Journals / Anadolu Üniversitesi Fen Fakültesi Dergisi / 2001 / Cilt: 0 - Sayı: 5

M $(DMA)_{2}$ Cd $(CN)_{4}$ (M=Ni, Co) Hofmann-Td-tipi komplekslerin kırmızı- altı spektroskopisiyle incelenmesi

Infrared spectroscopic studies on the Hofmann-Td-type complexes: M $(DMA)_{2}$ Cd $(CN)_{4}$ (M=Ni, Co)

Pages
61–70
Publication Date
2022-10-11
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The results of an Infrared spectroscopic study are presented for two new Hofmann-Td-type complexes M$(dimetilasetamid)_{2}$ Cd$(CN)_{4}$ (M=Ni, Co) .These structures consists of- M-$L_{2}$-M-$L_{2}$-(M=Ni, Co) inifinite chains along the a and b axis and the tetrahedral Cd$(CN)_{4}^{2-}$ ions are arranged in between two M atoms via the N-ends in the chains.

📌 3 Key Takeaways

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Objective & Hypothesis:The results of an Infrared spectroscopic study are presented for two new Hofmann-Td-type complexes M$(dimetilasetamid)_{2}$ Cd$(CN)_{4}$ (M=Ni, Co) .These structures consists of- M-$L_{2}$-M-$L_{2}$-(M=Ni, Co) inifinite chains along the a and b axis and the tetrahedral Cd$(CN)_{4}^{2-}$ ions are arranged in between two M atoms via the N-ends in the chains.
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Key Findings & Data:The results of an Infrared spectroscopic study are presented for two new Hofmann-Td-type complexes M$(dimetilasetamid)_{2}$ Cd$(CN)_{4}$ (M=Ni, Co) .These structures consists of- M-$L_{2}$-M-$L_{2}$-(M=Ni, Co) inifinite chains along the a and b axis and the tetrahedral Cd$(CN)_{4}^{2-}$ ions are arranged in between two M atoms via the N-ends in the chains.
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Conclusion & Impact:The results of an Infrared spectroscopic study are presented for two new Hofmann-Td-type complexes M$(dimetilasetamid)_{2}$ Cd$(CN)_{4}$ (M=Ni, Co) .These structures consists of- M-$L_{2}$-M-$L_{2}$-(M=Ni, Co) inifinite chains along the a and b axis and the tetrahedral Cd$(CN)_{4}^{2-}$ ions are arranged in between two M atoms via the N-ends in the chains.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

The results of an Infrared spectroscopic study are presented for two new Hofmann-Td-type complexes M$(dimetilasetamid)_{2}$ Cd$(CN)_{4}$ (M=Ni, Co) .These structures consists of- M-$L_{2}$-M-$L_{2}$-(M=Ni, Co) inifinite chains along the a and b axis and the tetrahedral Cd$(CN)_{4}^{2-}$ ions are arranged in between two M atoms via the N-ends in the chains.

Özet

Bu çalışmada ilk kez elde edilen iki yeni Hofmann-Td tipi M$(dimetilasetamid)_{2}$ Cd$(CN)_{4}$ (M=Ni, Co) komplekslerinin kırmızı-altı spektroskopik çalışmalarının sonuçları sunulmuştur.Bu komplekslerin yapılarında sonsuz uzun M-$L_{2}$-M-$L_{2}$-(M=Ni, Co) zincirleri bulunmakta ve tetrahedral Cd$(CN)_{4}^{2-}$ iyonları iki metal atomunun arasında azot ucundan bağlı olarak zinciri tamamlamaktadır.

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Cite This Article

ŞENYEL, M., KÜRKÇÜOĞLU, G. S. (2022). M $(DMA)_{2}$ Cd $(CN)_{4}$ (M=Ni, Co) Hofmann-Td-tipi komplekslerin kırmızı- altı spektroskopisiyle incelenmesi. Anadolu Üniversitesi Fen Fakültesi Dergisi, Cilt: 0 - Sayı: 5, 61–70. https://ajindex.com/articles/438643

References (14)

  1. T.Iwamoto, M.Kiyoki and N.Matsuura,Cyclohexadienyl radicals in y-irradiated catena ethylenediaminecadxnium(II) catena-j^-cyanomercurate(II)-benzene(l/2) and the analogous clathrates, Bull. Chem. Soc. Jpn., 51 (1978) 390
  2. R.Kuroda, Inorg. Nucl. Chem. Lett.,Metal ammine cyanide aromatic clathrates.XV.New type clathrate compound.Crystal structure of Cd(NH3)2Hg(CN)4.2C6H6, 9 (1973) 13
  3. T.Iwamoto, M.Kiyoki, Y.Ohtsu and Y.Takeshige-Kato,The analogous of Hofinann type clathrate formed between diammine or diamminemetal(II) tetracyanometallate(II) host and aromatic guest molecule, Bull. Chem. Soc. Jpn., 51 (1978) 488
  4. T.Iwamoto,Recent Developments in the Chemistry of Hofinann Type and the Analogous Clathrates, J. Mol. Structure, 75 (1981) 51
  5. Z.Kantarci,Infrared Spectra of Hofmann -Td- Type Host Complexes, Commun. Fac. Sci. Univ., Ankara, 37 (1988) 53
  6. H.Yuge and T.Iwamoto,Crystal structures of catena-"diligatocadmium(II)tetra-|I-cyanocadmate(II)"host clathrates: diamminecadmium(II) tetracyanocadmate(II)-benzene (1/2) diamminecadmium (II) tetracyanocadmate (Il)aniline (1/2), ethylenediaminecadmium(II) tetracyanocadmate(II)-aniline( 112), and a novel type bis(aniline)cadmium(II) tetracyanocadmate(II)- aniline(2/l),J. Inclusion Phenom.Mol.Recognit.chem.,14 (1992) 217-235
  7. Z.Kantarcı,N.Karacan,B.Davarcıoğlu., Infrared Spectroscopic Studies On The Hofmann-Td-Type Complexes.,J.of MoLStroct.,323(1994)53-58
  8. A.J. Carty,Proton Magnetic Rezonans and Infrared Spectra of Some Complexes of N,N Dimethylacetamide, C. Journal of Chem., (1966) 44, 16
  9. E.Kasap and Z.Kantarci,Vibrational Spectroscopic Studies on the en-Td- Type Benzene Clathrates: M(ethylenediamine)M' (CN) 4.2C6H6 (M=Mn or Cd,M'=Cd or Hg)., J. Inclusion Phenom.Mol. Recognit. chem., 23(1995) 1-9
  10. L.H. Jones,Vibrational spectrum and structureof metal cyanide complexes in the solid state. V.K^Zn(CN)4,K2Cd(CN)4,and K^CNX,., Spectrochim. Acta, 17 (1961) 188
  11. S.Akyiiz, at all,An Infrared and Raman Spectroscopic Study of some Metal Pyridine Tetracyanonickelate Complexes, J. Mol. Struct., 17(1973) 105
  12. M. Senyel, N,N Dimetilformamid Tetrasiyanonikelat Komplekslerinin IR Spektroskopik Bölgesinde İncelenmesi, Anadolu Univ., Fen-Ed. Fak. Dergisi, 3, 1 (1991), 137
  13. R.N. Jones, at all.,The Carbonyl Streching Band in the Spectra of Unsaturated Lactons, Can. J. Chem., 37, (1959), 2007
  14. M.A.J. Jungbauer and C.Curran, N-C=0 Bending Vibration in Complexes of Dimethylformamide with Metal