Dergiler / Turkish Journal of Chemistry / 2008 / Cilt: 32 - Sayı: 1

Synthesis and Characterization of a Novel Metal Phosphonate, Zirconium (IV)-Hydroxy Ethylidene Diphosphonate, and Its Application as an Ion Exchanger

Sayfa
63–74
Yayın Tarihi
2008-01-01
DOI
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The sorption of the metal ions follow the order Zn(II) > Cu(II) > Mn(II) \approx Ni(II).

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Amaç & Hipotez:A novel hybrid ion exchange material, Zirconium-hydroxy ethylidene diphosphonate [ZrHEDP], of the class of tetravalent metal acid (TMA) salts has been synthesized by the sol-gel technique.
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Temel Bulgular & Veri:The material was characterized with elemental analysis (ICP-AES), thermal analysis (TGA, DSC), and FT-IR and X-ray diffraction studies.
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Sonuç & Katkı:The sorption of the metal ions follow the order Zn(II) > Cu(II) > Mn(II) \approx Ni(II).
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Inorganic ion exchanger · metal phosphonate · tetravalent metal acid salt

Özet

A novel hybrid ion exchange material, Zirconium-hydroxy ethylidene diphosphonate [ZrHEDP], of the class of tetravalent metal acid (TMA) salts has been synthesized by the sol-gel technique. The material was characterized with elemental analysis (ICP-AES), thermal analysis (TGA, DSC), and FT-IR and X-ray diffraction studies. The chemical resistivity of the material in various media was evaluated. ZrHEDP was further investigated for its possible use as an ion exchanger. The Na+ ion-exchange capacity (IEC) of the material was determined, and kinetics and thermodynamics of exchange for the metal ions Cu(II), Ni(II), Zn(II), and Mn(II) towards ZrHEDP were studied. The sorption of the metal ions follow the order Zn(II) > Cu(II) > Mn(II) \approx Ni(II).

Abstract

A novel hybrid ion exchange material, Zirconium-hydroxy ethylidene diphosphonate [ZrHEDP], of the class of tetravalent metal acid (TMA) salts has been synthesized by the sol-gel technique. The material was characterized with elemental analysis (ICP-AES), thermal analysis (TGA, DSC), and FT-IR and X-ray diffraction studies. The chemical resistivity of the material in various media was evaluated. ZrHEDP was further investigated for its possible use as an ion exchanger. The Na+ ion-exchange capacity (IEC) of the material was determined, and kinetics and thermodynamics of exchange for the metal ions Cu(II), Ni(II), Zn(II), and Mn(II) towards ZrHEDP were studied. The sorption of the metal ions follow the order Zn(II) > Cu(II) > Mn(II) \approx Ni(II).

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Bu Makaleye Atıf Yap

JAYSWAL, A., CHUDASAMA, U. (2008). Synthesis and Characterization of a Novel Metal Phosphonate, Zirconium (IV)-Hydroxy Ethylidene Diphosphonate, and Its Application as an Ion Exchanger. Turkish Journal of Chemistry, Cilt: 32 - Sayı: 1, 63–74. https://ajindex.com/articles/217977

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