Journals / Sigma Mühendislik ve Fen Bilimleri Dergisi / 2017 / Cilt: 35 - Sayı: 1

SYNTHESIS, CHARACTERIZATION AND PHOTOPHYSICAL PROPERTIES OF EUROPIUM(III) PHTHALOCYANINES BEARING [4-(thiophen-3yl)-phenoxy]

Pages
23–34
Publication Date
2017-03-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The effects of the substituent and the nature of the europium on the photophysical parameters are also reported.

📌 3 Key Takeaways

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Objective & Hypothesis:In this study, two novel phthalonitriles (1,4) and their corresponding metal-free (2,5) and Eu(III) phthalocyanine derivatives (3,6) bearing 4-(thiophen-3yl)-phenoxy groups were synthesized.
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Key Findings & Data:These novel compounds were characterized by elemental analysis, FTIR, H NMR, UV-Vis, fluorescence, and mass spectroscopy.
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Conclusion & Impact:The effects of the substituent and the nature of the europium on the photophysical parameters are also reported.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Phthalocyanine · fluorescence · aggregation

Abstract

In this study, two novel phthalonitriles (1,4) and their corresponding metal-free (2,5) and Eu(III) phthalocyanine derivatives (3,6) bearing 4-(thiophen-3yl)-phenoxy groups were synthesized. These novel compounds were characterized by elemental analysis, FTIR, H NMR, UV-Vis, fluorescence, and mass spectroscopy. The aggregation behavior of these compounds was investigated in different solvents and concentrations. The effects of the substituent and the nature of the europium on the photophysical parameters are also reported.

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Cite This Article

KILIÇARSLAN, F. A., ERDEN, İ. (2017). SYNTHESIS, CHARACTERIZATION AND PHOTOPHYSICAL PROPERTIES OF EUROPIUM(III) PHTHALOCYANINES BEARING [4-(thiophen-3yl)-phenoxy]. Sigma Mühendislik ve Fen Bilimleri Dergisi, Cilt: 35 - Sayı: 1, 23–34. https://ajindex.com/articles/415158

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References (14)

  1. Andre J, Holczer K, Petit P, Riou M J, Clarisse C, Even R, Fourmigue M, and Simon J, “Electrical and magnetic properties of thin films and single crystals of bis(phthalocyaninato)lutetium” Chem. Phys. Lett. 115, 463-466, 1985
  2. De Cian A, Moussaui M, Fischer J, Weiss R, Inorganic Chem. “Synthesis, structure, and spectroscopic and magnetic properties of lutetium(III) phthalocyanine derivatives: LuPc2.CH2Cl2 and [LuPc(OAc)(H2O)2].H2O.2CH3OH”,24, 3162-3167,1985
  3. Pandoven A, Cozien Y, L’Her M, New J. Chem. 16, 711-718,1992
  4. Jiang J, Liu W, Poon K, Du D, Arnold D, Dennis KP, J. Inorg. Chem. “Synthesis, Spectroscopic, and Electrochemical Properties of Rare Earth Double Deckers with Tetra-(tertbutyl)-2,3-naphthalocyaninato Ligands”, 205-209, 2000
  5. Kobayashi N, Coord. Chem. Rev. “Optically active phthalocyanines”, 219, 99-123, 2001
  6. Toupance T, Bassoul P, Mineau L, Simon J, J. Phys. Chem. 100,1704-1713,1996
  7. Kobayashi N, Current Opinion in Solid State and Materials Science, “phthalocyanines”, 4, 345-353, 1999
  8. Ford WE, Rogers J, Schechtman L, Sounik JR, Inorganic Chem. Comm. 31, 3371-3376, 1992
  9. Ceyhan T, Altındal A, Özkaya A, Erbil MK, Bekaroğlu Ö, “Synthesis, characterization, and electrochemical, electrical and gas sensing properties of a novel tert-butylcalix[4]arene bridged bis double-decker lutetium(III) phthalocyanine” Polyhedron 26, 73-84, 2007
  10. Şen P, Dumludağ F, Salih B, Özkaya A, Bekaroğlu Ö, “Synthesis and electrochemical, electrochromic and electrical properties of novel s-triazine bridged trinuclear Zn(II), Cu(II) and Lu(III) and a tris double-decker Lu(III) phthalocyanines”, Synthetic Metals 161, 1245- 1254, 2011
  11. Bao G, Wang W, Mao Y, Lu F, “Raman spectroscopic characteristics of phthalocyanine in mixed [5-(4-hydroxyphenyl)-10,15,20- tris(4-octyloxyphenyl)porphyrinato]-(phthalocyaninato) rare earth triple-deckers”, Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy 102, 275-280, 2013
  12. Arıcı M, Bozoğlu C, Erdoğmuş A, Uğur AL, Koca A, “Electrochemical and spectroelectrochemical properties of novel lutetium(III) mono- and bis-phthalocyanines”, Elecrochimica Acta, 113, 668-678, 2013
  13. Iwatsu F, Kobayashi T, Uyeda N, “Solvent effects on crystal-growth and transformation of zinc phthalocyanine” J. Phys. Chem. 84, 3223-3230, 1980
  14. Erdogmus A, Koca A, Lütfi Ugur A, Erden I, “Synthesis, Electrochemical and Spectroelectrochemical Properties of Highly Soluble Tetra Substituted Phthaloc