Journals / NATURENGS / 2021 / Cilt: 2 - Sayı: 1

The Usage of Mg - Metal Chlorides in Hydrogen Generation

Journal
NATURENGS
Pages
60–73
Publication Date
2021-06-01
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

It has been observed that the use of acetic acid or citric acid solutions significantly enhances the amount of hydrogen formed. 4 hours milled Mg- 10wt% CoCl2 composite has the best hydrolysis properties for all experiments with its 138 ml of hydrogen generation at 30oC in 30 ml, 2 M citric acid solution.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:The reaction of metals with water is one of the hydrogen generation methods.
📊
Key Findings & Data:However, the emergence of Mg(OH)2, which interrupts hydrogen production in its reaction with water, has led to the search for new methods to improve the hydrogen production process.
💡
Conclusion & Impact:It has been observed that the use of acetic acid or citric acid solutions significantly enhances the amount of hydrogen formed. 4 hours milled Mg- 10wt% CoCl2 composite has the best hydrolysis properties for all experiments with its 138 ml of hydrogen generation at 30oC in 30 ml, 2 M citric acid solution.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Hydrogen Production · Mg- Metal chloride composites · Ball- milling

Abstract

The reaction of metals with water is one of the hydrogen generation methods. Mg stands out as a viable alternative when compared to other metals for producing hydrogen. However, the emergence of Mg(OH)2, which interrupts hydrogen production in its reaction with water, has led to the search for new methods to improve the hydrogen production process. For this reason, in our study, chloride salts (CoCl2 and AlCl3) have been used to improve hydrogen generation. The composites have been prepared with the addition of different chlorides (AlCl3 and CoCl2) into Mg with ball milling. AlCl3 and CoCl2 have been used separately and together while forming Mg metal composite powder. Powder mixtures have been grounded by a planetary ball mill at different times (2 and 4 hours). Deformations, which are thought to contribute positively to the reaction, have been obtained on the metal surface with ball milling. The microscopic images of the powder mixtures have been analyzed by SEM. In addition, distilled water, acetic acid and citric acid have been used in our study to observe the effects of hydrogen production. When distilled water has been used with powder mixtures in the hydrogen generation experiments, a minimal amount of hydrogen gas output has been observed. It has been observed that the use of acetic acid or citric acid solutions significantly enhances the amount of hydrogen formed. 4 hours milled Mg- 10wt% CoCl2 composite has the best hydrolysis properties for all experiments with its 138 ml of hydrogen generation at 30oC in 30 ml, 2 M citric acid solution.

🔖

Cite This Article

AYTAŞ, B. E., KARAOĞLU, S. Y. (2021). The Usage of Mg - Metal Chlorides in Hydrogen Generation. NATURENGS, Cilt: 2 - Sayı: 1, 60–73. https://ajindex.com/articles/793317

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (1)

  1. Referans1 Zhang, J., 2008, Hydrogen production by biomass gasification in supercritical water, Energeia, 19, 1-5. Referans2 Kaneko, H., Miura, T., Ishihara, H., Taku, S., Yokoyama, T., Nakajima, H., Tamaura, Y., 2007, Reactive ceramics of CeO2-MOx (M=Mn, Fe, Ni, Cu) for H2 generation by two-step water splitting using concentrated solar thermal energy. Energy, 32:656-663. Referans3 Fan, M.Q., Liu, S.S., Zhang, Y., Sun, L.X., Xu, F., 2010, Superior hydrogen storage properties of MgH2-10 wt% TiC composite., Energy, 35:3417-3421. Referans4 Yolcular, S., Karaoglu, S., 2017, Activation of Al powder with NaCl-assisted milling for hydrogen generation, Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 39(18):1919-1927. Referans5 Wang, M., Ouyang, L., Zeng, M., Liu, J., Peng, C., Shao, H., Zhu, M., 2019, Magnesium borohydride hydrolysis with kinetics controlled by ammoniate formation, International Journal of Hydrogen Energy, 44: 7392-7401. Referans6 Lalaurette, E., Thammannagowda, S., Mohagheghi, A., Maness, P.C. ve Logan, B.E., 2009, Hydrogen production from cellulose in a two-stage process combining fermentation and electrohydrogenesis, International Journal of Hydrogen Energy, 34:6201-6210. Referans7 Barbir, F., Ulgiati, S., 2008, Sustainable Energy Production and Consumption, Springer, Dordrecht, Holland, 372. Referans8 Yu, S.H., Uan, J.Y., Hsu, T.L., 2012, Effects of concentrations of NaCl and organic acid on generation of hydrogen from magnesium metal scrap, International Journal of Hydrogen Energy, 37:3033-3340. Referans9 Youssef, E.A., Nakhla, G. ve Charpentier, P.A., 2011, Oleic acid gasification over supported metal catalysts in supercritical water: hydrogen production and product distribution, International Journal of Hydrogen Energy, 36:4830-4842. Referans10 Uan, J.Y., Yu, S.H., Lin, M.C., Chen, L.F., Lin, H.I., 2009, Evolution of hydrogen from magnesium alloy scraps in citric acid-added seawater without catalyst, International Journal of Hydrogen Energy, 34:6137-6142. Referans11 Sun, Q., Zou, M., Guo, X., Yang, R., Huang, H., Huang, P., He, X., 2015, A study of hydrogen generation by reaction of an activated Mg–CoCl2 (magnesium–cobalt chloride) composite with pure water for portable applications, Energy, 79, 310-314. Referans12 Ouyang, L., Ma, M., Huang, M., Duan, R., Wang, H., Sun, L., Zhu, M., 2015, Enhanced Hydrogen Generation Properties of MgH2-Based Hydrides by Breaking the Magnesium Hydroxide Passivation Layer, Energies, 8: