Journals / Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi / 2021 / Cilt: 21 - Sayı: 1

Investigation of the Effects of Molybdenum Oxide, Pluronic®F127 and Mushroom on Capacitive Properties of Lithium tetraborate/ITO Electrodes

Molibden Oksit, Pluronic®F127 ve Mantarın Lityum tetraborat/ITO Elektrotların Kapasitif Özelliklerine Etkilerinin İncelenmesi

Pages
196–208
Publication Date
2022-10-12
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

It has been shown that the developed mushroom-carbon-based anode technology can replace graphite anodes by optimizing GMO, conductive polymer, and mushroom doping.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Nowadays, alternative energy production processes, efficient storage of generated energy, and the production of energy resources from environmentally friendly materials are important research topics.
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Key Findings & Data:While preparing the electrode, lithium tetraborate (LTB) was preferred as the doping salt.
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Conclusion & Impact:It has been shown that the developed mushroom-carbon-based anode technology can replace graphite anodes by optimizing GMO, conductive polymer, and mushroom doping.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

Nowadays, alternative energy production processes, efficient storage of generated energy, and the production of energy resources from environmentally friendly materials are important research topics. For this purpose, conductive polymers, biomass additives such as mushroom and transition metal oxides (GMO) as electrode materials were investigated electrochemically towards supercapacitors used in energy storage. While preparing the electrode, lithium tetraborate (LTB) was preferred as the doping salt. Electrodes were prepared by adding molybdenum oxide (MoO3), Pluronic®F127, and mushroom to LTB, respectively. The electrochemical properties of the prepared electrodes were investigated considering the current density variation in the applied potential range, and the findings obtained showed that LTB-MoO3-F127-Mushroom/ITO electrode increased capacitive effect approximately 3.5 times compared to LTB/ITO electrode, and electrode cycle life was preserved at 86% (anodic) and 87% (cathodic) rates after 20 cycles. In electrochemical studies, it has been shown that the capacitive effect of LTB-MoO3-F127-Mushroom/ITO electrode is increased approximately 3.5 times compared to LTB/ITO electrode and that the electrode cycle life is preserved at 86% (anodic) and 87% (cathodic) rates after 20 cycles. In this study, a low cost, high performance, and environmentally friendly alternative technology is presented for super capacitor applications. It has been shown that the developed mushroom-carbon-based anode technology can replace graphite anodes by optimizing GMO, conductive polymer, and mushroom doping.

Özet

Günümüzde alternatif enerji üretim süreçleri, üretilen enerjinin verimli bir şekilde depolanması ve enerjikaynaklarının çevre dostu malzemelerden üretilmesi önemli araştırma konularıdır. Bu amaçla enerjidepolamada kullanılacak süper kapasitörlerde elektrot materyali olarak iletken polimerler, grafitealternatif mantar gibi biyokütle katkıları ve geçiş metal oksitleri (GMO) elektrokimyasal olarakaraştırılmıştır. Elektrot hazırlarken lityum tetraborat (LTB) doping tuzu olarak tercih edilmiştir. LTB’yesırasıyla molibden oksit (MoO3), Pluronic®F127 ve mantar katkılanarak elektrotlar hazırlanmıştır.Hazırlanan elektrotların elektrokimyasal özellikleri uygulanan potansiyel aralığındaki akım yoğunluğudeğişimi dikkate alınarak araştırılmış ve elde edilen bulgular LTB-MoO3-F127-Mantar/ITO elektrotundaha iyi elektrokimyasal enerji depolama kapasitesine sahip olduğunu göstermiştir. Elektrokimyasalçalışmalarda LTB-MoO3-F127-Mantar/ITO elektrotta LTB/ITO elektrota kıyasla yaklaşık 3,5 kat kapasitifetkinin artırıldığı ve elektrot çevrim ömrünün 20 çevrim sonrası %86 (anodik) ve %87 (katodik)oranlarında korunduğu gösterilmiştir. Bu çalışma ile süper kapasitör uygulamaları için uygun maliyetli,yüksek performanslı ve çevre dostu teknoloji olarak grafite alternatif önerilen mantar-karbon tabanlıanot teknolojisi geliştirmek amacıyla GMO, iletken polimer ve mantar katkılamasının optimize edilerekgrafit anotların yerini alabileceği önerilmiştir.

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Cite This Article

AYHAN, M. E., GÜR, B. (2022). Investigation of the Effects of Molybdenum Oxide, Pluronic®F127 and Mushroom on Capacitive Properties of Lithium tetraborate/ITO Electrodes. Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi, Cilt: 21 - Sayı: 1, 196–208. https://ajindex.com/articles/429637

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References (10)

  1. Abdel-Khalek, E. K., Elsharkawy, M. A., Motawea, M. A., Elesh, E., & Farag, A. T. M., 2020. Dielectric and Thermal Properties of Tetragonal PbTiO3 Nanoparticles/Clusters Embedded in Lithium Tetraborate Glass Matrix. Silicon, 1-10.
  2. Abouelamaiem, D. I., Mostazo-López, M. J., He, G., Patel, D., Neville, T. P., Parkin, I. P., Lozano-Castelló, D., Morallón, E., Cazorla-Amorós, D., and Jorge, A.B.,. & Brett, D. J., 2018. New insights into the electrochemical behaviour of porous carbon electrodes for supercapacitors. Journal of Energy Storage, 19, 337-347.
  3. Boota, M., Pasini, M., Galeotti, F., Porzio, W., Zhao, M.Q., Halim, J. and Gogotsi, Y, 2017. Interaction of Polar and Nonpolar Polyfluorenes with Layers of TwoDimensional Titanium Carbide (MXene): Intercalation and Pseudocapacitance. Chemistry of Materials, 29(7), 2731-2738.
  4. Campbell, B., Ionescu, R., Favors, Z., Ozkan, C. S., & Ozkan, M., 2015.
  5. Bio-Derived, Binderless, Hierarchically Porous Carbon Anodes for Li-ion Batteries. Scientific Reports, 5(1), 14575. Elgrishi, N., Rountree, K. J., McCarthy, B. D., Rountree, E. S., Eisenhart, T. T., & Dempsey, J. L., 2018. A Practical Beginner's Guide to Cyclic Voltammetry. Journal of Chemical Education, 95(2), 197-206.
  6. Glushenkov, A. M., Hulicova-Jurcakova, D., Llewellyn, D., Lu, G.Q. and Chen, Y., 2010. Structure and Capacitive Properties of Porous Nanocrystalline VN Prepared by Temperature-Programmed Ammonia Reduction of V2O5. Chemistry of Materials, 22(3), 914-921.
  7. Gür, B., 2020. Determination of the pH-dependent immobilization efficacy of α-glycosidase and its catalytic performance on SnO2:Sb/ITO thin films. Biochemical Engineering Journal, 163, 107758. Gür, B., ve Ayhan, M.E., 2019. Molibden OksitOktadesilamin/Pluronic® F127 Kompozit Elektrotların Kapasitif Özelliklerinin İncelenmesi. Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 9(1), 487-499.
  8. Gür, B. and Meral, K., 2019. Characterization of merocyanine 540-octadecylamine thin films fabricated by Langmuir-Blodgett and Spin-Coating techniques. Journal of Molecular Structure, 1197, 227-234.
  9. Islam, M. M., Bredow, T. and Minot, C., 2006. Ionic Conductivity of Li2B4O7." The Journal of Physical Chemistry B, 110(35), 17518-17523.
  10. Iftikhar, S., Zahid, S., Safi, S. Z., Khan, A. F., Nawshad, M., Ghafoor, S.,. & Shah, A. T., 2020. Smart injectable self-setting bioceramics for dental applications. Materials Science and Engineering: C, 113, 110956. Jayalakshmi, M. and Balasubramanian, K., 2008. Simple Capacitors to