Journals / Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi / 2020 / Cilt: 20 - Sayı: 3

Synthesis and Characterization of Novel Fluorescent Cross-Linked Polyphosphazene Microspheres

Yeni Floresans Özellikli Çapraz Bağlı Polifosfazen Mikrokürelerin Sentezi ve Karakterizasyonu

Pages
418–425
Publication Date
2022-10-12
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The obtained results show that the synthesized polyphosphazene microspheres have a high potential for fluorescent sensor, biological catalysis and imaging applications etc.

📌 3 Key Takeaways

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Objective & Hypothesis:Cyclomatrix structured net-poly(cyclotetraphosphazene-co-tyramine) microspheres were synthesized by single step precipitation polymerization.
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Key Findings & Data:Besides, UV and fluorescence properties of microspheres were researched and it was determined that microspheres have been shown maximum absorption at 239 nm.
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Conclusion & Impact:The obtained results show that the synthesized polyphosphazene microspheres have a high potential for fluorescent sensor, biological catalysis and imaging applications etc.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

Cyclomatrix structured net-poly(cyclotetraphosphazene-co-tyramine) microspheres were synthesized by single step precipitation polymerization. The characterization of obtained microspheres were performed by SEM, EDX, FTIR, XRD and DLS techniques. Besides, UV and fluorescence properties of microspheres were researched and it was determined that microspheres have been shown maximum absorption at 239 nm. It was investigated the fluorescence characteristics of tyramine and microspheres as solid state, using 254 nm as the excitation wavelength. The microspheres showed a strong emission peak at 308 nm, whereas the emission peak of the tyramine was very weak. The obtained results show that the synthesized polyphosphazene microspheres have a high potential for fluorescent sensor, biological catalysis and imaging applications etc.

Özet

Siklomatriks yapılı net-poli(siklotetrafosfazen-ko-tiramin) mikroküreler çöktürme polimerizasyonu iletek adımda sentezlenmiştir. Elde dilen mikrokürelerin karakterizasyonu SEM, EDX, FTIR, XRD ve DLSteknikleri ile yapılmıştır. Ayrıca mikrokürelerin UV ve floresans özellikleri de incelenmiş olup,mikrokürelerin 239 nm’de maksimum absorbans yaptığı belirlenmiştir. Tiramin ve mikrokürelerin katıhal floresans özellikleri, 254 nm dalga boyunda uyarılarak incelenmiştir. Tiramin çok zayıf emisyonyaparken, mikroküreler 308 nm’de şiddetli emisyon göstermiştir. Elde edilen sonuçlar, sentezlenenpolifosfazen mikrokürelerin sensör, biyolojik kataliz ve görüntüleme gibi floresans uygulamalar içinyüksek potansiyele sahip olduğunu göstermektedir.

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Cite This Article

ÖRÜM, S. M. (2022). Synthesis and Characterization of Novel Fluorescent Cross-Linked Polyphosphazene Microspheres. Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi, Cilt: 20 - Sayı: 3, 418–425. https://ajindex.com/articles/429814

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References (7)

  1. Abbas, Y., Zuhra, Z., Basharat, M., Qiu, M., Wu, Z., Wu, D. and Ali, S., 2019. Morphology control of novel crosslinked ferrocenedimethanol derivative cyclophosphazenes: from microspheres to nanotubes and their enhanced physicochemical performances. The Journal of Pysical Chemistry B., 123, 4148−4156. Basharat, M., Liu, W., Zhang, S., Abbas, Y., Wu, Z. and Wu, D., 2019. Poly(cyclotriphosphazene-co-tris(4- hydroxyphenyl)ethane) microspheres with intrinsic excitation wavelength tunable multicolor photoluminescence. Macromolecular Chemistry and Physics, 220, 1900256-1900264.
  2. Berberoğlu, İ., Asmafiliz, N., Kılıç, Z., Hökelek, T., Koç, L. Y., Açık, L., Türk, M., Soltanzade, H. and Dal, H., 2016. Phosphorus nitrogen compounds: Part 34. Syntheses, structural investigations, cytotoxic and biological activities of spiro-ansa-spiro and spiro-bino-spiro tetrameric phosphazene derivatives. Inorganica Chimica Acta, 446, 75-86.
  3. Bi, B., Liu, H., Kang, W., Zhuo, R. and Jiang, X., 2019. An injectable enzymatically crosslinked tyraminemodified carboxymethyl chitin hydrogel for biomedical applications. Colloids and Surfaces B: Biointerfaces, 175, 614–624.
  4. Chen, K., Liu, Y., Hu, Y., Yuan, M., Zheng, X., Huang, X., 2020. Facile synthesis of amino-functionalized polyphosphazene microspheres and their application for highly sensitive fluorescence detection of Fe3+. Journal of Applied Polymer Science, 137, 48937- 48945. Elmas, G., Okumuş, A., Cemaloğlu, R., Kılıç, Z., Çelik, S. P., Açık, L., Tunalı, B. Ç., Türk, M., Çerçi, N. A., Güzel, R. and Hökelek, T., 2017. Phosphorus-nitrogen compounds. part 38. Syntheses, characterizations, cytotoxic, antituberculosis and antimicrobial activities and DNA interactions of spirocyclotetraphosphazenes with bis-ferrocenyl pendant arms. Journal of Organometallic Chemistry, 853, 93-106.
  5. Fu, J., Wang, M., Zhang, C., Zhang, P. and Xu, Q., 2012. High hydrogen storage capacity of heteroatomcontaining porous carbon nanospheres produced from cross-linked polyphosphazene nanospheres. Materials Letters, 81, 215–218.
  6. Fu, J., Wang, S., Zhu, J., Wang, K., Gao, M., Wang, X. and Xu, Q., 2018. Au-Ag bimetallic nanoparticles decorated multi-amino cyclophosphazene hybrid microspheres as enhanced activity catalysts for the reduction of 4-nitrophenol. Materials Chemistry and Physics, 207, 315-324.
  7. Hong, S., Li, J., Huang, X. and Liu, H., 2018. A facile approach to generate cross-linked poly (cyclotriphosphazeneco-oxyresveratrol) nanoparticle with intrinsically flu