, molecular electronics, photonics, and nanomedicine. Chemical Reviews 2009; 110: 1857-1959. doi: 10.1021/cr900327d 2. Singler RE, Willingham RA, Noel C, Friedrich C, Bosio L et al. Thermotropic liquid crystalline poly (organophosphazene). Macromolecules 1991; 24: 510-516. doi: 10.1021/ma00002a026 3. Wu D, Sedgwick AC, Gunnlaugsson T, Akkaya EU, Yoon J et al. Fluorescent chemosensors: the past, present and future. Chemical Society Reviews 2017; 6: 7105-7123. doi: 10.1039/C7CS00240H 4. Giordano F, Roma G, Liberatore M, Miruzzo V, Conte V. Smart materials and concepts for photovoltaics: dye sensitized solar cells. Smart Materials for Energy, Communications and Security 2008; 97-126. doi: 10.1007/978-1- 4020-8796-7_8 5. Çoşut B, Yeşilot S. Synthesis, thermal and photophysical properties of naphthoxycyclotriphosphazenyl-substituted dendrimeric cyclic phosphazenes. Polyhedron 2012; 35: 101-107. doi: 10.1016/j.poly.2012.01.013 6. Zhang W, Zhao X, Gu W, Cheng T, Wang B et al. A novel naphthalene-based fluorescent probe for highly selective detection of cysteine with a large Stokes shift and its application in bioimaging. New Journal of Chemistry 2018; 42: 18109-18116. doi: 10.1039/C8NJ04425B 7. Badekar PS, Kumbhar AA. Anthracene-based fluorescence turn-on chemodosimeter for the recognition of persulfate anion. New Journal of Chemistry 2018; 42: 3917-3923. doi: 10.1039/C7NJ03425C 8. Wei AP, Blumenthal DK, Herron JN. Antibody-mediated fluorescence enhancement based on shifting the intramolecular dimer monomer equilibrium of fluorescent dyes. Analytical Chemistry 1994; 66: 1500-1506. doi: 10.1021/ac00081a023 9. Dunsing V, Luckner M, Zühlke B, Petazzi RA, Herrmann A et al. Optimal fluorescent protein tags for quantifying protein oligomerization in living cells. Scientific Reports 2018; 2018: 1-12. doi: 10.1038/s41598-018-28858-0 10. Smith RC, Tennyson AG, Lim MH, Lippard SJ. Conjugated polymer-based fluorescence turn-on sensor for nitric oxide. Organic Letters 2005; 7: 3573-3575. doi: 10.1021/ol0513903 11. Tuncel D. π -Conjugated nanostructured materials: preparation, properties and photonic applications. Nanoscale Advances 2019; 1: 19-33. doi: 10.1039/C8NA00108A 12. Allen CW. Regio- and stereochemical control in substitution reactions of cyclophosphazenes. Chemical Reviews 1991; 91: 119-135. doi: 10