SavedAdd your journal

Journals / Turkish Journal of Chemistry / 2018 / Cilt: 42 - Sayı: 2

Electrochemical polymerization of a new alkoxy-bridged dithieno (3,2-B:2’,3’-D) pyrrole derivative

Arif KIVRAK
Hüseyin Bekir YILDIZ
Selahattin GÖKYER
Buket BEZGİN ÇARBAŞ
Pages
439–447
Publication Date
2022-11-04
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The results showed that the polymer film exhibits multielectrochromic behavior and a low band gap of 1.82 eV.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:A novel alkoxy-bridged dithieno (3, 2-B:2’,3’-D) pyrrole (DTP) derivative was synthesized and its corresponding polymer poly(1,2-bis(2-(4H-dithieno[3,2-b:2’,3’-d]pyrrol-4-yl)ethoxy)ethane) (P(DTP-alkoxy-DTP)) was successfully obtained electrochemically.
📊
Key Findings & Data:The effects of alkoxy bridge in the structure on the electrochemical and spectroelectrochemical properties of the polymer were also investigated in detail.
💡
Conclusion & Impact:The results showed that the polymer film exhibits multielectrochromic behavior and a low band gap of 1.82 eV.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

A novel alkoxy-bridged dithieno (3, 2-B:2’,3’-D) pyrrole (DTP) derivative was synthesized and its corresponding polymer poly(1,2-bis(2-(4H-dithieno[3,2-b:2’,3’-d]pyrrol-4-yl)ethoxy)ethane) (P(DTP-alkoxy-DTP)) was successfully obtained electrochemically. The effects of alkoxy bridge in the structure on the electrochemical and spectroelectrochemical properties of the polymer were also investigated in detail. The results showed that the polymer film exhibits multielectrochromic behavior and a low band gap of 1.82 eV.

🔖

Cite This Article

KIVRAK, A., YILDIZ, H. B., GÖKYER, S., ÇARBAŞ, B. B. (2022). Electrochemical polymerization of a new alkoxy-bridged dithieno (3,2-B:2’,3’-D) pyrrole derivative. Turkish Journal of Chemistry, Cilt: 42 - Sayı: 2, 439–447. https://ajindex.com/articles/601991

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (23)

  1. Evenson, S. J.; Mimm, M. J.; Pohodya, K. I.; Rasmussen, S. C. Macromolecules 2011, 44, 835-841
  2. Balaji, G.; Phua, D. I.; Shim, W.; Valiyaveettil, S. Org. Lett. 2010, 12, 232-235
  3. Jeong, H. G.; Lim, B.; Na, S. I.; Baeg, K. J.; Kim, J.; Yun, J. M.; Kim, D. Y. Macromol. Chem. Phys. 2011, 212, 2308-2318
  4. Lu, Y.; Chen, H.; Hau, X.; Hu, X.; Ng, S. C. Synth. Met. 2010, 160, 1438-1441
  5. Schwendeman, I.; Hickman, R.; Sonmez, G.; Schottland, P.; Zong, K.; Welsh, D.; Reynolds, J. R. Chem. Mater. 2002, 14, 3118-3122
  6. Meng, H.; Tucker, D.; Chaffins, S.; Chen, Y.; Helgeson, R.; Dunn, B.; Wudl, F. Adv. Mater. 2003, 15, 146-149
  7. Nyström, G.; Razaq, A.; Stromme, M.; Nyholm, L.; Mihranyan, A. Nanoletters 2009, 9, 3635-3639
  8. Su, C.; Ye, Y.; Xu, L.; Zhang, C. J. Mater. Chem. 2012, 22, 22658-22662
  9. Cihaner, A. J. Electroanal. Chem. 2007, 605, 8-14
  10. Berlin, A.; Pagani, G.; Zotti, G.; Schiavon, G., Macromol. Chem. 1992, 193, 399-409
  11. Ogawa, K.; Stafford, J. A.; Rothstein, S. D.; Tallman, D. E.; Rasmussen, S. C. Synth. Met. 2005, 152, 137-140
  12. Koeckelberghs, G.; De Cremer, L.; Persoons, A.; Verbiest, T. Macromolecules 2007, 40, 4173-4181
  13. Vanormelingen, W.; Van den Bergh, K.; Koeckelberghs, G. Macromolecules 2008, 41, 5582-5589
  14. Liu, J.; Zhang, R.; Sauve, G.; Kowalewski, T.; McCullough, R. D. J. Am. Chem. Soc. 2008, 130, 13167-13176
  15. Mishra, S. P.; Palai, A. K.; Srivastava, R.; Kamalasanan, M. N.; Patri, M. J. Polym. Sci., Part A: Polym. Chem. 2009, 47, 6514-6525
  16. Zhou, E.; Nakamura, M.; Nishizawa, T.; Zhang, Y.; Wei, Q.; Tajima, K.; Yang, C.; Hashimoto, K. Macromolecules 2008, 41, 8302-8305
  17. Nakamura, M.; Yang, C.; Zhou, E.; Tajima, K.; Hashimoto, K. ACS Appl. Mater. Interfaces 2009, 1, 2703-2706
  18. Zhou, E.; Tajima, K.; Yang, C.; Hashimoto, K. J. Mater. Chem. 2010, 20, 2362-2368
  19. Zhang, S.; Guo, Y.; Fan, H.; Liu, Y.; Chen, H. Y.; Yang, G.; Zhan, X.; Liu, Y.; Li, Y.; Yang, Y. J. Polym. Sci., Part A: Polym. Chem. 2009, 47, 5498-5508
  20. Yue, W.; Zhao, Y.; Shao, S.; Tian, H.; Xie, Z.; Geng, Y.; Wang, F. J. Mater. Chem. 2009, 19, 2199-2206
  21. Zhan, X.; Tan, Z.; Zhou, E.; Li, Y.; Misra, R.; Grant, A.; Domercq, B.; Zhang, X. H.; An, Z.; Zhang, X.; et al. J. Mater. Chem. 2009, 19, 5794-5803
  22. Steckler, T. T.; Zhang, X.; Hwang, J.; Honeyager, R.; Ohira, S.; Zhang, X.; Grant, A.; Ellinger, S.; Odom, S. A.; Sweat, D.; et al. J. Am. Chem. Soc. 2009, 131, 2824-2826
  23. Parameswaran, M.; Balaji, G.; Jin, T.M.;Vijila, C.;