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Dergiler / Turkish Journal of Chemistry / 2018 / Cilt: 42 - Sayı: 4

Syntheses and characterizations of cyclotriphosphazenes containing a 4-oxy-1-naphthaldehyde group

Hanife İBİŞOĞLU
Esra TANRIVERDİ EÇİK
Gönül YENİLMEZ ÇİFTÇİ
Sayfa
1174–1183
Yayın Tarihi
2018-08-03
DOI
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The structures of the new compounds (3-7) were determined by elemental analysis, FT-IR, and mass and nuclear magnetic resonance (11^{1}H and 3131^{31}P) spectroscopies.

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Amaç & Hipotez:The nucleophilic substitution reaction of hexachlorocyclotriphosphazene (N33_{3}P33_{3}Cl66_{6}, trimer) (1) with 4-hydroxy-1-naphthaldehyde (2) has been investigated for the first time. 4′′^{{\prime}} -Oxy-1′′^{{\prime}} -naphthaldehyde substituted mono- (3), bis- (4), and tris- (5) cyclotriphosphazenes were obtained from the nucleophilic substitution of compound 1 with 2 in a 1:2 molar ratio in the presence of Cs22_{2}CO33_{3} in acetone at reflux.
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Temel Bulgular & Veri:The pentakis-(6) and hexakis-substituted (7) cyclotriphosphazenes were prepared from the reaction of 1 with 2 in a 1:7 molar ratio using K22_{2}CO33_{3} as a proton abstractor in tetrahydrofuran at room temperature.
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Sonuç & Katkı:The structures of the new compounds (3-7) were determined by elemental analysis, FT-IR, and mass and nuclear magnetic resonance (11^{1}H and 3131^{31}P) spectroscopies.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Cyclotriphosphazene · 4-hydroxy-1-naphthaldehyde · nuclear magnetic resonance

Abstract

The nucleophilic substitution reaction of hexachlorocyclotriphosphazene (N33_{3}P33_{3}Cl66_{6}, trimer) (1) with 4-hydroxy-1-naphthaldehyde (2) has been investigated for the first time. 4′′^{{\prime}} -Oxy-1′′^{{\prime}} -naphthaldehyde substituted mono- (3), bis- (4), and tris- (5) cyclotriphosphazenes were obtained from the nucleophilic substitution of compound 1 with 2 in a 1:2 molar ratio in the presence of Cs22_{2}CO33_{3} in acetone at reflux. The pentakis-(6) and hexakis-substituted (7) cyclotriphosphazenes were prepared from the reaction of 1 with 2 in a 1:7 molar ratio using K22_{2}CO33_{3} as a proton abstractor in tetrahydrofuran at room temperature. The structures of the new compounds (3-7) were determined by elemental analysis, FT-IR, and mass and nuclear magnetic resonance (11^{1}H and 3131^{31}P) spectroscopies.

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Bu Makaleye Atıf Yap

İBİŞOĞLU, H., EÇİK, E. T., ÇİFTÇİ, G. Y. (2018). Syntheses and characterizations of cyclotriphosphazenes containing a 4-oxy-1-naphthaldehyde group. Turkish Journal of Chemistry, Cilt: 42 - Sayı: 4, 1174–1183. https://ajindex.com/articles/184382

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