Dergiler / Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji / 2018 / Cilt: 6 Sayı: 4

Polianilin/Aljinat Kompozit Malzemesinin Asit Violet 90 Boyar Maddesinin Gideriminde Kullanılması: Kinetik Ve İzoterm Değerlendirmesi

Sayfa
729–740
Yayın Tarihi
2018-12-30
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Deney sonuçları PANİ/SA adsorbentinin AV 90 boyar maddesinin adsorpsiyonu için oldukça iyi bir alternatif olduğunu göstermiştir.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Bu çalışmada Polianilin/Aljinat (PANİ/SA) kompozit malzemesi Asit Violet 90 (AV 90) boyar maddesinin adsorpsiyonunda kullanılmıştır.
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Temel Bulgular & Veri:PANİ/SA’nın karakterizasyonu Fourier Dönüşüm Kızılötesi Spektroskopisi (FTIR ile analiz edilmiştir. pH (2-6), PANİ/SA küre miktarı (10-50 adet) ve AV 90 derişiminin (25-200 mg/L) boyar madde giderimine etkisi incelenmiştir.
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Sonuç & Katkı:Deney sonuçları PANİ/SA adsorbentinin AV 90 boyar maddesinin adsorpsiyonu için oldukça iyi bir alternatif olduğunu göstermiştir.
🔬Tür:Modelleme & Sayısal Simülasyon
📍Kapsam:50 adet
⚙️Değişkenler:Polianilin · aljinat · Asit violet 90

Özet

Bu çalışmada Polianilin/Aljinat (PANİ/SA) kompozit malzemesi Asit Violet 90 (AV 90) boyar maddesinin adsorpsiyonunda kullanılmıştır. PANİ/SA’nın karakterizasyonu Fourier Dönüşüm Kızılötesi Spektroskopisi (FTIR ile analiz edilmiştir. pH (2-6), PANİ/SA küre miktarı (10-50 adet) ve AV 90 derişiminin (25-200 mg/L) boyar madde giderimine etkisi incelenmiştir. En yüksek boyar madde giderimi pH 2’de elde edilmiştir. AV 90 adsorpsiyon izotermlerini belirlemek için Langmuir, Freundlich ve Temkim izoterm modelleri kullanılmıştır. 25-200 mg/L boyar madde derişimi aralığında Langmuir modelinden elde edilen maksimum adsorpsiyon kapasitesi (q m ) değeri 138,9 mg/g olarak bulunmuştur. Adsorpsiyon kinetiğinin belirlenmesi için yalancı birinci derece ve ikinci derece kinetik modelleri kullanılmış ve en Yalancı ikinci derece kinetik modelin deney verileri ile daha uyumlu olduğu görülmüştür. Deney sonuçları PANİ/SA adsorbentinin AV 90 boyar maddesinin adsorpsiyonu için oldukça iyi bir alternatif olduğunu göstermiştir.

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Bu Makaleye Atıf Yap

Okur, M., Aktı, F., Çetintaş, A. (2018). Polianilin/Aljinat Kompozit Malzemesinin Asit Violet 90 Boyar Maddesinin Gideriminde Kullanılması: Kinetik Ve İzoterm Değerlendirmesi. Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji, Cilt: 6 Sayı: 4, 729–740. https://doi.org/10.29109/gujsc.383614

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Kaynakça (46)

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  2. Mohammadi, A., Daemi, H., Barikani, M., Fast removal of malachite green dye using novel superparamagnetic sodium alginate-coated Fe3O4 nanoparticles, International Journal of Biological Macromolecules, 69, 447-455, 2014
  3. Laabd, M., Ahsaine, H. A., Jaouhari, A., Bakiz, B., Bazzaoui, M., Ezahri, M., Albourine, A., Benlhachemi A., Congo red removal by PANi/Bi2WO6 nanocomposites: Kinetic, equilibrium and thermodynamic studies, Journal of Environmental Chemical Engineering 4, 3096–3105, 2016
  4. Patil, M.R., Shrivastava, V.S., Adsorption removal of carcinogenic acid violet19 dye from aqueous solution by polyaniline-Fe2O3 magnetic nano-composite, J.Mater.Environ.Sci. 6 (1), 11-21, 2015
  5. Hassani, A., Soltani, R. D. C., Karaca, S., Khataee, A., “Preparation of montmorillonite–alginate nanobiocomposite for adsorption of a textile dye in aqueous phase: Isotherm, kinetic and experimental design approaches”, Journal of Industrial and Engineering Chemistry 21, 1197–1207, 2015
  6. Sarıoğlu, Ö.F., Keskin, N.O., Çelebioğlu, A., Tekinay, T., Uyar, T., Bacteria encapsulated electrospun nanofibrous webs for remediation of methylene blue dye in water, Colloids and Surfaces B: Biointerfaces, 152, 245-251, 2017
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  10. Pandiselvi, K., Thambidurai, S., “Synthesis of porous chitosan–polyaniline/ZnO hybrid composite and application for removal of reactive orange 16 dye”, Colloids and Surfaces B: Biointerfaces 108, 229– 238, 2013
  11. Wang, J., Han, X., Ma, H., Ji, Y., Bi, L., Adsorptive removal of humic acid from aqueous solution on polyaniline/attapulgite composite, Chemical Engineering Journal 173, 171– 177, 2011
  12. Salem, M.A., Elsharkawy, R., Hablas, M.F., ‘Adsorption of Brilliant Green dye by polyaniline/silver nanocomposite: Kinetic, equilibrium, and thermodynamic studies’, European Polymer Journal, 75, 577-590, 2016
  13. Mu,B., Tang, J., Zhang, L., Wang, A., Preparation, characterization and application on dye adsorption of a well-defined two-dimensional superparamagnetic clay/polyaniline/Fe3O4 nanocomposite, Applied Clay Science, 132–133, 7-16, 2016
  14. Olad, A., Naseri, B., Preparation, characterization and anticorrosive properties of a novel polyaniline/clinoptilolite nanocomposite, Progress in Organic Coatings, 67, 233–238, 2010
  15. Jiang, N., Xu, Y., Dai, Y., Lou, W., Dai, L., ‘Polyaniline nanofibers assembled on alginate microsphere for Cu2+ and Pb2+ uptake’, Journal of Hazardous Materials,215-216,17-24, 2012
  16. Ayazi,Z., Khoshhesab, Z.M., Azhar, F.F., Mohajeri, Z., “Modeling and Optimization of Adsorption Removal of Reactive Orange 13 on the Alginate–Montmorillonite–Polyaniline Nanocomposite via Response Surface Methodology”, Journal of the Chinese Chemical Society, 64, 627-639, 2017
  17. Zhuang, Y., Yu, F., Chen, J., Ma, J., Batch and column adsorption of methylene blue by graphene/alginate nanocomposite: Comparison of single-network and double-network hydrogels, Journal of Environmental Chemical Engineering, 4(1), 147-156, 2016
  18. Karthik, R., Meenakshi, S., ‘Removal of Cr(VI) ions by adsorption onto sodiumalginate-polyaniline nanofibers’, International Journal of Biological Macromolecules, 72, 711–717, 2015
  19. Sharma, V., Rekha, P., Mohanty, P., Nanoporous hypercrosslinked polyaniline: An efficient adsorbent for the adsorptive removal of cationic and anionic dyes, 222, 1091-1100, 2016
  20. Lu, T., Xiang, T., Huang, X.L., Li,C., Zhao, W.F., Zhang, Q., Zhao, C.S., “Post-crosslinking towards stimuli-responsive sodium alginate beads fort he removal of dye and heavy metals”, Carbohydrate Polymers, 133, 587-595, 2015
  21. Kaykıoğlu, G., “Kolemanit ve Üleksit Atığı ile Sulu Çözeltilerden Metilen Mavisi Giderimi: Kinetik ve İzoterm Değerlendirmesi”, CBÜ Fen Bil. Dergi., 12(3), 499-509, 2016
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  23. Rafiqi, F.A., Majid, K., ‘Removal of copper from aqueous solution using polyaniline and polyaniline/ferricyanide composite, Journal of Environmental Chemical Engineering, 3,2492-2501,2015
  24. Yang, L., Ma, X., Guo, N., Sodium alginate/Na+-rectorite composite microspheres: preparation, characterization, and dye adsorption, Carbohydrate Polymers, 90, 853-858, 2012
  25. Mohammadi, A., Daemi, H., Barikani, M., Fast removal of malachite green dye using novel superparamagnetic sodium alginate-coated Fe3O4 nanoparticles, International Journal of Biological Macromolecules, 69, 447-455, 2014
  26. Laabd, M., Ahsaine, H. A., Jaouhari, A., Bakiz, B., Bazzaoui, M., Ezahri, M., Albourine, A., Benlhachemi A., Congo red removal by PANi/Bi2WO6 nanocomposites: Kinetic, equilibrium and thermodynamic studies, Journal of Environmental Chemical Engineering 4, 3096–3105, 2016
  27. Patil, M.R., Shrivastava, V.S., Adsorption removal of carcinogenic acid violet19 dye from aqueous solution by polyaniline-Fe2O3 magnetic nano-composite, J.Mater.Environ.Sci. 6 (1), 11-21, 2015
  28. Hassani, A., Soltani, R. D. C., Karaca, S., Khataee, A., “Preparation of montmorillonite–alginate nanobiocomposite for adsorption of a textile dye in aqueous phase: Isotherm, kinetic and experimental design approaches”, Journal of Industrial and Engineering Chemistry 21, 1197–1207, 2015
  29. Sarıoğlu, Ö.F., Keskin, N.O., Çelebioğlu, A., Tekinay, T., Uyar, T., Bacteria encapsulated electrospun nanofibrous webs for remediation of methylene blue dye in water, Colloids and Surfaces B: Biointerfaces, 152, 245-251, 2017
  30. Kocaer, F.O., Alkan, U., “Boyar madde içeren tekstil atık sularının arıtım alternatifleri”, Uludağ Üniv. Müh.Mim.Fak.Dergisi, Cilt 7, No 1, 47-55, 2002
  31. Jain, R., Gupta, V.K., Sikarwa, S., “Adsorption and desorption studies on hazardous dye Naphthol Yellow S”, Journal of Hazardous Materials, Cilt 182, 749-756, 2010
  32. Gengec, E., Color removal from anaerobic/aerobic treatment effluent of bakery yeast wastewater by polyaniline/beidellite composite materials, Journal of Environmental Chemical Engineering, 3, 2484–2491, 2015
  33. Pandiselvi, K., Thambidurai, S., “Synthesis of porous chitosan–polyaniline/ZnO hybrid composite and application for removal of reactive orange 16 dye”, Colloids and Surfaces B: Biointerfaces 108, 229– 238, 2013
  34. Wang, J., Han, X., Ma, H., Ji, Y., Bi, L., Adsorptive removal of humic acid from aqueous solution on polyaniline/attapulgite composite, Chemical Engineering Journal 173, 171– 177, 2011
  35. Salem, M.A., Elsharkawy, R., Hablas, M.F., ‘Adsorption of Brilliant Green dye by polyaniline/silver nanocomposite: Kinetic, equilibrium, and thermodynamic studies’, European Polymer Journal, 75, 577-590, 2016
  36. Mu,B., Tang, J., Zhang, L., Wang, A., Preparation, characterization and application on dye adsorption of a well-defined two-dimensional superparamagnetic clay/polyaniline/Fe3O4 nanocomposite, Applied Clay Science, 132–133, 7-16, 2016
  37. Olad, A., Naseri, B., Preparation, characterization and anticorrosive properties of a novel polyaniline/clinoptilolite nanocomposite, Progress in Organic Coatings, 67, 233–238, 2010
  38. Jiang, N., Xu, Y., Dai, Y., Lou, W., Dai, L., ‘Polyaniline nanofibers assembled on alginate microsphere for Cu2+ and Pb2+ uptake’, Journal of Hazardous Materials,215-216,17-24, 2012
  39. Ayazi,Z., Khoshhesab, Z.M., Azhar, F.F., Mohajeri, Z., “Modeling and Optimization of Adsorption Removal of Reactive Orange 13 on the Alginate–Montmorillonite–Polyaniline Nanocomposite via Response Surface Methodology”, Journal of the Chinese Chemical Society, 64, 627-639, 2017
  40. Zhuang, Y., Yu, F., Chen, J., Ma, J., Batch and column adsorption of methylene blue by graphene/alginate nanocomposite: Comparison of single-network and double-network hydrogels, Journal of Environmental Chemical Engineering, 4(1), 147-156, 2016
  41. Karthik, R., Meenakshi, S., ‘Removal of Cr(VI) ions by adsorption onto sodiumalginate-polyaniline nanofibers’, International Journal of Biological Macromolecules, 72, 711–717, 2015
  42. Sharma, V., Rekha, P., Mohanty, P., Nanoporous hypercrosslinked polyaniline: An efficient adsorbent for the adsorptive removal of cationic and anionic dyes, 222, 1091-1100, 2016
  43. Lu, T., Xiang, T., Huang, X.L., Li,C., Zhao, W.F., Zhang, Q., Zhao, C.S., “Post-crosslinking towards stimuli-responsive sodium alginate beads fort he removal of dye and heavy metals”, Carbohydrate Polymers, 133, 587-595, 2015
  44. Kaykıoğlu, G., “Kolemanit ve Üleksit Atığı ile Sulu Çözeltilerden Metilen Mavisi Giderimi: Kinetik ve İzoterm Değerlendirmesi”, CBÜ Fen Bil. Dergi., 12(3), 499-509, 2016
  45. Okur, M., “Tekstil Atıksularındaki Metal Kompleks Boyarmaddelerin Yumurta Kabukları İle Giderimi”, Journal of the Faculty of Engineering and Architecture of Gazi University, 28 (4), 777-785, 2013
  46. Rafiqi, F.A., Majid, K., ‘Removal of copper from aqueous solution using polyaniline and polyaniline/ferricyanide composite, Journal of Environmental Chemical Engineering, 3,2492-2501,2015.