Journals / Türk Doğa ve Fen Dergisi / 2022 / Cilt: 11 - Sayı: 3

Viscometric Investigation of Compatibilizer Effect on Polyvinyl chloride/Polystyrene Blends

Polivinilklorür/Polistiren Karışımlarına Uyumlaştırıcı Etkisinin Viskozimetrik İncelenmesi

Pages
171–177
Publication Date
2022-09-29
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

It was determined by viscometric method that the MAS copolymer was a good compatibilizer in the range where the polymer pair did not form a compatible blend.

📌 3 Key Takeaways

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Objective & Hypothesis:In this study, polyvinyl chloride (PVC) and polystyrene (PS) polymers, which do not form a compatible blend with each other in certain concentration ranges and are widely used on an industrial scale, were used.
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Key Findings & Data:The concentration range in which the polymer pair did not form a compatible blend was determined as 1.5 and 2.0 g dL-1.
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Conclusion & Impact:It was determined by viscometric method that the MAS copolymer was a good compatibilizer in the range where the polymer pair did not form a compatible blend.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:maleik anhidrit · polistiren · polivinilklorür

Abstract

In this study, polyvinyl chloride (PVC) and polystyrene (PS) polymers, which do not form a compatible blend with each other in certain concentration ranges and are widely used on an industrial scale, were used. The concentration range in which these two polymers do not form a compatible blend were determined viscometrically, and maleic anhydride-styrene (MAS) copolymer was added as a compatibilizing agent in this concentration range. The concentration range in which the polymer pair did not form a compatible blend was determined as 1.5 and 2.0 g dL-1. In this concentration range, 5.0 and 10.0 % MAS copolymer was added to the polymer couple and its compatibilizing effect was investigated. It was determined by viscometric method that the MAS copolymer was a good compatibilizer in the range where the polymer pair did not form a compatible blend.

Özet

Bu çalışmada belirli derişim aralıklarında birbirleriyle uyumlu karışım oluşturmayan ve endüstriyel ölçekte yaygın kullanıma sahip polivinilklorür (PVC) ve polistiren (PS) polimeleri kullanıldı. Bu iki polimerin uyumlu karışım oluşturmadığı derişim aralığı viskozimetrik yolla belirlenerek bu derişim aralığında maleik anhidrit-stiren (MAS) ko-polimeri uyumlaştırıcı ajan olarak eklendi. Polimer çiftinin uyumlu karışım oluşturmadığı derişim aralığı 1.5 ve 2.0 g dL-1 olarak saptandı. Bu derişim aralığında polimer çiftine % 5.0 ve 10.0 oranlarında MAS ko-polimeri eklenerek uyumlaştırıcı etkisi araştırıldı. Eklenen ko-polimerin PVC/PS polimer çifti için iyi bir uyumlaştırıcı olduğu belirlendi.

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Cite This Article

YILMAZ, E., BOZTUĞ, A. (2022). Viscometric Investigation of Compatibilizer Effect on Polyvinyl chloride/Polystyrene Blends. Türk Doğa ve Fen Dergisi, Cilt: 11 - Sayı: 3, 171–177. https://ajindex.com/articles/705684

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References (11)

  1. Jayakumar A., Radoor S., Radhakrishnan E.K., Nair I. C., Siengchin S., Parameswaranpillai J., 3 - Soy protein-based polymer blends and composites, Editor(s): Sanjay Mavinkere Rangappa, Jyotishkumar Parameswaranpillai, Suchart Siengchin, M. Ramesh, In Woodhead Publishing Series in Composites Science and Engineering, Biodegradable Polymers, Blends and Composites,Woodhead Publishing, 2022, Pages 39-57
  2. Sabzi F., Chapter 24 - Gas Transport Through Polymer Blends, Editor(s): Sabu Thomas, Runcy Wilson, Anil Kumar S., Soney C. George, Transport Properties of Polymeric Membranes, Elsevier, 2018, Pages 517-532, ISBN 9780128098844
  3. Yilmaz E. Compatibilization of polyvinyl chloride - polymethyl methacrylate polymer blends with maleic anhydride-styrene-methyl methacrylate terpolymer. J. Appl. Polym. Sci., 2022, 139(10), 51745
  4. Imren Koç D., Koç M. L. Fuzzy viscometric analysis of polymer-polymer miscibility based on fuzzy regression. Chemometrics and Intelligent Laboratory Systems, 2016, 157, 58-66
  5. Siskey R., Smelt H., Boon-Ceelen K., Persson M., 22 - UHMWPE Homocomposites and Fibers, Editor(s): Steven M. Kurtz, UHMWPE Biomaterials Handbook (Third Edition), William Andrew Publishing, 016, Pages 398-411, ISBN 9780323354011
  6. Biron M., 3 - Recycling: The First Source of Renewable Plastics, Editor(s): Michel Biron, In Plastics Design Library, Industrial Applications of Renewable Plastics, William Andrew Publishing, 2017, Pages 67-114, ISBN 9780323480659
  7. Huang JY. and Jiang WC. Effects of chemical composition and structure of unsaturated polyester resins on the miscibility, cured sample morphology and mechanical properties for styrene/unsaturated polyester/low-profile additive ternary systems. 1: Miscibility and cured sample morphology. Polymer, 1998, 39(25), 6631-6641
  8. Imren D., Boztug A., Basan S. Investigation Of Miscibility Of Poly(vinyl chloride) With Poly(ethylene-co-vinyl acetate) By Viscosimetric Method. Material Research Innovations, 2006, 10(2), xlvii-xlviii
  9. Bensemra NB., Bedda A., Belaabed A. Study of the properties of rigid and plasticized PVC/PMMA blends. Macromolecular Symposia, 2003, 202, 151-165
  10. Krache R., Benachour D., Pötschke P. Binary and ternary blends of polyethylene, polypropylene, and polyamide 6,6: The effect of compatibilization on the morphology and rheology. J. Appl Polym. Sci., 2004, 94 (5), 1976-1985
  11. Sivalingam G., Madras G. Thermal degradation of ternary blends of poly(ε-caprolactone)/poly(vi