Journals / Sakarya University Journal of Science / 2021 / Cilt: 25 Sayı: 4

Investigation of The Effects of Diaminopyridine and o-Vanillin Derivative Schiff Base Complexes of Mn(II), Mn(III), Co(II) and Zn(II) Metals on The Oxidative Bleaching Performance of H2O2

Pages
984–994
Publication Date
2021-08-30
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

According to the bleaching measurement results; the highest catalytic effect on the bleaching performance of H2O2 in pH 10.5 buffer at 25°C under homogeneous conditions was obtained with Co(II) complex, and it was understood that this complex was followed by Mn(II), Mn(III) and Zn(II) complexes, respectively

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Catalytic applications are widely used in both industrial and individual applications today due to their many advantages, especially the energy and time they provide.
📊
Key Findings & Data:For this purpose, many coordination compounds have been synthesized and their catalytic performances have been investigated in recent years.
💡
Conclusion & Impact:According to the bleaching measurement results; the highest catalytic effect on the bleaching performance of H2O2 in pH 10.5 buffer at 25°C under homogeneous conditions was obtained with Co(II) complex, and it was understood that this complex was followed by Mn(II), Mn(III) and Zn(II) complexes, respectively
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Schiff base · o-vanillin · metal complexes

Abstract

Catalytic applications are widely used in both industrial and individual applications today due to their many advantages, especially the energy and time they provide. For this purpose, many coordination compounds have been synthesized and their catalytic performances have been investigated in recent years. In this study, the Schiff base ligand, (N,N’-bis(2-hydroxy-3-methoxyphenylmethylidene)-2,6-pyridinediamine, BHMP), was synthesized with 2,6-diaminopyridine with o-vanillin. Mn(II), Mn(III), Co(II), Zn(II) complexes were obtained with the synthesized ligand. Spectroscopic methods such as FT-IR, 1H-NMR, UV-vis, Mass, and melting point determination methods were used for the structure elucidation of the synthesized compounds. The performances of the obtained complexes as bleach catalysts, which is an important application area of Schiff base complexes, were investigated. According to the bleaching measurement results; the highest catalytic effect on the bleaching performance of H2O2 in pH 10.5 buffer at 25°C under homogeneous conditions was obtained with Co(II) complex, and it was understood that this complex was followed by Mn(II), Mn(III) and Zn(II) complexes, respectively

🔖

Cite This Article

UĞUR, T., TUNA, M. (2021). Investigation of The Effects of Diaminopyridine and o-Vanillin Derivative Schiff Base Complexes of Mn(II), Mn(III), Co(II) and Zn(II) Metals on The Oxidative Bleaching Performance of H2O2. Sakarya University Journal of Science, Cilt: 25 Sayı: 4, 984–994. https://ajindex.com/articles/941779

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (1)

  1. REFERENCES [1] A.Sakthivel, K.Jeyasubramanian, B. Thangagiri and J. Dhaveethu, “Recent advances in schiff base metal complexes derived from 4-aminoantipyrine derivatives and their potential applications” Journal of Molecular Structure, vol. 1222, 128885, 2020. [2] B. Naureen, G.A.Miana, K. Shahid, M. Asghar, S. Tanveer and A. Sarwar, “Iron (III) and zinc (II) monodentate Schiff base metal complexes: Synthesis, characterisation and biological activities” Journal of Molecular Structure, vol. 1231, 129946, 2021. [3] N. Beyazit, D. Çakmak and C. Demetgül, “Chromone-based Schiff base metal complexes as catalysts for catechol oxidation: Synthesis, kinetics and electrochemical studies” Tetrahedron, vol. 73, no. 19, pp 2774-2779, 2017 [4] S. Sengupta, S. Khan, B. N. Mongal, W.Lewis, M. Fleck, S. K. Chattopadhyay and S. Naskar, “Electrocatalytic hydrogen production and carbon dioxide conversion by earth abundant transition metal complexes of the Schiff base ligand: (E)-1-((2-dimethylamino)-propylimino) methyl)naphthalene-2-ol” Polyhedron, vol. 191, Article ID 114798, 2020. [5] A. A. Alshaheri, M. I. M. Tahir, M. B. A. Rahman, T. B. S. A.Ravoof and T. A. Saleh, “Catalytic oxidation of cyclohexane using transition metal complexes of dithiocarbazate Schiff base” Chemical Engineering Journal, vol. 327, pp. 423-430, 2017. [6] B. Tamami and S. Ghasemi, “Catalytic activity of Schiff-base transition metal complexes supported on crosslinked polyacrylamides for hydrogen peroxide decomposition” Journal of Organometallic Chemistry, vol. 794, pp. 311-317, 2015. [7] S. Annapoorani and C. Krishnan, “Synthesis and spectroscopic studies of trinuclear N4 Schiff base complexes” International Journal of Chem Tech Research, vol. 5, no. 6, pp.180–185, 2013. [8] H. I. Ugras, I. Basaran, T. Kilic and U. Cakir, “Synthesis, complexation and antifungal, antibacterial activity studies of a new macrocyclic schiff base” Journal of Heterocyclic Chemistry, vol. 43, no. 6. pp.1679-1684, 2006. [9] L. Shi, H-M. Ge, Shu-H. Tan, H-Q. Li, Yong-C. Song and H-L. Zhu, “Synthesis and antimicrobial activities of Schiff bases derived from 5-chloro-salicylaldehyde” European Journal of Medicinal Chemistry, vol. 42, no. 4, pp. 558-564, 2007. [10] A. A. Osowole, A. C. Ekennia and B. O. Achugbu, “Synthesis, Spectroscopic Characterization and Antibacterial Properties of some Metal (II) Complexes of 2-(6-methoxybenzothiazol-2-ylimino) methyl)-4-nitrophenol” Research and Reviews: Journal of Pharmaceutical Analysis,