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Dergiler / Journal of Scientific Reports-A / 2018 / Issue: 041

(1Z, 2E)-N’-HİDROKSİL-2-HİDROKSİİMİNO-N-p-TOLİL-ASETAMİDİN LİGANDININ Fe(II) VE Zn(II) KOMPLEKSLERININ SENTEZI VE YAPILARININ AYDINLATILMASI

AND CHARACTERIZATION OF METAL COMPLEXES OF (1Z,2E)-N'-HYDROXY-2-(HYDROXYIMINO)-N-(p-TOLYL)ACETIMIDAMIDE LIGAND

Halil İlkimen0000-0003-1747-159X
Sayfa
13–22
Yayın Tarihi
2018-12-16
DOI
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Amorf halde elde edilen Fe(II) ve Zn(II) komplekslerinin yapıları ise elementel analiz, ICP-OES, FT-IR, UV-Vis, manyetik duyarlılık ve molar iletkenlik sonuçları dikkate alınarak önerilmiştir.

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Amaç & Hipotez:Bu çalışmada anti -kloroglioksim (gly) ile p -toluidin ( p tol) reaksiyonundan (1Z, 2E)- N’ -hidroksil-2-hidroksiimino- N - p- tolil-asetamidin (H 2 L) ligandı literatürde belirtildiği şekilde sentezlenmiştir.
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Temel Bulgular & Veri:Ligandın yapısı elementel analiz, 1 H-NMR, 13 C-NMR , FT-IR, UV-Vis metotları ile aydınlatılmıştır.
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Sonuç & Katkı:Amorf halde elde edilen Fe(II) ve Zn(II) komplekslerinin yapıları ise elementel analiz, ICP-OES, FT-IR, UV-Vis, manyetik duyarlılık ve molar iletkenlik sonuçları dikkate alınarak önerilmiştir.
🔬Tür:Literatür & Derleme Çalışması
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Glioksim · Metal Kompleksleri · p-Toluidin

Özet

Bu çalışmada anti -kloroglioksim (gly) ile p -toluidin ( p tol) reaksiyonundan (1Z, 2E)- N’ -hidroksil-2-hidroksiimino- N - p- tolil-asetamidin (H 2 L) ligandı literatürde belirtildiği şekilde sentezlenmiştir. Daha sonra bu ligandının Fe(II) ve Zn(II) metal kompleksleri sentezlenmiştir. Ligandın yapısı elementel analiz, 1 H-NMR, 13 C-NMR , FT-IR, UV-Vis metotları ile aydınlatılmıştır. Amorf halde elde edilen Fe(II) ve Zn(II) komplekslerinin yapıları ise elementel analiz, ICP-OES, FT-IR, UV-Vis, manyetik duyarlılık ve molar iletkenlik sonuçları dikkate alınarak önerilmiştir.

Abstract

In this study, (1Z,2E)- N '-hydroxy-2-(hydroxyimino)- N -( p -tolyl)acetimidamide (H 2 L) ligand was synthesized, which is reported in literature, and ligand constituted anti -chloroglyoxime (gly) and p- toluidin ( p tol) was synthesized and its metal complexes with Fe(II) and Zn(II) were obtained. The structure of ligand has been proposed by using elemantal analysis, 1 H-NMR, 13 C‑NMR, FT-IR, UV-Vis techniques. The structure of amorphous Fe(II) and Zn(II)complexes have been proposed by using elemantal analysis, ICP-OES, FT-IR, UV-Vis, magnetic susceptibility and molar conductivity techniques.

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Bu Makaleye Atıf Yap

İlkimen, H. (2018). (1Z, 2E)-N’-HİDROKSİL-2-HİDROKSİİMİNO-N-p-TOLİL-ASETAMİDİN LİGANDININ Fe(II) VE Zn(II) KOMPLEKSLERININ SENTEZI VE YAPILARININ AYDINLATILMASI. Journal of Scientific Reports-A, Issue: 041, 13–22. https://ajindex.com/articles/1512094

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