Dergiler / Atmospheric Pollution Research / 2019 / Cilt: 10 - Sayı: 2

Combining chemical components with stable isotopes to determine nitrate sources of precipitation in Hangzhou and Huzhou, SE China

Sayfa
386–394
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The seasonal variation of $delta^{15}N_{-NO_3}$ values wasinfluenced by the changing contributions of the main $N{O^-}_3$sources in precipitation collected from the studyareas: soil emissions increased in summer and coal consumption emissions increased because of coal consumption for winter heating from northern China in Hangzhou and Huzhou.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:The chemical components, air pollutants and stable isotopes of $N{O^-}_3$ were used to determine $N{O^-}_3$ sources inprecipitation and reveal $NO_x$ transformation mechanisms from 2015 to 2017 in the cities of Hangzhou andHuzhou, which are representative of most cities in Southeastern China (SE China).
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Temel Bulgular & Veri:The mean concentrations(monthly weighted-mean values) of $N{O^-}_3$ were 49.52 μmol $L^{-1}$ in Hangzhou, and were higher than $N{O^-}_3$concentrations (39.35 μmol $L^{-1}$) in Huzhou.
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Sonuç & Katkı:The seasonal variation of $delta^{15}N_{-NO_3}$ values wasinfluenced by the changing contributions of the main $N{O^-}_3$sources in precipitation collected from the studyareas: soil emissions increased in summer and coal consumption emissions increased because of coal consumption for winter heating from northern China in Hangzhou and Huzhou.
🔬Tür:Araştırma Makalesi
📍Kapsam:2015 Verileri
⚙️Değişkenler:Alan Parametreleri

Özet

The chemical components, air pollutants and stable isotopes of $N{O^-}_3$ were used to determine $N{O^-}_3$ sources inprecipitation and reveal $NO_x$ transformation mechanisms from 2015 to 2017 in the cities of Hangzhou andHuzhou, which are representative of most cities in Southeastern China (SE China). The mean concentrations(monthly weighted-mean values) of $N{O^-}_3$ were 49.52 μmol $L^{-1}$ in Hangzhou, and were higher than $N{O^-}_3$concentrations (39.35 μmol $L^{-1}$) in Huzhou. Both $delta^{15}N_{-NO_3}$ values (−4.4‰–3.7‰) and $delta^{18}O_{-NO_3}$ values(27.9‰–83.4‰) varied widely in the study areas. It was demonstrated that the main $N{O^-}_3$ sources in Hangzhouand Huzhou included coal consumption, traffic emissions and soil emissions. Higher levels of traffic emissions inHangzhou were responsible for the spatial variations in $N{O^-}_3$concentrations and $delta^{15}N_{-NO_3}$ values betweenHangzhou and Huzhou. The different NO2 oxidation pathways are particularly important in seasonal variation ofoxygen stable isotope in $N{O^-}_3$ Due to the oxidation of $NO_2$ via $O_3$ forming $HNO_3$ in the $N_2O_5$ pathway, thehighest $delta^{18}O_{-NO_3}$ values were observed in the winter. The lowest $delta^{18}O_{-NO_3}$ values were explained by the $NO_x$oxidation forming $HNO_3$ via the OH pathway in the summer. The seasonal variation of $delta^{15}N_{-NO_3}$ values wasinfluenced by the changing contributions of the main $N{O^-}_3$sources in precipitation collected from the studyareas: soil emissions increased in summer and coal consumption emissions increased because of coal consumption for winter heating from northern China in Hangzhou and Huzhou.

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Bu Makaleye Atıf Yap

JİN, Z., WANG, S. L. Y., QİAN, L., HU, Y., JİN, X., HONG, C., Lİ, F. (2019). Combining chemical components with stable isotopes to determine nitrate sources of precipitation in Hangzhou and Huzhou, SE China. Atmospheric Pollution Research, Cilt: 10 - Sayı: 2, 386–394. https://ajindex.com/articles/351294

Kaynakça (10)

  1. Buda, A.R., DeWalle, D.R., 2009. Using atmospheric chemistry and storm track information to explain the variation of nitrate stable isotopes in precipitation at a site in central Pennsylvania, USA. Atmos. Environ. 43, 4453–4464.
  2. Buzek, F., Cejkova, B., Hellebrandova, L., Jackova, I., Lollek, V., Lnenickova, Z., Matolakova, R., Veselovsky, F., 2017. Isotope composition of NH3, NOx and SO2 air pollution in the Moravia-Silesian region, Czech Republic. Atmos. Pollut. Res. 8, 221–232.
  3. Casciotti, K.L., Sigman, D.M., Hastings, M.G., Böhlke, J.K., Hilkert, A., 2002. Measurement of the oxygen isotopic composition of nitrate in seawater and freshwater using the denitrifier method. Anal. Chem. 74, 4905–4912.
  4. Dentener, F.J., Crutzen, P.J., 1994. A three-dimensional model of the global ammonia cycle. J. Atmos. Chem. 19, 331–369.
  5. Elliott, E.M., Kendall, C., Wankel, S.D., Burns, D.A., Boyer, E.W., Harlin, K., Bain, D.J., Butler, T.J., 2007. Nitrogen isotopes as indicators of NOx source contributions to atmospheric nitrate deposition across the Midwestern and Northeastern United States. Environ. Sci. Technol. 41, 7661–7667. EPAHZ1, 2009-2017. Environmental Protection Agency of Hangzhou (EPAHZ1), 2009- 2017. Hangzhou Environmental Bulletin. http://www.hzepb.gov.cn/. EPAHZ2, 2009-2017. Environmental Protection Agency of Huzhou (EPAHZ2), 2009- 2017. Huzhou Environmental Bulletin. http://www.hzhbj.gov.cn/.
  6. Felix, J.D., Elliott, E.M., Shaw, S.L., 2012. Nitrogen isotopic composition of coal-fired power plant NOx: influence of emission controls and implications for global emission inventories. Environ. Sci. Technol. 46 (6), 3528–3535.
  7. Felix, J.D., Elliott, E.M., Avery, G.B., Kieber, R.J., Mead, R.N., Willey, J.D., Mullaugh, K.M., 2015. Isotopic composition of nitrate in sequential Hurricane Irene precipitation samples Implications for changing $NO_x$ sources. Atmos. Environ. 106, 191–195.
  8. Fibiger, D.L., Hastings, M.G., 2016. First measurements of the nitrogen isotopic composition of $NO_x$ from biomass burning. Environ. Sci. Technol. 50 (21), 11569–11574.
  9. Freyer, H.D., Kley, D., Volz-Thomas, A., Kobel, K., 1993. On the interaction of isotopic exchange processes with photochemical reactions in atmospheric oxides of nitrogen. J. Geophys. Res. Atmos. 98 (8), 14791–14796.
  10. Galloway, J.N., Dentener, F.J., Capone, D.G., Boyer, E.W., Howarth, R.W., Seitzinger, S.P., Asner, G.P., Cleveland, C.C., Green, P.A., Holland, E.A., Karl, D.M., Michaels, A.F., Porter, J.H., Townsend, A.R., Vö rös