Dergiler / Gazi University Journal of Science / 2019 / Cilt: 32 - Sayı: 1

Structural Variations in SBA-15 by Copper Incorporation and a Test in Catalytic Wet Peroxide Oxidation of Phenol

Sayfa
91–102
Yayın Tarihi
2019-03-01
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The wet hydrogen peroxide catalytic oxidation of phenol performed in a batch reactor at 25, 40 and 60oC temperatures provided 56% phenol conversion at 60oC.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:This study presents the phenol removal in the wastewater via catalytic wet peroxide oxidation over Cu-SBA-15 catalyst.
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Temel Bulgular & Veri:The hydrothermally synthesized copper catalyst was characterized using XRD, N2 adsorption-desorption isotherms and FTIR analysis techniques.
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Sonuç & Katkı:The wet hydrogen peroxide catalytic oxidation of phenol performed in a batch reactor at 25, 40 and 60oC temperatures provided 56% phenol conversion at 60oC.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Cu-SBA-15 · Catalytic wet peroxide oxidation · Phenol

Abstract

This study presents the phenol removal in the wastewater via catalytic wet peroxide oxidation over Cu-SBA-15 catalyst. The hydrothermally synthesized copper catalyst was characterized using XRD, N2 adsorption-desorption isotherms and FTIR analysis techniques. The multiple BET surface area, total pore volume and mesopore diameter values were determined as 996 m2/g, 1.55 cm3/g and 6.82 nm, respectively. XRD pattern showed that the copper loading did not demolish the characteristic structure of SBA-15. FTIR spectrum of SBA-15 and catalyst without and with pyridine sorption showed the enhancement both in Lewis and Brønsted acidities by copper incorporation to the structure. The wet hydrogen peroxide catalytic oxidation of phenol performed in a batch reactor at 25, 40 and 60oC temperatures provided 56% phenol conversion at 60oC.

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Bu Makaleye Atıf Yap

AKTI, F., BALCI, S. (2019). Structural Variations in SBA-15 by Copper Incorporation and a Test in Catalytic Wet Peroxide Oxidation of Phenol. Gazi University Journal of Science, Cilt: 32 - Sayı: 1, 91–102. https://ajindex.com/articles/254483

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Kaynakça (13)

  1. Catrinescu, C., Teodosiu, C., Macoveanu, M., Miche-Brendle, J., Dred, R., “Catalytic wet peroxide oxidation of phenol over Fe- exchanged pillared beidellite”, Water Res., 37: 1154–1160, (2003)
  2. Taran, O.P., Zagoruiko, A.N., Yashnik, S. A., Ayusheev, A. B., Andrey V., Prosvirin, I.P., Prihod’kof, R.V., Goncharukf, V.V., Parmon, V.N., “Wet peroxide oxidation of phenol over carbon/zeolite catalysts. Kinetics and diffusion study in batch and flow reactors”, J. Environ. Chem. Eng., 6: 2551–2560, (2018)
  3. Damjanovic, L., Rakic, V., Rac, V., Stosic, D., Auruox, A., “The investigation of phenol removal from aqueous solutions by zeolites as solid adsorbents”, J.Hazard. Mat., 184: 477– 484, (2010)
  4. Garrido-Ramirez, E. G., Theng, B. K. G. Mora, M. L., “Clays and oxide minerals as catalysts and nanocatalysts in Fenton-like reactions—a review”, App. Clay Sci., 47 (3–4): 182–192, (2010)
  5. Moyo, M., Mutare, E., Chigondo F., Nyamunda, B.C., “Removal of phenol from aqueous by adsorption on yeast, Saccharomyces Cerevisiae”, IJRRAS, 11: 3, (2012)
  6. Zhong, M., Wang, Y., Yu, J., Tian, Y., Xu, G., “Porous carbon from vinegar lees for phenol adsorption”, Particuology, 10: 35– 41, (2012)
  7. Alejandre A., Medina F., Salagre P., Fabregat A., Sueiras J.E. “Characterization and activity of copper and nickel catalysts for the oxidation of phenol aqueous solutions.” Applied Catalysis B: Environmental, 18: 307–315, (1998)
  8. Rokhina E.V. Virkutyte J. “Environmental application of catalytic processes: Heterogeneous liquid phase oxidation of phenol with hydrogen peroxide.” Critical Reviews in Environmental Science and Technology, 41: 125-167, (2011)
  9. Kim, K.H., Ihm, S.K., “Heterogeneous catalytic wet air oxidation of refractory organic pollutants in industrial wastewaters: A review”, Journal of Hazardous Materials, 186: 16–34, (2011)
  10. Kulkarni S.J, Kaware J.P., “Review on research for removal of phenol from wastewater”, Int. J, Sci. Res. Publ., 3: 1–4, (2013)
  11. Divate, S.B., Hinge, R.V., “Review on research removal of phenol from wastewater by using different methods”, International Journal of Scientific and Research Publications, 5: 1-3, (2014)
  12. Cordova Villegas, L.G., Mashhadi, N., Chen, M., Mukherjee, D., Taylor, K.E., Biswas, N.A., “Short Review of Techniques for Phenol Removal from Wastewater”, Curr Pollution Rep., 2: 157–167, (2016)
  13. Emgili, H., Yabalak, Erdal., Görmez, Ö., Gizir, A.M., “Degradation of Maxilon Blue GRL Dye ısing subcri