Journals / Turkish Journal of Chemistry / 2004 / Cilt: 28 - Sayı: 1

Acylated Iridoid Glycosides from Verbascum lasianthum

Pages
101–110
Publication Date
2004-01-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Buddlejoside A5 (4) was found for the first time in the genus Verbascum.

📌 3 Key Takeaways

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Objective & Hypothesis:From the roots of Verbascum lasianthum Boiss. ex Bentham 4 catalpol derivatives, 6-O-(a-L-rhamnopyranosyl)-catalpol (1), verbascoside A [= 6-O-(4''-O-trans-p-methoxycinnamoyl)-a -L-rhamnopy- ranosylcatalpol] (2), pulverulentoside I [= 6-O-(3''-O-acetyl-2''-O-trans-p-methoxycinnamoyl)-a -L-rham-nopyranosylcatalpol] (3), and buddlejoside A5 [= 6-O-(2''-O-acetyl-3''-O-trans-p-methoxycinnamoyl)-a -L-rhamnopyranosylcatalpol] (4), as well as aucubin (5) and an aucubin derivative, unduloside III [= 6-O-(3''-O-trans-p-methoxycinnamoyl)- a-L-rhamnopyranosylaucubin] (6), were isolated and characterized.
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Key Findings & Data:The structure elucidation of the compounds was established on the basis of spectroscopic evidence.
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Conclusion & Impact:Buddlejoside A5 (4) was found for the first time in the genus Verbascum.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Verbascum lasianthum Boiss. ex Bentham · Scrophulariaceae · iridoid glycosides

Abstract

From the roots of Verbascum lasianthum Boiss. ex Bentham 4 catalpol derivatives, 6-O-(a-L-rhamnopyranosyl)-catalpol (1), verbascoside A [= 6-O-(4''-O-trans-p-methoxycinnamoyl)-a -L-rhamnopy- ranosylcatalpol] (2), pulverulentoside I [= 6-O-(3''-O-acetyl-2''-O-trans-p-methoxycinnamoyl)-a -L-rham-nopyranosylcatalpol] (3), and buddlejoside A5 [= 6-O-(2''-O-acetyl-3''-O-trans-p-methoxycinnamoyl)-a -L-rhamnopyranosylcatalpol] (4), as well as aucubin (5) and an aucubin derivative, unduloside III [= 6-O-(3''-O-trans-p-methoxycinnamoyl)- a-L-rhamnopyranosylaucubin] (6), were isolated and characterized. The structure elucidation of the compounds was established on the basis of spectroscopic evidence. Buddlejoside A5 (4) was found for the first time in the genus Verbascum.

Özet

From the roots of Verbascum lasianthum Boiss. ex Bentham 4 catalpol derivatives, 6-O-(a-L-rhamnopyranosyl)-catalpol (1), verbascoside A [= 6-O-(4''-O-trans-p-methoxycinnamoyl)-a -L-rhamnopy- ranosylcatalpol] (2), pulverulentoside I [= 6-O-(3''-O-acetyl-2''-O-trans-p-methoxycinnamoyl)-a -L-rham-nopyranosylcatalpol] (3), and buddlejoside A5 [= 6-O-(2''-O-acetyl-3''-O-trans-p-methoxycinnamoyl)-a -L-rhamnopyranosylcatalpol] (4), as well as aucubin (5) and an aucubin derivative, unduloside III [= 6-O-(3''-O-trans-p-methoxycinnamoyl)- a-L-rhamnopyranosylaucubin] (6), were isolated and characterized. The structure elucidation of the compounds was established on the basis of spectroscopic evidence. Buddlejoside A5 (4) was found for the first time in the genus Verbascum.

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Cite This Article

AKDEMİR, Z. Ş., TATLI, İ. İ. (2004). Acylated Iridoid Glycosides from Verbascum lasianthum. Turkish Journal of Chemistry, Cilt: 28 - Sayı: 1, 101–110. https://ajindex.com/articles/382261

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