Journals / Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering / 1995 / Cilt: 41

LIMITS ON THE PREDICTION OF ISOBARIC QUINARY PHASE EQUILIBRIA BY WILSON AND UNIQUAC EQUATIONS

Pages
1–1
Publication Date
1995-01-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Devications ranging from 0,0033- 0,0103 where as the Wilson equation could predict the quinary vapour phase with the accuracy of 0,0048-0,0104 R.M.S.D.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The isobaric separation of multicomponent mixtures by distillation require reliable vapour¬liquid equilibrium data.
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Key Findings & Data:Since the experimental determination of multicomponent vapour-liqu¬id equilibrium data is laborious and time consuming, there is a need to use a predictive method for the liquid-phase activity coefficients.
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Conclusion & Impact:Devications ranging from 0,0033- 0,0103 where as the Wilson equation could predict the quinary vapour phase with the accuracy of 0,0048-0,0104 R.M.S.D.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:ISOBARIC · EQUILIBRIA · UNIQUAC EQUATIONS

Abstract

The isobaric separation of multicomponent mixtures by distillation require reliable vapour¬liquid equilibrium data. Since the experimental determination of multicomponent vapour-liqu¬id equilibrium data is laborious and time consuming, there is a need to use a predictive method for the liquid-phase activity coefficients. The abilities of Wilso and UNIQUAC equationsto predict isobaric quinary vapour-liquid equilibria using only binary constants of both equations were compared in this paper. The quinary system under study, is n. Hexane / Methylcyclopen¬tane I Cyclohexane / Benzene / Toluene. UNIQUAC equation was found to be superior in the prediction of quinary vapour-liquid equilibria with the R.M.S. Devications ranging from 0,0033- 0,0103 where as the Wilson equation could predict the quinary vapour phase with the accuracy of 0,0048-0,0104 R.M.S.D.

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Cite This Article

ÖZALP, Ü. (1995). LIMITS ON THE PREDICTION OF ISOBARIC QUINARY PHASE EQUILIBRIA BY WILSON AND UNIQUAC EQUATIONS. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, Cilt: 41, 1–1. https://ajindex.com/articles/827520

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References (1)

  1. LIMITS ON THE PREDICTION OF ISOBARIC QUINARY PHASE EQUILIBRIA BY WILSON AND UNIQUAC EQUATIONS