Journals / Journal of New Results in Science / 2023 / Cilt: 12 Sayı: 2

A new colorimetric sensor based on semithiocarbazone for some anions: 2-(1,3-dioxo-1,3-dihydro-2H-inden-2-ylidene)-N-phenylhydrazine-1-carbothioamide

Pages
108–117
Publication Date
2023-08-31
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Finally, we evaluate the anion-sensing ability of the title compound via UV-vis spectroscopic studies.

📌 3 Key Takeaways

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Objective & Hypothesis:Carbazones are molecules containing important functional groups in designing anion chemosensors due to proton donor and acceptor sites in their structures.
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Key Findings & Data:In this paper, we synthesize a novel colorimetric receptor with 1,3-dioxo-indene and thiosemicarbazone moieties by the reaction of ninhydrin and 4-phenyl-thiosemicarbazide in quantitative yield.
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Conclusion & Impact:Finally, we evaluate the anion-sensing ability of the title compound via UV-vis spectroscopic studies.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:4-Phenylsemithiocarbazide · Ninhydrin · Anion receptor

Abstract

Carbazones are molecules containing important functional groups in designing anion chemosensors due to proton donor and acceptor sites in their structures. In this paper, we synthesize a novel colorimetric receptor with 1,3-dioxo-indene and thiosemicarbazone moieties by the reaction of ninhydrin and 4-phenyl-thiosemicarbazide in quantitative yield. We then identify its structure by means of FT-IR, $^{1}$H-NMR, $^{13}$C-NMR, and MS spectroscopic techniques. Moreover, we observe the reaction of the title compound with biologically important F$^¯$, OAc$^¯$, CN$^¯$, H2PO4$^¯$, and OH$^¯$ anions in the presence of other anions, such as Cl$^¯$, Br$^¯$, I$^¯$, SCN$^¯$, and OCl$^¯$ in dimethylsulfoxide solution through a color change from yellow to orange-red that can easily be distinguished even by the naked eye under ambient light. Finally, we evaluate the anion-sensing ability of the title compound via UV-vis spectroscopic studies.

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Cite This Article

AYDIN, F. (2023). A new colorimetric sensor based on semithiocarbazone for some anions: 2-(1,3-dioxo-1,3-dihydro-2H-inden-2-ylidene)-N-phenylhydrazine-1-carbothioamide. Journal of New Results in Science, Cilt: 12 Sayı: 2, 108–117. https://ajindex.com/articles/959578

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