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Dergiler / Karaelmas Fen ve Mühendislik Dergisi / 2025 / Cilt: 15 Sayı: 3

Monte Carlo FLUKA Simülasyonları Kullanılarak Hidrotermal Olarak Sentezlenen CuO Nanopartiküllerinin Radyasyon Kalkanı Özelliklerinin Değerlendirilmesi

Evaluation of Radiation Shielding Properties of Hydrothermally Synthesized CuO Nanoparticles Using Monte Carlo FLUKA Simulations

Saniye Tekerek(KAHRAMANMARAŞ SÜTÇÜ İMAM ÜNİVERSİTESİ)0000-0003-3326-358X
Sayfa
120–130
Yayın Tarihi
2025-11-19
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Malzemedeki enerji birikimi, çalışılan malzemenin radyasyon zırhlama özelliklerini değerlendirmek için önemli bilgiler sağladı.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Bakır oksit nanoparçacıkları (CuO NP), 105 °C’de hidrotermal çöktürme yöntemiyle sentezlendi.
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Temel Bulgular & Veri:Nanopartiküllerin direkt optik bant genişliği ve Urbach boşluk genişliği sırasıyla 2,88 eV ve 0,44 eV olarak bulundu.
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Sonuç & Katkı:Malzemedeki enerji birikimi, çalışılan malzemenin radyasyon zırhlama özelliklerini değerlendirmek için önemli bilgiler sağladı.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:CuO nanoparticles · FLUKA simulation · Monte Carlo

Özet

Bakır oksit nanoparçacıkları (CuO NP), 105 °C’de hidrotermal çöktürme yöntemiyle sentezlendi. CuO nanoparçacıklarının yapısı, X-ışını kırınımı (XRD) ve taramalı elektron mikroskobu (SEM) ile karakterize edildi. Optik özellikleri ise UV-vis spektrofotometresi kullanılarak incelendi. Tüm nanoparçacıklar için XRD ölçümleri, monoklinik CuO fazının oluştuğunu ortaya koydu. Nanopartiküllerin direkt optik bant genişliği ve Urbach boşluk genişliği sırasıyla 2,88 eV ve 0,44 eV olarak bulundu. Optik ölçümlere dayanarak kırılma indisi (n), soğurma katsayısı (k) ve dielektrik sabitinin gerçek (ε1) ve sanal (ε2) bileşenleri gibi optik parametreler hesaplandı. 550 nm dalga boyunda, n ve k değerleri sırasıyla 2,75 ve 0,00024 olarak bulunurken, bu değerlere karşılık gelen ε1 ve ε2 değerleri 7,570 ve 0,0013 olarak belirlendi. Ayrıca, farklı enerji seviyelerinde fotonların CuO NP’lerle etkileşimi FLUKA programı ile simüle edildi. Malzemedeki enerji birikimi, çalışılan malzemenin radyasyon zırhlama özelliklerini değerlendirmek için önemli bilgiler sağladı.

Abstract

Copper oxide nanoparticles (CuO NPs) were synthesized at 105 °C via a hydrothermal deposition technique. The CuO nanoparticle structure was characterized via X-ray diffraction (XRD) and scanning electron microscopy (SEM). The optical properties of the nanoparticles were examined via a UV‒vis spectrophotometer. For all the nanoparticles, the XRD measurements revealed the monoclinic CuO phase. The direct optical band and Urbach gap width of the nanoparticles were 2.88 eV and 0.44 eV, respectively. On the basis of optical measurements, optical parameters such as the refractive index (n), extinction coefficient (k), and real (ε1) and imaginary (ε2) components of the dielectric constant were calculated. At a wavelength of 550 nm, the optical constants n and k were found to be 2.75 and 0.00024, respectively, corresponding to dielectric real and imaginary constants of 7.570 and 0.0013. Additionally, photon interactions with CuO NPs at various energy levels were simulated via the FLUKA program. The energy deposition in the material provided valuable information for assessing the radiation shielding capabilities of the investigated material.

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Bu Makaleye Atıf Yap

Tekerek, S. (2025). Monte Carlo FLUKA Simülasyonları Kullanılarak Hidrotermal Olarak Sentezlenen CuO Nanopartiküllerinin Radyasyon Kalkanı Özelliklerinin Değerlendirilmesi. Karaelmas Fen ve Mühendislik Dergisi, Cilt: 15 Sayı: 3, 120–130. https://doi.org/10.7212/karaelmasfen.1752771

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Kaynakça (29)

  1. Agar, O., Sayyed, MI., Akman, F., Tekin, HO., Kaçal, MR. 2019. An extensive investigation on gamma ray shielding features of Pd/Ag-based alloys. Nuclear Engineering and Technology, 51(3), 853-859. https://doi.org/10.1016/j.net.2018.12.014
  2. Ali, AM., Issa, SA., Ahmed, MR., Saddeek, YB., Zaid, MHM., Sayed, M., Somaily, H. H., Tekin, HO., Sidek, HAA., Matori, KA., Zakaly, HM. 2020. Promising applicable heterometallic Al2O3/PbO2 nanoparticles in shielding properties. Journal of Materials Research and Technology, 9(6), 13956-13962. https://doi.org/10.1016/j.jmrt.2020.09.125
  3. Alzahrani, JS., Alrowaili, ZA., Sriwunkum, C., Al-Buriahi, MS. 2024. Radiation and nuclear shielding performance of tellurite glass system containing Li2O and MoO3: XCOM and FLUKA Monte Carlo. Journal of Radiation Research and Applied Sciences, 17(2), 100923. https://doi.org/10.1016/j.jrras.2024.100923
  4. Amri, A., Hasan, K., Taha, H., Rahman, MM., Herman, S., Awaltanova, E., Wantono, I., Kabir, H., Yin, CY., Ibrahim, K., Bahri, S., Frimayanti, N., Hossain, MA., Jiang, Z. T. 2019. Surface structural features and optical analysis of nanostructured Cu-oxide thin film coatings coated via the sol-gel dip coating method. Ceramics International, 45(10), 12888-12894. https://doi.org/10.1016/j.ceramint.2019.03.213
  5. Ballarini, F., Battistoni, G., Campanella, M., Carboni, M., Cerutti, F., Empl, A., Fassò, A., Ferrari, A., Gadioli, E., Garzelli, MV. 2006. The FLUKA code: an overview. In Journal of Physics: Conference Series, IOP Publishing, 41, 151–160. https://doi.org/10.1088/1742-6596/41/1/014
  6. Basith, NM., Vijaya, JJ., Kennedy, LJ., Bououdina, M. 2013. Structural, optical and room-temperature ferromagnetic properties of Fe-doped CuO nanostructures. Physica E: Low-dimensional Systems and Nanostructures, 53, 193-199. https://doi.org/10.1016/j.physe.2013.05.009
  7. Chen, Y., Zhang, L., Zhang, H., Zhong, K., Zhao, G., Chen, G., Lin Y, Chen S., Huang, Z. 2018. Band gap manipulation and physical properties of preferred orientation CuO thin films with nano wheatear array. Ceramics International, 44(1), 1134-1141. https://doi.org/10.1016/j.ceramint.2017.10.070
  8. Dridi, W., Alsulami, RA., Albarqi, MM., Alsufyani, SJ., Hosni, F. 2024. Radiation shielding features of Na2O–P2O5 glasses doped with MnO experimentally and using FLUKA and Phy-X. Journal of Radiation Research and Applied Sciences, 17(1), 100805. https://doi.org/10.1016/j.jrras.2023.100805
  9. El-Taher, A., Zakaly, HM., Allam, EA., El-Sharkawy, RM., Al Meshari, M., Soliman, A. M.,. Mahmoud, ME. 2025. Fluka and microshield simulation assessment of nuclear radiation attenuation by binary nanocomposites. Radiation Physics and Chemistry, 229, 112409. https://doi.org/10.1016/j.radphyschem.2024.112409
  10. Ferrari, A., Sala, PR., Fasso, A., Ranft, J. 2005. FLUKA: A Multi-Particle Transport Code. CERN-library, 55(99), 100. https://cds.cern.ch/record/898301
  11. Hubbell, JH. 1969. Photon Cross Sections, Attenuation Coefficients and Energy Absorption Coefficients from 10 keV to 100 GeV, Natl. Stand. Ref. Data Ser. 29.
  12. Hubbell, JH., Seltzer, SM. 2004. Cross section data for electron–positron pair production by photons: a status report. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 213, 1-9. https://doi.org/10.1016/S0168-583X(03)01524-6
  13. Mansy, MS., Lasheen, YF., Breky, MM., Selim, Y. 2021. Experimental and theoretical investigation of Pb–Sb alloys as a gamma-radiation shielding material. Radiation Physics and Chemistry, 183, 109416. https://doi.org/10.1016/j.radphyschem.2021.109416
  14. Meulepas, JM., Hauptmann, M., Lubin, JH., Shuryak, I., Brenner, DJ. 2018. Is there unmeasured indication bias in radiation-related cancer risk estimates from studies of computed tomography. Radiat. Res., 189(2), 128-135. https://doi.org/10.1667/RR14807.1
  15. Moss, TS., Burrell, GJ., Ellis, B. 1973. Semiconductor Opto-electronics. John Wiley & Sons, New York. Mullenders, L., Atkinson, M., Paretzke, H., Sabatier, L., Bouffler, S. 2009. Assessing cancer risks of low-dose radiation. Nat. Rev. Cancer., 9(8): 596–604. https://doi.org/10.1038/nrc2677
  16. Nandhakumar, E., Priya, P., Selvakumar, P., Vaishnavi, E., Sasikumar, A., Senthilkumar, N. 2019. One step hydrothermal green approach of CuO/Ag nanocomposites: Analysis of structural, biological activities. Mater. Res. Express., 6(9): 0950g4. https://doi.org/10.1088/2053-1591/ab2eb9
  17. Nitta, R., Kubota, Y., Kishi, T., Matsushita, N. 2022. Fabrication of nanostructured CuO NPs with controllable optical band gaps using a mist spin spray technique at 90 °C. Thin Solid Films, 762: 139555. https://doi.org/10.1016/j.tsf.2022.139555
  18. Perkowitz, S. 1993. Optical Characterizations of Semiconductors: Infrared, Raman, and Photoluminescence Spectroscopy. Academic Press, San Diego.
  19. Rai, RS. 2024. Carbon fiber fabrics functionalized with monoclinic CuO nanostructures using seed-assisted hydrothermal growth treatment. Ceram. Int. 50(21): 44635–44647. https://doi.org/10.1016/j.ceramint.2024.08.311
  20. Rehman, SU., Khan, S., Iqbal, Z., Bilal, M., Alkhybari, E., Alhailiy, A.,. Alotaibi, S. 2025. Simulation of shielding parameters of Gd–Pb binary alloys using FLUKA code and Phy-x/PSD platform. Radiation Physics and Chemistry, 230, 112582. https://doi.org/10.1016/j.radphyschem.2025.112582
  21. Sagadevan, S., Pal, K., Chowdhury, ZZ. 2017. Fabrication of CuO nanoparticles for structural, optical and dielectric analysis using chemical precipitation method. J. Mater. Sci. Mater. Electron., 28(17): 12591–12597. https://doi.org/10.1007/s10854-017-7083-3
  22. Sayyed, MI., Lakshminarayana, G., Dong, MG., Ersundu, MÇ., Ersundu, AE., Kityk, IV. 2018. Investigation on gamma and neutron radiation shielding parameters for BaO/SrO‒Bi2O3‒B2O3 glasses. Radiation Physics and Chemistry, 145, 26–33. https://doi.org/10.1016/j.radphyschem.2017.12.010
  23. Sayyed, MI., Rashad, M., Elsafi, M., Maghrbi, Y. 2025. The impact of CuO in modifying the radiation shielding performance of PbO–BaO–CaO–B2O3–CuO: An experimental approach. Radiation Physics and Chemistry, 226, 112271. https://doi.org/10.1016/j.radphyschem.2024.112271
  24. Stokes, AR., Wilson, AJC. 1944. The diffraction of X rays by distorted crystal aggregates-I. Proc. Phys. Soc., 56(3): 174.
  25. Şakar, E., Özpolat, ÖF., Alım, B., Sayyed, MI., Kurudirek, M. 2020. Phy-X/PSD: development of a user friendly online software for calculation of parameters relevant to radiation shielding and dosimetry. Radiation Physics and Chemistry, 166, 108496. https://doi.org/10.1016/j.radphyschem.2019.108496
  26. Tauc, J. 1974. Amorphous and Liquid Semiconductors. Plenum Press, New York.
  27. Wooten, F. 1972. Optical Properties of Solids. Academic Press, New York.
  28. El-Taher, A., Zakaly, HM., Allam, EA., El-Sharkawy, RM., Al Meshari, M., Soliman, A. M.,. Mahmoud, ME. 2025. Fluka and microshield simulation assessment of nuclear radiation attenuation by binary nanocomposites. Radiation Physics and Chemistry, 229, 112409. https://doi.org/10.1016/j.radphyschem.2024.112409
  29. Rehman, SU., Khan, S., Iqbal, Z., Bilal, M., Alkhybari, E., Alhailiy, A.,. Alotaibi, S. 2025. Simulation of shielding parameters of Gd–Pb binary alloys using FLUKA code and Phy-x/PSD platform. Radiation Physics and Chemistry, 230, 112582. https://doi.org/10.1016/j.radphyschem.2025.112582