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Dergiler / Turkish Journal of Chemistry / 2005 / Cilt: 29 - Sayı: 3

New Complexes of Organotin(IV) 2-(N-Maleoylamino)-2-methylpropanoate: Synthesis, Spectroscopic Characterization and Biological Activity

Sajjad AHMAD
Saqib ALI
Saira SHAHZADI
Fiaz AHMED
Khalid M. KHAN
Sayfa
299–308
Yayın Tarihi
2005-03-01
DOI
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These results show that triorganotin(IV) carboxylates are more active against the animal and plant pathogens tested as compared to diorganotin dicarboxylates.

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Amaç & Hipotez:Organotin(IV) complexes of 2-(N-maleoylamino)-2-methylpropanoate were prepared by treating the ligand acid with diorganotin dichloride and triorganotin chloride in 1:2 and 1:1 molar ratios, respectively.
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Temel Bulgular & Veri:These reactions proceeded smoothly to completion and the complexes formed were characterized by elemental analysis, infrared, multinuclear NMR (1H, 13C, 119Sn) and mass spectrometry.
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Sonuç & Katkı:These results show that triorganotin(IV) carboxylates are more active against the animal and plant pathogens tested as compared to diorganotin dicarboxylates.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Organotin(IV) carboxylates · spectroscopic studies · biological activity.

Özet

Organotin(IV) complexes of 2-(N-maleoylamino)-2-methylpropanoate were prepared by treating the ligand acid with diorganotin dichloride and triorganotin chloride in 1:2 and 1:1 molar ratios, respectively. These reactions proceeded smoothly to completion and the complexes formed were characterized by elemental analysis, infrared, multinuclear NMR (1H, 13C, 119Sn) and mass spectrometry. The biological activities of the tin complexes were studied by screening the compounds against various animal and plant pathogens. These results show that triorganotin(IV) carboxylates are more active against the animal and plant pathogens tested as compared to diorganotin dicarboxylates.

Abstract

Organotin(IV) complexes of 2-(N-maleoylamino)-2-methylpropanoate were prepared by treating the ligand acid with diorganotin dichloride and triorganotin chloride in 1:2 and 1:1 molar ratios, respectively. These reactions proceeded smoothly to completion and the complexes formed were characterized by elemental analysis, infrared, multinuclear NMR (1H, 13C, 119Sn) and mass spectrometry. The biological activities of the tin complexes were studied by screening the compounds against various animal and plant pathogens. These results show that triorganotin(IV) carboxylates are more active against the animal and plant pathogens tested as compared to diorganotin dicarboxylates.

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Bu Makaleye Atıf Yap

AHMAD, S., ALI, S., SHAHZADI, S., AHMED, F., KHAN, K. M. (2005). New Complexes of Organotin(IV) 2-(N-Maleoylamino)-2-methylpropanoate: Synthesis, Spectroscopic Characterization and Biological Activity. Turkish Journal of Chemistry, Cilt: 29 - Sayı: 3, 299–308. https://ajindex.com/articles/185429

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