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Journals / Hacettepe Journal of Biology and Chemistry / 2019 / Cilt: 47 - Sayı: 1

Vibrational Spectroscopic Study on the Hofmann-Td-type 1,4-Dioxane Clathrates

Hofmann-Td–tipi Dioksan Klatratlarının Titreşim Spektroskopisi ile İncelenmesi

Celal BAYRAK
Pages
99–106
Publication Date
2022-10-17
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The spectral data suggest that the host frameworks of thesecompounds are similar to those of the Hofmann-Td-type benzene clathrates.

📌 3 Key Takeaways

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Objective & Hypothesis:Two new 1,4-dioxane-Td-type clathrates of the form Cd(CPA)2M${left(CNright)}_4$.2${left(CNright)}_4$$2C_4H_8O_2$ (CPA= cyclopentylamine; M = Cd or Hg) havebeen prepared in powder form and their FT-IR (400-4000 cm-1), FT-Raman (70-4000 cm-1), far-IR (50-400 cm-1) spectra,X-ray diffraction (XRD) and elemental analyses are reported.
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Key Findings & Data:Two new 1,4-dioxane-Td-type clathrates of the form Cd(CPA)2M${left(CNright)}_4$.2${left(CNright)}_4$$2C_4H_8O_2$ (CPA= cyclopentylamine; M = Cd or Hg) havebeen prepared in powder form and their FT-IR (400-4000 cm-1), FT-Raman (70-4000 cm-1), far-IR (50-400 cm-1) spectra,X-ray diffraction (XRD) and elemental analyses are reported.
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Conclusion & Impact:The spectral data suggest that the host frameworks of thesecompounds are similar to those of the Hofmann-Td-type benzene clathrates.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

Two new 1,4-dioxane-Td-type clathrates of the form Cd(CPA)2M${left(CNright)}_4$.2${left(CNright)}_4$$2C_4H_8O_2$ (CPA= cyclopentylamine; M = Cd or Hg) havebeen prepared in powder form and their FT-IR (400-4000 cm-1), FT-Raman (70-4000 cm-1), far-IR (50-400 cm-1) spectra,X-ray diffraction (XRD) and elemental analyses are reported. The spectral data suggest that the host frameworks of thesecompounds are similar to those of the Hofmann-Td-type benzene clathrates.

Özet

Toz formunda Cd(CPA)2M${left(CNright)}_4$ .$2C_4H_8O_2$(CPA=siklopentilamin;M=Cd veya Hg) şeklindeki iki yeni 1,4-dioksan-Td tipi klatrat hazırlanmış ve bunların FT-IR (400-4000 cm-1), FT-Raman (70-4000 cm-1), uzak-IR (50-400 cm-1) spektrumları, X-ışınımı kırınım dağılımı (XRD) ve elemental analizleri rapor edilmiştir. Spektral veriler, bu bileşiklerin konuk yapılarının Hofmann-Td tipi benzen klatratları ile benzer olduğunu ileri sürmektedir.

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Cite This Article

BAYRAK, C. (2022). Vibrational Spectroscopic Study on the Hofmann-Td-type 1,4-Dioxane Clathrates. Hacettepe Journal of Biology and Chemistry, Cilt: 47 - Sayı: 1, 99–106. https://ajindex.com/articles/529021

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