Journals / Turkish Journal of Physics / 2010 / Cilt: 34 - Sayı: 3

INEPT NMR Spectroscopy of $^ {14}ND _n$ groups: product operator theory and simulation

Pages
139–148
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Also, it is suggested that the INEPT NMR experiment of IS (I =1, S=1) spin system can be used in NMR quantum computing.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Product operator formalism is widely used for the analytical description of multi-dimensional and multiple-pulse NMR experiments for the weakly coupled spin systems having spin-1/2 and spin-1 nuclei.
📊
Key Findings & Data:In this study, the INEPT NMR experiment was analytically investigated by using product operator theory for weakly coupled IS n ($^ {14}ND _n$) (I =1, S =1; n=1, 2, 3) spin systems.
💡
Conclusion & Impact:Also, it is suggested that the INEPT NMR experiment of IS (I =1, S=1) spin system can be used in NMR quantum computing.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Özet

Product operator formalism is widely used for the analytical description of multi-dimensional and multiple-pulse NMR experiments for the weakly coupled spin systems having spin-1/2 and spin-1 nuclei. The INEPT NMR experiment is a polarization transfer experiment including J-coupling. In this study, the INEPT NMR experiment was analytically investigated by using product operator theory for weakly coupled IS n ($^ {14}ND _n$) (I =1, S =1; n=1, 2, 3) spin systems. The obtained theoretical results represent the FID values of $^ {14}ND _n$ groups. In order to make Fourier transform of the obtained FID values, a Maple program is used and then simulated spectra of the INEPT experiment are obtained for $^ {14}ND _n$ groups. Then, the experimental suggestions are made for the INEPT NMR experiment of $^ {14}ND _n$ groups. Also, it is suggested that the INEPT NMR experiment of IS (I =1, S=1) spin system can be used in NMR quantum computing.

🔖

Cite This Article

TÜRKPENÇE, D., ŞAKA, İ., GENÇTEN, A. (2010). INEPT NMR Spectroscopy of $^ {14}ND _n$ groups: product operator theory and simulation. Turkish Journal of Physics, Cilt: 34 - Sayı: 3, 139–148. https://ajindex.com/articles/378595

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (31)

  1. P. Nolis and T. Parella, Curr. Anal. Chem., 3, (2007), 47
  2. J. M. Bulsing and D. M. Doddrell, J. Magn. Reson., 61, (1985), 197
  3. D. M. Doddrell, D. T. Pegg and M. R. Bendall, J. Magn. Reson., 48, (1982), 323
  4. G. A. Morris and R. J. Freeman, Am. Chem. Soc., 101, (1979), 760
  5. J. A. Jones, R. H. Hansen and M. Mosca, J. Magn. Reson., 135, (1998), 353
  6. J. A. Jones, Prog. NMR Spectrosc., 38, (2001), 325
  7. L. K. M. Vandersypen, C. S. Yannoni, I. L. Chuang, in: Encyclopedia of Nuclear Magnetic Resonance, Vol. 9, Advanced in NMR, Eds. D.M. Grant, R.K. Harris, (2002), p. 687
  8. Güleç and S. Bahçeli, Acta Phys. Pol. A, 107, (2005), 983
  9. W. Sφrensen, G. W. Eich, M. H. Levitt, G. Bodenhausen and R. R. Ernst, Prog. NMR Spectrosc., 16, (1983), 163
  10. F. J. M. Van de Ven and C. W. Hilbers, J. Magn. Reson., 54, (1983), 512
  11. K. J. Packer and K. M. Wright, Mol. Phys., 50, (1983), 797
  12. N. Chandrakumar and S. Subramanian, Modern Techniques in High Resolution FT NMR, Springer-Verlag Press, New York, 1987
  13. N. Chandrakumar, J. Magn. Reson., 60, (1984), 28
  14. R. R. Ernst, G. Bodenhausen and A. Wokaum, Principles of Nuclear Magnetic Resonance in One and Two Dimentions, Clarendon Press, Oxford, 1987
  15. A. Gençten and F. Köksal, Spectrosc. Lett., 30, (1997), 71
  16. İ. Şaka, S. Gümüş and A. Gençten, Turk. J. Phys., 31, (2007), 347
  17. N. Chandrakumar, Spin-1 NMR, Springer-Verlag, Berlin, 1996
  18. İ. Şaka and A. Gen¸cten, Z. Naturforsch., 63a, (2008), 339
  19. A. Gençten, Ö. Tezel and A. Köroğlu, Appl. Magn. Reson., 20, (2001), 265
  20. T. T. Nakashima, R. E. D McClung and B. K. John, J. Magn. Reson. 58, (1984), 27
  21. T. Özdoğan, A. Gençten and F. Köksal, Balkan Phys. Lett., 6, (1998), 41
  22. A. Gençten, T. Özdoğan, F. Köksal, Spectrosc. Lett., 31, (1998) 981
  23. A. Tokatlı, A. Gençten, M. S¸ahin, Ö. Tezel and S. Bahçeli, J. Magn. Reson., 169, (2004), 68
  24. N. Chandrakumar, H.-E. Mons, D. H¨uls and H. Günther, Magn. Reson. Chem., 34, (1996), 715
  25. S. Venkata Raman and N. Chandrakumar, Mol. Phys., 90, (1997), 855
  26. A. Gen¸cten and İ. Şaka, Mol.Phys., 104, (2006), 2983
  27. İ. Şaka, S. Gümüş and A. Gen¸cten, Z. Naturforsch., 64a, (2009), 377
  28. İ. Şaka, Braz. J. Phys., 38, (2008), 323
  29. M. J. Duer, Introduction to Solid-State NMR Spectroscopy, Blackwell Publishing Ltd., Oxford, 2004
  30. A. Gençten, Turk. J. Phys., 20, (1996) 146
  31. C. A. Fyfe, K. C. Wong-Moon, Y. Huang and H. Gronday, J. Am. Che