Journals / Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji / 2019 / Cilt: 7 - Sayı: 3

The Effect of Additives on Structural and Magnetic Properties of CoNi Alloy Thin Film Coatings Produced by Electrodeposition

Elektrodepolama ile Üretilen CoNi Alaşım İnce Film Kaplamaların Yapısal ve Manyetik Özellikleri Üzerine Ek Katkı Maddelerinin Etkisi

Pages
661–675
Publication Date
2022-10-18
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

CoNi alloy thin film coating produced without additional additive; It was found that the crystal structure was face centered cubic (fcc) and the cobalt content of the coating was 67.94%.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Electrodeposition of metals and alloys may contain one or more organic or inorganic additives.
📊
Key Findings & Data:CoNi alloy thin film coating produced without additional additive; It was found that the crystal structure was face centered cubic (fcc) and the cobalt content of the coating was 67.94%.
💡
Conclusion & Impact:It was seen that the additives had a great effect on the amount of matter, crystal structure and magnetic properties in the alloy film.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Ek katkılar · Kumarin ve tiyoüre · Kobalt-nikel

Abstract

Electrodeposition of metals and alloys may contain one or more organic or inorganic additives. Additives it affects the surface morphology, grainsize and crystal structure of the thin film coatings. In this study, CoNi alloy thin film coatings were produced by electrodeposition without additives and using additional additives (organic coumarin and thiourea). CoNi alloy thin film coating produced without additional additive; It was found that the crystal structure was face centered cubic (fcc) and the cobalt content of the coating was 67.94%. When coumarin was added to the bath composition, cobalt in the film content decreased to 43.82%, decreased to 34.33% when thiourea was added, and both films showed amorphous properties. The magnetic field applied was changed between -75000 Oe to +75000 Oe, magnetization values were measured and hysteresis curves were obtained. It was seen that the additives had a great effect on the amount of matter, crystal structure and magnetic properties in the alloy film.

Özet

Metallerin ve alaşımların elektrodepolanması bir veya daha fazla organik veya inorganik ek katkı maddeleri içerebilir. Ek katkılar; depolanan ince film kaplamaların yüzey morfolojisine, tane büyüklüğüne ve kristal yapısına etki etmektedir. Bu çalışmada CoNi alaşım ince film kaplamalar, katkı madde olmadan ve ek katkı maddeleri (organik kumarin ve tiyoüre) kullanılarak elektrodepolamayla üretildi. Ek katkısız depolanan CoNi alaşım ince film kaplamanın; kristal yapısının yüzey merkezli kübik (fcc) ve kaplama içeriğindeki kobalt miktarının % 67.94 olduğu bulundu. Banyo kompozisyonuna, kumarin katıldığında film içeriğindeki kobaltın % 43.82’ye, tiyoüre katıldığında %34.33’e düştüğü ve her iki filmin amorf özellik gösterdiği belirlendi. Uygulanan manyetik alan, -75000 Oe ile +75000 Oe arasında değiştirilerek, manyetizasyon değerleri ölçüldü ve histerezis eğrileri elde edildi. Katkı maddelerinin alaşım film içerisindeki madde miktarına, kristal yapıya ve manyetik özelliklere büyük etki ettiği görüldü.

🔖

Cite This Article

ÖZDEMİR, R. (2022). The Effect of Additives on Structural and Magnetic Properties of CoNi Alloy Thin Film Coatings Produced by Electrodeposition. Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji, Cilt: 7 - Sayı: 3, 661–675. https://ajindex.com/articles/522032

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (12)

  1. F.Z. Bouzit, A. Nemamcha, H. Moumeni, J.L. Rehspringer, “Morphology and Rietveld analysis of nano structured Co-Ni electrodeposited thin films obtained at different current densities,” Surface & Coatings Technology, vol.315, pp. 172-180, 2017
  2. L. Wang, X. Lu, Y. Ye, L. Sun, Y. Song, “Nickel-cobalt nanostructures coated reduced graphene oxide nano composite electrode for nonenzymatic glucose,” Electrochimica Acta, vol.114, pp. 484-493, 2013
  3. X. Sun, Q. Yuan, D. Fang, H. Zhang, “Electrodeposition and characterization of CoNiMnP permanent magnet arrays for MEMS sensors and actuators,” Sensors and Actuators A, vol. 188, pp. 190-197, 2012
  4. C. Xu, D. Nie, H. Chen, Y. Wang, Y. Liu, “Template-free synthesis of magnetic CoNi nanoparticles via a solvo thermal method,” Materials Letters, vol 138, pp. 158–161, 2015
  5. A. Karpuz, H. Kockar, M. Alper, “The effect of different chemical compositions caused by the variation of deposition potential on properties of Ni–Co films,” Applied Surface Science, vol. 257, pp. 3632–3635, 2011
  6. F. Noori, A. Ramazani, M.A. Kashi, “Controlling structural and magnetic properties in CoNi and CoNiFe nanowire arrays by fine-tuning of Fe content,” Journal of Alloys and Compounds, vol. 756, pp. 193–201, 2018
  7. N.S. Nguyen, G. Das, H.H. Yoon, “Nickel/cobalt oxide-decorated 3D graphene nano composite electrode for enhanced electrochemical detection of urea,” Biosensors and Bioelectronics, vol. 77, pp. 372–377, 2016
  8. W. Yan, D. Wang, G.G. Botte, “Nickel and cobalt bimetallic hydroxide catalysts for urea electro-oxidation,” Electrochimica Acta, vol. 61, pp. 25–30, 2012
  9. D. Kim, R. Shanmugam, M.R. Choi, B. Yoo, “Formation of CoNi alloy thin films on silicon by electroless deposition,” Electrochimica Acta, vol. 75, pp. 42–48, 2012
  10. J S. Temel, M. Nebi, D. Peker, Sol-gel döndürerek kaplama tekniği ile saydam iletken ZnO ince filmlerin üretilmesi ve karakterizasyonu, Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım Ve Teknoloji, 5(3): p. 51-59, 2017
  11. R. Özdemir, C.A. Korkmaz, İ.H. Karahan, “Investigation of the structural and magnetic properties of the cobalt-nickel alloys fabricated in various electrolyte solutions,” Acta Physica Polonica A, vol. 132 (3), pp. 1045–1049, 2017
  12. S. Yıldırım, Sol-Gel Döner Kaplama Yöntemiyle Oluşturulmuş Ta2O5 İnce Film Kondansatörün Düşük Sıcaklık Bölgesi Dielektrik Özellikleri ve AC İletkenlik Davranışı, Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım Ve T