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Journals / Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi / 2019 / Cilt: 19 - Sayı: 2

Synthesis And Determination of Some Properties of a Methactylate Monomers Having Flour And Ketone

Yan Dalda Flor Ve Keton İçeren Bir Metakrilat Monomerinin Sentezi ve Bazı Özelliklerinin Belirlenmesi

İbrahim EROL
Pages
301–306
Publication Date
2022-10-12
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The copolymer compositions were determined by elemental analysis with nitrogen content.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this work, new type of methacrylate monomers, with fluorine and ketone chain (4-florophenyl)-2- oxo ethyl methactylate (FFMA) were synthesized.
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Key Findings & Data:The free-radical-initiated copolymerization FFMA with acrylonitrile (AN) were carried out in 1,4-dioxane solution at 65 oC using 2,2’-azobisisobutyronitrile (AIBN) as an initiator with different monomer-to-monomer ratios in the feed.
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Conclusion & Impact:The copolymer compositions were determined by elemental analysis with nitrogen content.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

In this work, new type of methacrylate monomers, with fluorine and ketone chain (4-florophenyl)-2- oxo ethyl methactylate (FFMA) were synthesized. The free-radical-initiated copolymerization FFMA with acrylonitrile (AN) were carried out in 1,4-dioxane solution at 65 oC using 2,2’-azobisisobutyronitrile (AIBN) as an initiator with different monomer-to-monomer ratios in the feed. The monomers and copolymers were characterized by FTIR, 1H and 13C-NMR spectral studies. The copolymer compositions were determined by elemental analysis with nitrogen content.

Özet

Bu çalışmanın ilk basamağında, yan dalda flor ve ester grubu içeren bir metakrilat monomeri (4-florofenil)-2- okso etil metakrilat (FFMA) sentezlendi. Daha sonra FFMA monomerin akrilonitril (AN) ilekomopolimeri cam ampullerde, azot atmosferi altında benzoil peroksit(BPO) başlatıcısı ile 1,4-dioksançözücüsünde 65 oC sıcaklıkta sentezlendi. Monomerin ve homopolimerlerin yapıları, IR, 1H-NMR ve 13CNMRteknikleri kullanılarak karakterize edildi. Oluşan kopolimerlerin bileşimleri kopolimer yapısındabulunan azot oranın elementel analizle tayiniyle belirlendi.

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Cite This Article

EROL, İ. (2022). Synthesis And Determination of Some Properties of a Methactylate Monomers Having Flour And Ketone. Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi, Cilt: 19 - Sayı: 2, 301–306. https://ajindex.com/articles/429897

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