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Dergiler / Turkish Journal of Chemistry / 2015 / Cilt: 39 - Sayı: 3

A new and simple procedure for the trace determination of mercury using differential pulse polarography and application to a salt lake sample

GÜLER SOMER
A. CENGİZ ÇALIŞKAN
OLCAY ŞENDİL
Sayfa
639–647
Yayın Tarihi
2015-08-13
DOI
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It was found that sulfite concentration had to be 3 times larger than mercury at pH 6, in order to have a quantitative reaction.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:A new and simple differential pulse polarographic procedure was established for the trace determination of mercury(II).
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Temel Bulgular & Veri:According to their standard potentials, the reaction between SO$_{3}^{2-}$ and Hg(II) was suitable.
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Sonuç & Katkı:It was found that sulfite concentration had to be 3 times larger than mercury at pH 6, in order to have a quantitative reaction.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:The procedure is simple: to a known amount of sulfite in the polarographic cell (HAc · pH 6 or 7) is added an unknown Hg(II) sample. The Hg(II) concentration is calculated simply from the decrease in the sulfite peak after reaction with Hg(II). The limit · The procedure is simple: to a known amount of sulfite in the polarographic cell (HAc

Özet

A new and simple differential pulse polarographic procedure was established for the trace determination of mercury(II). An indirect method had to be used since no polarographic peak can be observed for its direct determination. According to their standard potentials, the reaction between SO$_{3}^{2-}$ and Hg(II) was suitable. The peak height of sulfite at about -0.70 V (pH 6, 7) was sharp, high, and very reproducible, enabling the accurate determination of low concentrations of Hg(II). It was found that sulfite concentration had to be 3 times larger than mercury at pH 6, in order to have a quantitative reaction.

Abstract

A new and simple differential pulse polarographic procedure was established for the trace determination of mercury(II). An indirect method had to be used since no polarographic peak can be observed for its direct determination. According to their standard potentials, the reaction between SO$_{3}^{2-}$ and Hg(II) was suitable. The peak height of sulfite at about -0.70 V (pH 6, 7) was sharp, high, and very reproducible, enabling the accurate determination of low concentrations of Hg(II). It was found that sulfite concentration had to be 3 times larger than mercury at pH 6, in order to have a quantitative reaction.

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Bu Makaleye Atıf Yap

SOMER, G., ÇALIŞKAN, A. C., ŞENDİL, O. (2015). A new and simple procedure for the trace determination of mercury using differential pulse polarography and application to a salt lake sample. Turkish Journal of Chemistry, Cilt: 39 - Sayı: 3, 639–647. https://ajindex.com/articles/184947

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