Journals / Hacettepe Journal of Biology and Chemistry / 2012 / Cilt: 40 - Sayı: 3

Poly(ma-alt-nvp) kopolimerinin çözünürlük profili-vizkozite davranışına grafiksel ve matematiksel olarak açıklık getirilmesi

The mathematical and graphical ınterpretation of solubility profile-viscosity behavior of poly(ma-alt-nvp)

Pages
239–250
Publication Date
2022-10-17
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Spectral characterization of that copolymer is achieved by FTIR, 1H, 13C NMR spectroscopic methods whereas the polymer hydrodynamic behavior of the copolymer is investigated by viscometric method for comparison purpose with that obtained from the solubility profile through algorithmic calculations.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Alternating copolymer of maleic anhydride (MA) with N-vinyl-2-pyrrolidone (NVP) is synthesized by free radical polymerization reaction.
📊
Key Findings & Data:Solubility of the copolymer in certain solvents is investigated by different algorithmic approaches such as Van Krevelen Hoftyzer (VKH), Hoy and Askadskii.
💡
Conclusion & Impact:Spectral characterization of that copolymer is achieved by FTIR, 1H, 13C NMR spectroscopic methods whereas the polymer hydrodynamic behavior of the copolymer is investigated by viscometric method for comparison purpose with that obtained from the solubility profile through algorithmic calculations.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

Alternating copolymer of maleic anhydride (MA) with N-vinyl-2-pyrrolidone (NVP) is synthesized by free radical polymerization reaction. Solubility of the copolymer in certain solvents is investigated by different algorithmic approaches such as Van Krevelen Hoftyzer (VKH), Hoy and Askadskii. Spectral characterization of that copolymer is achieved by FTIR, 1H, 13C NMR spectroscopic methods whereas the polymer hydrodynamic behavior of the copolymer is investigated by viscometric method for comparison purpose with that obtained from the solubility profile through algorithmic calculations.

Özet

Maleik anhidritin (MA) N-vinil-2-pirolidon (NVP) ile ardışık kopolimeri serbest radikal kopolimerleşme reaksiyonu ile sentezlendi. Kopolimerin çeşitli çözücülerdeki çözünürlüğü, Van Krevelen Hoftyzer (VKH), Hoy ve Askadskii gibi değişik algoritmik yaklaşımlarla irdelendi. Kopolimerin spektral karakterizasyonu, FTIR, 1H, 13C NMR gibi spektroskopik yöntemlerle gerçekleştirilirken, polimer hidrodinamik davranışı ise algoritmik hesaplamalar yoluyla elde edilen çözünürlük profili verilerinin vizkometrik metod kullanılarak elde edilen verilerle karşılaştırılmasıyla araştırıldı.

🔖

Cite This Article

BOZDOĞAN, D. D., KİBARER, G., GÜNER, A., RZAYEV, Z. M. O. (2022). Poly(ma-alt-nvp) kopolimerinin çözünürlük profili-vizkozite davranışına grafiksel ve matematiksel olarak açıklık getirilmesi. Hacettepe Journal of Biology and Chemistry, Cilt: 40 - Sayı: 3, 239–250. https://ajindex.com/articles/529191

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (20)

  1. L-S. Wan, Z-K. Xu, X-J. Huang, Z-G.Wang, J-L. Wang, Copolymerization of acrylonitrile with N-vinyl- 2-pyrrolidone to improve the hemocompatibility of polyacrylonitrile, Polymer, 46 (2005) 7715
  2. R. Duncan, J. Kopecek, Soluble synthetic polymers as potential drug carriers, Adv. Polym. Sci., 57 (1984) 51
  3. M. Şen, O. Kantoğlu, O. Güven, The effect of external stimuli on the equilibrium swelling properties of poly(N-vinyl 2-pyrrolidone/itaconic acid) poly- electrolyte hydrogels, Polymer, 40 (1999) 913
  4. RC. Weast, Handbook of Chemistry and Physics, 53rd Edition., The Chemical Rubber Co. Ohio, 1972
  5. H.W. Kang, Y. Tabata, T. Ikada, Fabrication of porous gelatin scaffolds for tissue engineering, Biomaterials, 20 (1999) 1339
  6. L. Veron, MCD. Bignicourt, T. Delair, C. Pichot, B. Mandrand, Synthesis of poly[N-(2,2- dimethoxyethyl)-N-methyl acrylamide] for the immobilization of oligonucleotides, J. Appl. Polym. Sci., 60 (1996) 235
  7. ZMO. Rzaev, Polymers and copolymers of maleic anhydride, Chem. Abstr., Baku: Elm., 102:114108w, 1985
  8. ZMO. Rzaev, Complex-radical alternating copoly merization, Prog. Polym. Sci., 25 (2000), 163
  9. VA. Kabanov, VP. Zubov, YuD. Semchikov, Complex radical polymerization, Moscow: Nauka, 1987
  10. BC. Trivedi, BM. Culberston, Maleic anhydride. New York: Plenum Pres, 1982
  11. AD. Tomalia, Functional monomers, 2. New York: Marcel Dekker, 1974
  12. CM. Hansen, The three dimensional solubility parameter-key to paint component affinities. II. Solvents, plasticizers, polymers and resins, J. Paint Technol., 39, (1967) 104, 509
  13. AFM. Barton, CRC Handbook of solubility parameters and other cohesion parameters, CRC Press: Boca Raton FL, 1983
  14. AFM., Barton Applications of solubility parameters and other cohesion parameters in polymer science and technology, Pure Appl. Chem., 57 (1985) 905-912
  15. CM. Hansen, Hansen solubility parameter, A user’s Handbook, Boca Raton FL: CRC Press, 1999
  16. CM. Hansen, Aspects of solubility, surfaces and diffusion in polymers, Prog. Org. Coat, 51 (2004) 55
  17. MA Bustamante, JB. Pena, Partial solubility parameters of piroxicam and niflumic acid, Int. J. Pharm., 174, (1998) 141
  18. DW. Van Krevelen, Properties of polymers, Amsterdam: Elsevier Science, 1997
  19. DW. Van Krevelen, PJ. Hoftyzer, Properties of polymers: Their estimation and correlation with chemical structure, 2nd Edition, Amsterdam: Elsevier, 1976
  20. KL. Hoy, Solubility parameter as a design parameter for water borne pol