Journals / Turkish Journal of Chemistry / 2017 / Cilt: 41 - Sayı: 3

Dehydration behavior and kinetics of kurnakovite under microwave irradiation

Pages
399–409
Publication Date
2022-11-05
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

According to the results, kurnakovite was identified as a compound with the powder diffraction file (pdf) number 00-024-0700 before the dehydration process and after the dehydration process amorphous formations were observed.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this research, the dehydration behavior of kurnakovite was studied under microwave irradiation.
📊
Key Findings & Data:According to the results, kurnakovite was identified as a compound with the powder diffraction file (pdf) number 00-024-0700 before the dehydration process and after the dehydration process amorphous formations were observed.
💡
Conclusion & Impact:For the activation energy calculation, the Page model best fits the experimental data and was found as 9.92 W × g −1.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

In this research, the dehydration behavior of kurnakovite was studied under microwave irradiation. The kinetic parameters of the dehydration reaction were determined using different kinetic models. Kurnakovite was characterized by the techniques of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscopy (SEM) before and after the dehydration process. According to the results, kurnakovite was identified as a compound with the powder diffraction file (pdf) number 00-024-0700 before the dehydration process and after the dehydration process amorphous formations were observed. Moreover, FT-IR results showed that dehydration was completed successfully because of the disappearance in the band values of structural water. The dehydration process was ended at 25, 20, and 15 min for the power levels of 360, 600, and 800 W, respectively. Among the models, the two-term exponential model best fits the drying experimental data. For the activation energy calculation, the Page model best fits the experimental data and was found as 9.92 W × g −1.

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Cite This Article

ŞENBERBER, F. T., DERUN, E., KIPÇAK, A. S., YILDIRIM, M., ÖZDOĞAN, İ. N. (2022). Dehydration behavior and kinetics of kurnakovite under microwave irradiation. Turkish Journal of Chemistry, Cilt: 41 - Sayı: 3, 399–409. https://ajindex.com/articles/601863

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References (26)

  1. Beatty, R. Boron; Marshall Cavendish Corporation: Tarrytown, NY, USA, 2006
  2. Garrett, D. E. Borates: Handbook of Deposits, Processing, Properties, and Use; Academic Press: London, UK, 1998
  3. Derun, E. M.; Kipcak, A. S. J. Radioanal. Nucl. Chem. 2012, 292, 871-878
  4. Zhou, B.; Michaelis, V. K.; Pan, Y.; Yao, Y.; Tait, K. T.; Hyde, B. C.; Wren, J. E. C.; Sherriff, B. L.; Kroeker, S. Am. Mineral. 2012, 97, 1858-1865
  5. Abdullaev, G. K.; Abbasov, B. E.; Rza-Zade, P. F. Issled. Obl. Neorg. Fiz. Khim. 1971, 147-52
  6. Frost, R. L.; Lopez, A.; Xi, Y., Lima, R. M. F.; Scholz, R.; Granja, A. Spectrochim. Acta Mol. Biomol. Spectrosc. 2013, 116, 160-164
  7. Gabriel, C.; Gabriel, S.; Grant, E.; Halstead, B.; Mingos, D. Chem. Soc. Rev. 1998, 27, 213-223
  8. Adnadjevic, B.; Jovanovic, J. In Advances in Induction and Microwave Heating of Mineral and Organic Materials; Grundas, S., Ed. Intech: Croatia, 2011, pp. 392-420
  9. Loupy, A. Microwave in Organic Synthesis; Wiley–VCH: Weinheim, Germany, 2002
  10. Kipcak, A. S.; Derun, E. M.; Piskin, S. J. Chem. 2013, Article ID 329238, 1-6
  11. Bogdal, D.; Prociak, A. Microwave-Enhanced of Polymer Chemistry and Technology; Blackwell Pub: Oxford, UK, 2007
  12. Perelaer, J.; de Gans, B.; Schubert, U. Adv. Mater. 2006, 18, 2101-2104
  13. Tsuji, M.; Hashimoto, Y.; Nishizawa, Y.; Kubokawa, M.; Tsuji, T. Chem. Eur. J. 2005, 1, 440-452
  14. Li, J.; Jin, Y. L.; Zhang, X. G.; Yang, H. Solid State Ionics 2007, 178, 1590-1594
  15. Elander, N.; Jones, J.; Lu, S.; Stone-Elander, S. Chem. Soc. Rev. 2000, 29, 239-249
  16. Shipe, W.; Wolkenberg, S.; Linfsley, C. Nature Rev. Drug Discov. Today Technol. 2005, 2, 155-161
  17. Collins, J.; Leadbeater, N. Org. Biomol. Chem. 2007, 5, 1141-1150
  18. N¨uchten, M.; Ondruschka, B.; Bonrath, W.; Gum, A. Green Chem. 2004, 6, 128-141
  19. Vanderah, T. Science, 2002, 298, 1182-1184
  20. Li, Y.; Lei, Y.; Zhang, L.; Peng, J.; Li, C. Trans. Nonferrous Met. Soc. China, 2011, 21, 202-207
  21. Roussy, G.; Zoulalian A.; Charreyre, M.; Thiebaut J. J. Phys. Chem. 1984, 88, 5702-5708
  22. Saito, Y.; Kawahira, K.; Yoshikawa, N.; Todoroki, H.; Taniguch, S. ISIJ Int. 2011, 51, 878-883
  23. Eymir, C¸.; Okur, H. Thermochim. Acta 2005, 428, 125-129
  24. Kocakusak, S.; Koroglu, H. J.; Tolun, R. Chem. Eng. Process. 1998, 37, 197-201
  25. Kocakusak, S.; Koroglu H. J.; Gozmen, T.; Savascı, O. T.; Tolun R. Ind. Eng. Chem. Res. 1996, 35, 159-163
  26. Ozdogan, I. N.; Aksoy, Y. T.; Senberber, F. T., Kipcak, A. S.; Piskin, M