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Journals / Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi / 2001 / Cilt: 5 - Sayı: 3

FITIR spectroscopic studies on the Hofmann-dahpn-type clathrates: {M(H2N(CH2)7NH2)Ni(CN)4.G(M=Ni. or Cd;G=biphenyl, anthracene or phenanthrene}

Hofmann-dahpn-tipi klatratlar: {M(H2N(CH2)7NH2)Ni(CN)4.G(M=Ni. veya Cd;G=bifenil, antrasen, veya fenantren} için FTIR spektroskopik çalışmaları

Mustafa ŞENYEL
Pages
188–193
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Their structure consists of corrugated pclymeric layers of ${M-Ni(CN)4}infty$ with the 1,7-diaminoheptane bound directly to the metal atom M.

📌 3 Key Takeaways

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Objective & Hypothesis:In this study, Hofmann-diaminoheptane-type clathrates of the form M(l,7-diaminoheptane) Ni(CN)4G (M=Ni, or Cd; G=biphenyl, anthracene, or phenanthrene) have been prepared in powder form and FTIR spectra of the clathrates are reported.
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Key Findings & Data:Their spectral data were compared with those of onding hosts.
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Conclusion & Impact:Their structure consists of corrugated pclymeric layers of ${M-Ni(CN)4}infty$ with the 1,7-diaminoheptane bound directly to the metal atom M.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

In this study, Hofmann-diaminoheptane-type clathrates of the form M(l,7-diaminoheptane) Ni(CN)4G (M=Ni, or Cd; G=biphenyl, anthracene, or phenanthrene) have been prepared in powder form and FTIR spectra of the clathrates are reported. Their spectral data were compared with those of onding hosts. Their structure consists of corrugated pclymeric layers of ${M-Ni(CN)4}infty$ with the 1,7-diaminoheptane bound directly to the metal atom M.

Özet

Bu çalışmada toz halde hazırlanan M(l,7-diaminoheptan)Ni(CN)4GM=Ni veya Cd; G=bifenil , antrasen veya fenantren) klatratlarının FTIR spektrumları incelendi. Klatratlann spektral verileri bu konuk moleküller için mukayese edildiğinde, klatratların yapılarının; M metal atomuna doğrudan bağlı 1,7- diaminoheptan ligandının, sonsuz polimerik ${M-Ni(CN)4}infty$ tabakalarıyla oluşturduğu boşluklardan meydana geldiği saptandı

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Cite This Article

ŞENYEL, M. (2001). FITIR spectroscopic studies on the Hofmann-dahpn-type clathrates: {M(H2N(CH2)7NH2)Ni(CN)4.G(M=Ni. or Cd;G=biphenyl, anthracene or phenanthrene}. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, Cilt: 5 - Sayı: 3, 188–193. https://ajindex.com/articles/310342

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