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Dergiler / Turkish Journal of Chemistry / 2002 / Cilt: 26 - Sayı: 4

Bromination of 2,3-Dibromobenzobarrelene at Different Conditions: Highly Brominated Benzobicyclic Systems

Arif DAŞTAN
Sayfa
535–546
Yayın Tarihi
2002-04-01
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

All compounds were characterized properly, by NMR spectroscopy and chemical transformation.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:The electrophilic addition of bromine to 2,3-dibromobenzobarrelene at 10oC led to the formation of completely rearranged products in high yield.
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Temel Bulgular & Veri:Bromination of 2,3-dibromobenzobarrelene with molecular bromine in decalin at 150oC and with DBTCE in CCl4 at 77oC gave rearranged and non-rearranged products.
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Sonuç & Katkı:All compounds were characterized properly, by NMR spectroscopy and chemical transformation.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:benzobarrelene · high temperature bromination · Wagner-Meerwein rearrangement and poly-bromides.

Özet

The electrophilic addition of bromine to 2,3-dibromobenzobarrelene at 10oC led to the formation of completely rearranged products in high yield. Bromination of 2,3-dibromobenzobarrelene with molecular bromine in decalin at 150oC and with DBTCE in CCl4 at 77oC gave rearranged and non-rearranged products. The radical and ionic mechanism are discussed. All compounds were characterized properly, by NMR spectroscopy and chemical transformation.

Abstract

The electrophilic addition of bromine to 2,3-dibromobenzobarrelene at 10oC led to the formation of completely rearranged products in high yield. Bromination of 2,3-dibromobenzobarrelene with molecular bromine in decalin at 150oC and with DBTCE in CCl4 at 77oC gave rearranged and non-rearranged products. The radical and ionic mechanism are discussed. All compounds were characterized properly, by NMR spectroscopy and chemical transformation.

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Bu Makaleye Atıf Yap

DAŞTAN, A. (2002). Bromination of 2,3-Dibromobenzobarrelene at Different Conditions: Highly Brominated Benzobicyclic Systems. Turkish Journal of Chemistry, Cilt: 26 - Sayı: 4, 535–546. https://ajindex.com/articles/406213

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