Dergiler / Hittite Journal of Science and Engineering / 2021 / Cilt: 8 - Sayı: 4

Production and Characterization of Palm Oil Based Epoxy Biocomposite by RSM Design

Sayfa
287–297
Yayın Tarihi
2022-10-18
DOI
—
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The function with the highest R2 value has been determined according to the Coats Redfern method, and the deviation in Flynn Wall Ozawa and Kissinger model results was below 7%.

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:In this research, some physical and chemical properties of the biocomposite obtained from synthesized epoxy modified palm oil (MPO) and epoxy resin have been characterized.
📊
Temel Bulgular & Veri:The experimental study plan is made according to Response Surface Methodology (RSM) and biocomposites with different MPO rates are obtained.
💡
Sonuç & Katkı:The function with the highest R2 value has been determined according to the Coats Redfern method, and the deviation in Flynn Wall Ozawa and Kissinger model results was below 7%.
🔬Tür:Modelleme & Sayısal Simülasyon
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Biocomposite · modified palm oil · sulfonamide

Abstract

In this research, some physical and chemical properties of the biocomposite obtained from synthesized epoxy modified palm oil (MPO) and epoxy resin have been characterized. The experimental study plan is made according to Response Surface Methodology (RSM) and biocomposites with different MPO rates are obtained. The chemical bond structure of MPO and epoxy biocomposite has been evaluated with Fourier Transform Infrared Spektrofotometre (FTIR). The experimental, and RSM model results obtained, the density of the biocomposite rise as the MPO rate increases. It is determined that the Shore D hardness of the biocomposite is inversely proportional to the MPO rate by mass. The thermal conductivity coefficient and thermal stability also rise with the rate of MPO (wt.%) in the biocomposite. In the thermal degradation experiments of the obtained biocomposite, it is observed that the thermal stability of the composite goes up as the MPO rate rises. Activation energies are calculated using the Flynn Wall Ozawa, Kissinger, and Coats Redfern models. The activation energies calculated for the 9th, 2nd, and 13th experiments according to the Flynn Wall Ozawa method are approximately 139.65, 143.56, and 145.28 kJ/mol, respectively. The function with the highest R2 value has been determined according to the Coats Redfern method, and the deviation in Flynn Wall Ozawa and Kissinger model results was below 7%.

🔖

Bu Makaleye Atıf Yap

Şahal, H., Aydoğmuş, E. (2022). Production and Characterization of Palm Oil Based Epoxy Biocomposite by RSM Design. Hittite Journal of Science and Engineering, Cilt: 8 - Sayı: 4, 287–297. https://ajindex.com/articles/537903

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (11)

  1. Zamri MH, Akil HM, MohdIshak ZA. Pultruded Kenaf Fibre Reinforced Composites: Effect of Different Kenaf Fibre Yarn Tex. Procedia Chem. 19 (2016) 577–585
  2. Ilyas RA, Sapuan SM. The Preparation Methods and Processing of Natural Fibre Bio-polymer Composites. Curr. Org. Synth. 16 (2020) 1068–1070
  3. Ilyas RA, Sapuan SM. Biopolymers and Biocomposites: Chemistry and Technology. Curr. Anal. Chem. 16 (2020) 500–503
  4. Abral H, Atmajaya A, Mahardika M, Hafizulhaq F, Handayani DK, Sapuan SM, Ilyas RA. Effect of ultrasonication duration of polyvinyl alcohol (PVA) gel on characterizations of PVA film. J. Mater. Res. Technol. 9 (2020) 2477–2486
  5. Faruk O, Bledzki AK, Fink HP, Sain M. Biocomposites reinforced with natural fibers: 2000–2010. Prog. Polym. Sci. 37 (2012) 1552–1596
  6. Ilyas RA, Sapuan SM, Atikah, MSN, Asyraf MRM, Rafiqah SA, Aisyah HA, Nurazzi NM, Norrrahim MNF. Effect of hydrolysis time on the morphological, physical, chemical and thermal behavior of sugar palm nanocrystalline cellulose (Arenga pinnata (Wurmb.) Merr). Text. Res. J. 91(2021) 152–167
  7. Ilyas RA, Sapuan SM, Ibrahim R, Abral H, Ishak MR, Zainudin ES, Atikah MSN, Mohd Nurazzi N, Atiqah A, Ansari MNM, Syafri E, Asrofi M, Sari NH, Cumaidink R. Effect of sugar palm nanofibrillated cellulose concentrations on morphological, mechanical and physical properties of biodegradable films based on agro-waste sugar palm (Arenga pinnata (Wurmb.) Merr) starch. J. Mater. Res. Technol. 8 (2019) 4819–4830
  8. Ilyas RA, Sapuan SM, Ibrahim R, Abral H, Ishak MR, Zainudin ES, Asrofi M, Atikah MSN, Huzaifah MMR, Radzi AM, Azammi AMN, Shaharuzaman MA, Nurazzi NM, Syafri E, Sari NH, Norrrahim MRF, Jumaidinp R. Sugar palm (Arenga pinnata (Wurmb.) Merr) cellulosic fibre hierarchy: A comprehensive approach from macro to nanoscale. J. Mater. Res. Technol. 8 (2019) 2753–2766
  9. Aisyah HA, Paridah MT, Sapuan SM, Khalina A, Berkalp OB, Lee SH, Lee CH, Nurazzi NM, Ramli N, Wahab MS, Ilyas RA. Thermal Properties of Woven Kenaf/Carbon Fibre-Reinforced Epoxy Hybrid Composite Panels. Int. J. Polym. Sci. (2019) 1–8
  10. Jumaidin R, Saidi ZAS, Ilyas RA, Ahmad MN, Wahid MK, Yaakob MY, Maidin NA, Rahman MHA, Osman MH. Characteristics of Cogon Grass Fibre Reinforced Thermoplastic Cassava Starch Biocomposite: Water Absorption and Physical Properties. J. Adv. Res. Fluid Mech. Therm. Sci. 62 (2019) 43–52
  11. Alsubari S, Zuhri MYM, Sapuan SM, Ishak M.R, Ilyas R.A, Asyraf M.R.M. Potential of Natural Fiber Reinforced