Dergiler / Organic Communications / 2020 / Cilt: 13 - Sayı: 2

Synthesis of chalcone-containing zinc and cobalt metallophthalocyanines; investigation of their photochemical, DPPH radical scavenging and metal chelating characters

Sayfa
65–78
DOI
—
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Singlet oxygen quantum yields of the synthesized compounds, aggregates in different solutions, metal chelating and 2,2- Diphenyl-1-picrylhydrazyl (DPPH) radical scavenging properties were reported.

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Amaç & Hipotez:In this study, two new phthalocyanines (M = Zn and Co) were synthesized using the (E)-4-(4-(3-(4- (benzyloxy)phenyl)acryloyl)phenoxy)phthalonitrile (3) as ligand prepared from the chemical reaction of 4- nitrophthalonitrile with (E)-3-(4-(benzyloxy)phenyl)-1-(4-hydroxyphenyl)prop-2-en-1-one (2).
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Temel Bulgular & Veri:All compounds were characterized using by 1H-NMR, 13C-NMR, UV–Vis, FT-IR, and MALDI-TOF mass spectra.
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Sonuç & Katkı:Singlet oxygen quantum yields of the synthesized compounds, aggregates in different solutions, metal chelating and 2,2- Diphenyl-1-picrylhydrazyl (DPPH) radical scavenging properties were reported.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Özet

In this study, two new phthalocyanines (M = Zn and Co) were synthesized using the (E)-4-(4-(3-(4- (benzyloxy)phenyl)acryloyl)phenoxy)phthalonitrile (3) as ligand prepared from the chemical reaction of 4- nitrophthalonitrile with (E)-3-(4-(benzyloxy)phenyl)-1-(4-hydroxyphenyl)prop-2-en-1-one (2). All compounds were characterized using by 1H-NMR, 13C-NMR, UV–Vis, FT-IR, and MALDI-TOF mass spectra. Singlet oxygen quantum yields of the synthesized compounds, aggregates in different solutions, metal chelating and 2,2- Diphenyl-1-picrylhydrazyl (DPPH) radical scavenging properties were reported.

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Bu Makaleye Atıf Yap

BARAN, A., KARAKILIÇ, E., FAİZ, Ö., ÖZEN, F. (2020). Synthesis of chalcone-containing zinc and cobalt metallophthalocyanines; investigation of their photochemical, DPPH radical scavenging and metal chelating characters. Organic Communications, Cilt: 13 - Sayı: 2, 65–78. https://ajindex.com/articles/288458

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Kaynakça (13)

  1. Claessens, C. G.; Hahn, U.; Torres, T. Phthalocyanines: From outstanding electronic properties to emerging applications. Chem. Record, 2008, 8, 75-97
  2. Çakır, D.; Arslan, T.; Bıyıklıoğlu, Z. Effect of substituent position and metal type on the electropolymerization properties of chalcone substituted metallophthalocyanines. Dalton Transaction. 2015, 44(48), 20859-20866
  3. Saka, E. T.; Çelik, G.; Sarkı, G.; Kantekin, H. Symmetrical and difunctional substituted cobalt phthalocyanines with benzoic acids fragments: Synthesis and catalytic activity J. Incl. Phenom. Macrocycl. Chem. 2016, 85, 161-168
  4. Stavric, B. Role of chemopreventers in human diet Clin. Biochem. 1994, 27(5), 319-332
  5. Lu, J.; Wang, C. Medicinal components and pharmacological effects of Rosa rugosa.Rec.Nat.Prod. 1994, 12, 535-543
  6. Çarıkçı, S.; Kılıç, T.; Özer, Z.; Dirmenci, T.; Arabaci, T.; Gören, A.C. Quantitative determination of some phenolics in Origanum laevigatum Boiss. extracts via validated LC-MS/MS method and antioxidant activity. J.Chem.Metrol. 2018, 12, 121-127
  7. Miller, J. D.; Baron, E. D.; Scull, H:; Hsia, A,; Berlin, J. C.; McCormick, T,; Colussi, V.; Kenney, M. E.; Cooper, K. D.; Oleinick. N. L. Photodynamic therapy with the phthalocyanine photosensitizer Pc 4: The case experience with preclinical mechanistic and early clinical–translational studies. Toxicol. Appl. Pharmacol. 2007, 224(3), 290–299
  8. Bacellar, I. O. L.;Tsubone, T. M.; Pavani, C.; Baptista, M. S. Photodynamic efficiency: From molecular photochemistry to cell death. Int. J. Mol. Sci. 2015, 16(9), 20523–20559
  9. Dougherty, T. J.;Charles J. G.; Henderson B. W.; Jori, Giulio.; D, Kessel.; Korbelik, M.; Moan J.; Qian, P. Photodynamic therapy. J. Nat. Cancer Inst. 1998, 90(12), 889–905
  10. O’Connor, A. E.; Gallagher, W. M.; Byrne, A. T. Porphyrin and nonporphyrin photosensitizers in oncology: Preclinical and clinical advances in photodynamic therapy. Photochem. Photobiol. 2009, 85, 1053–1074
  11. Manashi, B.; Milnes, M.; Williams, C.; Balmoori, J.; Ye, X.; Stohsand, S.; Bagchi, D. Acute and chronic stress-induced oxidative gastrointestinal injury in rats, and the protective ability of a novel grape seed proanthocyanidin extract. Nutr. Res. 1999, 19(8), 1189–1199
  12. Yıldız, S. Z.; Küçükislamoglu, M.; Tuna, M. Synthesis and characterization of novel flavonoidsubstituted phthalocyanines using (±)naringenin. J. Organomet. Chem. 2009, 694, 4152–4161
  13. Acar, I.; Arslan, T.; Topçu, S.; Serk