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Journals / Sigma Journal of Engineering and Natural Sciences / 2018 / Cilt: 36 Sayı: 2

SYNTHESIS, CHARACTERIZATION, SPECTRAL, AGGREGATION AND FLUORESCENCE AND IMPROVED PHOTOPHYSICAL PROPERTIES OF (ethylsulfanyl) PORPHYRAZINES CONTAINING β-THIOETHER APPENDED [(bpy)2RuCl2]

Fatma Aytan KILIÇARSLAN
Ali ERDOĞMUŞ
Sabiha MANAV YALÇIN
Ahmet GÜL
Pages
487–499
Publication Date
2018-06-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Insertion of (bpy)2RuII moiety on the porphyrazines structure have been investigated photophysical properties of the complexes.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, (ethylsulfanyl) porphyrazines have been modified with one peripheral ruthenium bipyridine groups.
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Key Findings & Data:These compounds possess (bpy)2RuII moieties directly attached to the β position in the (ethylsulfanyl) porphyrazines through thioether chelation.
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Conclusion & Impact:Insertion of (bpy)2RuII moiety on the porphyrazines structure have been investigated photophysical properties of the complexes.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Porphyrazines · bipyridine · ruthenium

Abstract

In this study, (ethylsulfanyl) porphyrazines have been modified with one peripheral ruthenium bipyridine groups. These compounds possess (bpy)2RuII moieties directly attached to the β position in the (ethylsulfanyl) porphyrazines through thioether chelation. The new compounds have been characterized by elemental analysis, FT-IR, 1H-NMR spectroscopy and mass spectra. The spectral properties such as electronic spectra, aggregation and fluorescence of compounds have been studied in THF. Insertion of (bpy)2RuII moiety on the porphyrazines structure have been investigated photophysical properties of the complexes.

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Cite This Article

KILIÇARSLAN, F. A., ERDOĞMUŞ, A., YALÇIN, S. M., GÜL, A. (2018). SYNTHESIS, CHARACTERIZATION, SPECTRAL, AGGREGATION AND FLUORESCENCE AND IMPROVED PHOTOPHYSICAL PROPERTIES OF (ethylsulfanyl) PORPHYRAZINES CONTAINING β-THIOETHER APPENDED [(bpy)2RuCl2]. Sigma Journal of Engineering and Natural Sciences, Cilt: 36 Sayı: 2, 487–499. https://ajindex.com/articles/897744

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