Then, it is investigated that the reactionbetween 2 and arylboronic acids give a new rearrangement reaction involving free radicals.Ferrocene structure displays critical roles for the formation of 2,3-diaryl-1,4-naphthoquinones.This reaction could be first example for the radical C-C bond cleavage reactions includingferrocene.
📌 3 Key Takeaways
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Objective & Hypothesis:In general, Suzuki-Miyaura coupling reaction between aryl bromide and arylboronic acids formthe new C-C bond in the presence of Pd-catalyst.
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Key Findings & Data:In the present study, 2-bromo-3-ferrocenyl1,4-naphthoquinone 2 intermediate is synthesized by starting from 2,3-dibromo-1,4-naphthoquinone via Suzuki-Miyaura Coupling reaction.
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Conclusion & Impact:Then, it is investigated that the reactionbetween 2 and arylboronic acids give a new rearrangement reaction involving free radicals.Ferrocene structure displays critical roles for the formation of 2,3-diaryl-1,4-naphthoquinones.This reaction could be first example for the radical C-C bond cleavage reactions includingferrocene.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters
Abstract
In general, Suzuki-Miyaura coupling reaction between aryl bromide and arylboronic acids formthe new C-C bond in the presence of Pd-catalyst. In the present study, 2-bromo-3-ferrocenyl1,4-naphthoquinone 2 intermediate is synthesized by starting from 2,3-dibromo-1,4-naphthoquinone via Suzuki-Miyaura Coupling reaction. Then, it is investigated that the reactionbetween 2 and arylboronic acids give a new rearrangement reaction involving free radicals.Ferrocene structure displays critical roles for the formation of 2,3-diaryl-1,4-naphthoquinones.This reaction could be first example for the radical C-C bond cleavage reactions includingferrocene.
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Cite This Article
Kivrak, A., Ertas, N. A. (2022). Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. Manas Journal of Engineering, Cilt: 8 - Sayı: 1, 22–27. https://ajindex.com/articles/578027
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