✨
Yapay Zeka Hızlı Bakış & Çıkarımlar
AI Insight⚡ TL;DR(1 Cümlede Hızlı Çıkarım)
The structural determinations were accomplished by NOESY $^{1}$H NMR and X-ray crystallography.
📌 3 Maddede Bu Makale
🎯
Amaç & Hipotez:Regio- and stereoselective synthesis of $N$-substituted azole acrylonitriles has been achieved smoothly in $N,N$-dimethylformamide (DMF) in the presence of potassium carbonate (K$_{2}$CO$_{3})$ as a base catalyst. $N$-Substituted azole acrylonitriles were obtained in moderate to good yields (39%-87%) with a one-pot reaction between readily available $N$-acetylazoles and Baylis-Hillman nitriles.
📊
Temel Bulgular & Veri:Regio- and stereoselective synthesis of $N$-substituted azole acrylonitriles has been achieved smoothly in $N,N$-dimethylformamide (DMF) in the presence of potassium carbonate (K$_{2}$CO$_{3})$ as a base catalyst. $N$-Substituted azole acrylonitriles were obtained in moderate to good yields (39%-87%) with a one-pot reaction between readily available $N$-acetylazoles and Baylis-Hillman nitriles.
💡
Sonuç & Katkı:The structural determinations were accomplished by NOESY $^{1}$H NMR and X-ray crystallography.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Baylis-Hillman nitriles · benzimidazole · benzotriazole
Abstract
Regio- and stereoselective synthesis of $N$-substituted azole acrylonitriles has been achieved smoothly in $N,N$-dimethylformamide (DMF) in the presence of potassium carbonate (K$_{2}$CO$_{3})$ as a base catalyst. $N$-Substituted azole acrylonitriles were obtained in moderate to good yields (39%-87%) with a one-pot reaction between readily available $N$-acetylazoles and Baylis-Hillman nitriles. The structural determinations were accomplished by NOESY $^{1}$H NMR and X-ray crystallography.
Anahtar kelimeler
🔖
Bu Makaleye Atıf Yap
AYDIN, O., KÖKTEN, Ş., ÜNVER, H., ÇELİK, İ. (2019). $N$-Acylazole mediated stereoselective and regioselective synthesis of $N$-substituted azole acrylonitriles. Turkish Journal of Chemistry, Cilt: 43 - Sayı: 4, 1134–1148. https://ajindex.com/articles/184342