Dergiler / Journal of International Environmental Application and Science / 2019 / Cilt: 14 - Sayı: 4

Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder

Sayfa
183–192
Yayın Tarihi
2019-12-30
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The negative ΔG◦ values revealed that this separation process was endothermic and natural.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:In this study, the usage of pine cone powder as an adsorbent for removing methylene blue from aqueous solution was investigated.
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Temel Bulgular & Veri:The results also determined that the pseudo second order kinetic model demonstrated higher correlation coefficients (R2) values compared to the pseudo first order and intra-particle diffusion models.
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Sonuç & Katkı:The negative ΔG◦ values revealed that this separation process was endothermic and natural.
🔬Tür:Modelleme & Sayısal Simülasyon
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:dye adsorption · isotherm · kinetic

Abstract

In this study, the usage of pine cone powder as an adsorbent for removing methylene blue from aqueous solution was investigated. Within this scope adsorption experiments were performed and the results showed that the Freundlich isotherm model was a more convenient option compared to the Langmuir and Temkin models. The results also determined that the pseudo second order kinetic model demonstrated higher correlation coefficients (R2) values compared to the pseudo first order and intra-particle diffusion models. Initial dye concentration was found to shift from 100 to 300 mg/l, while adsorption capacity onto the pine cone powder changed from 40.99 to 95.24 mg/g, 41.56 to 97.93 mg/g, and 43.51 to 101.41 mg/g for 298 K, 308 K and 318 K, respectively. The thermodynamic parameters for the instant free energy (ΔG), enthalpy (ΔH), and entropy (ΔS) of this separation process were found by referring to -1595,11 J/mol, 2465,83 J/mol and 12,77 J/mol, respectively. The negative ΔG◦ values revealed that this separation process was endothermic and natural.

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Bu Makaleye Atıf Yap

ALDEMİR, A., KUL, A. R., ELİK, H. (2019). Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder. Journal of International Environmental Application and Science, Cilt: 14 - Sayı: 4, 183–192. https://ajindex.com/articles/376632

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Kaynakça (14)

  1. Allafchian, A., Mousavi, Z. S., Hosseini, S. S., (2019) Application of cress seed musilage magnetic nanocomposites for removal of methylene blue dye from water, Int J Biol Macromol 136, 199-208.
  2. Bedin, K. C., Martins, A. C., Cazetta, A. L., Pezoti, O., Almeida, V. C., (2016) KOH-activated carbon prepared from sucrose spherical carbon: Adsorption equilibrium, kinetic and thermodynamic studies for methylene blue removal. Chemical Engineering Journal, 286, 476-484.
  3. Caparkaya, D., Cavas. L., (2008) Biosorption of methylene blue by a brown alga Cystoseirabarbatula Kutzing. Acta Chimia Slovakia, 55, 547-553.
  4. Cherifi, H., Fatiha, B., Salah, H., (2013) Kinetic studies on the adsorption of methylene blue onto vegetal fiber activated carbons. Applied Surface Science, 282, 52-59.
  5. Crini, G., (2006) Non-conventional low-cost adsorbents for dye removal: A review. Bioresource Technology, 97(9), 1061-1085.
  6. Dawood, S., Sen, T. K., (2012) Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: equilibrium, thermodynamic, kinetics, mechanism and process design. Water Res, 46(6), 1933-46.
  7. Debnath, S., Ballav, N., Maity, A., Pillay, K., (2017) Competitive adsorption of ternary dye mixture using pine cone powder modified with β-cyclodextrin. Journal of Molecular Liquids, 225, 679-688.
  8. Demirak, A., Keskin, F., Şahin, Y., Kalemci, V., (2015) Removal of ammonium from water by cone powder as biosorbent. Mugla Journal of Science and Technology, 1(1), 5-12.
  9. El-Sikaily, A., Khaled, A., El-Nemr, A., Abdelwahab, O., (2006) Removal of methylene blue from aqueous solution by marine green alga ulva lactuca. Chemical Ecology, 22(2), 149-157.
  10. Forgacs E., Cserhati T., Oros G., (2004) Removal of synthetic dyes from wastewaters: a review. Environment International, 30, 953-971.
  11. Fu, Y., Viraraghavan, T., (2000) Removal of a dye from an aqueous solution by the fungus Aspergillus niger. Water Quality Research Journal, 35(1), 95-111.
  12. Ghaedi, M., Hajjati. S., Mahmudi, Z., Tyagi, I., Agarwal, S., Maity, A., Gupta, V. K., (2015) Modeling of competitive ultrasonic assisted removal of the dyes – methylene blue and safranin-O using Fe3O4 nanoparticles. Chemical Engineering Journal, 268, 28-37.
  13. Gouamid, M., Ouahrani, M. R., Bensaci, M. B., (2013) Adsorption equilibrium, kinetics and thermodynamics of methylene blue from aqueous solutions using date palm leaves. Energy Procedia, (36), 898-907.
  14. Gupta V. K., Suhas, (2009) Application of low-cost adso