Journals / Çukurova Üniversitesi Mühendislik-Mimarlik Fakültesi Dergisi / 2015 / Cilt: 30 - Sayı: 1

Investigation of Adsorption of Reactive Black 5 Dye onto Activated Carbon by Using Kinetic and Adsorption Models

Reaktif Black 5 Boyar Maddesinin Aktif Karbon Üzerine Adsorpsiyonunun Kinetik ve Adsorpsiyon Modelleri Kullanılarak İncelenmesi

Pages
257–269
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

It was determined that GAC dosage was effective on adsorption kinetic.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study the adsorption of Reactive Black 5 (RB5) dye onto granulated activated carbon (GAC) has been studied in batch experiments. 17 different adsorption isotherms which have two and more than two parameters have been used to explain the adsorption process.
📊
Key Findings & Data:Greater than 0.99 regression coefficients were obtained from Freundlich, Halsey and Henderson isotherms, defining adsorption of heterogeneous surfaces, among two parameters models.
💡
Conclusion & Impact:It was determined that GAC dosage was effective on adsorption kinetic.
🔬Design:Modeling & Simulation
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

In this study the adsorption of Reactive Black 5 (RB5) dye onto granulated activated carbon (GAC) has been studied in batch experiments. 17 different adsorption isotherms which have two and more than two parameters have been used to explain the adsorption process. Greater than 0.99 regression coefficients were obtained from Freundlich, Halsey and Henderson isotherms, defining adsorption of heterogeneous surfaces, among two parameters models. The highest regression coefficient (0,998) was obtained from four parameters Fritz–Schlunder model among all adsorption isotherms. Langmuir isotherm predicted 23.58 mg/g maximum adsorption of GAC. The model that best describes the adsorption kinetics was found as the pseudo second order model. It was determined that GAC dosage was effective on adsorption kinetic.

Özet

Bu çalışmada Reaktif Black 5 (RB5) boyar maddesinin granül aktif karbon (GAK) üzerine kesikli deneyler ile adsorpsiyonu çalışılmıştır. Adsorpsiyon sürecini açıklayabilmek için iki ve ikiden fazla parametreli olmak üzere toplam 17 farklı izoterm modeli kullanılmıştır. İki parametreli modeller arasında 0,99‟dan büyük regresyon katsayıları, heterojen yüzey adsorpsiyon süreçlerinin tanımlanmasında kullanılan Freundlich, Halsey ve Henderson izotermlerinden elde edilmiştir. Tüm adsorpsiyon izotermleri arasında en yüksek regresyon katsayısı (0,998) Fritz-Schlunder modelinden hesaplanmıştır. Langmuir izotermi GAK‟ın maksimum adsorpsiyon kapasitesini 23,58 mg/g olarak tahmin etmiştir. Adsorpsiyon kinetiğini en iyi açıklayan modelin yalancı ikinci derece kinetik eşitliği olduğu bulunmuştur. Adsorpsiyon kinetiği üzerine GAK dozunun etkili olduğu tespit edilmiştir.

🔖

Cite This Article

ERKURT, F. E., BALCI, B. (2015). Investigation of Adsorption of Reactive Black 5 Dye onto Activated Carbon by Using Kinetic and Adsorption Models. Çukurova Üniversitesi Mühendislik-Mimarlik Fakültesi Dergisi, Cilt: 30 - Sayı: 1, 257–269. https://ajindex.com/articles/350322

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (13)

  1. Senthilkumaar S, Kalaamani P, Porkodi K, Varadarajan PR, Subburaam CV. 2006. Adsorption of Dissolved Reactive Red Dye from Aqueous Phase onto Activated Carbon Prepared from Agricultural Waste. Bioresource Technology, 97/14: 1618-25
  2. Ahmad MA, Alrozi R. 2011. Optimization of Rambutan Peel Based Activated Carbon Preparation Conditions for Remazol Brilliant Blue Removal. Chemical Engineering Journal, 168/1: 280-85
  3. Ip AWM, Barford JP, McKay G. 2009. Reactive Black Dye Adsorption/Desorption onto Different Adsorbents: Effect of Salt, Surface Chemistry, Pore Size and Surface Area. Journal of Colloid and Interface Science, 337/1: 32-38
  4. Walker GM, Weatherley LR. 1997. Adsorption of Acid Dyes onto Granular Activated Carbon in Fixed Beds, Water Research, 31/8; 2093- 101
  5. Hameed BH, Mahmoud D.K, Ahmad A.L. 2008. Equilibrium Modeling and Kinetic Studies on the Adsorption of Basic Dye By a Low Cost Adsorbent: Coconut (Cocos Nucifera) Bunch Waste. Journal Hazardous Materials, 158/1: 65-72
  6. Mittal A, Gupta VK, Malviya A., Mittal J2008. Process Development for the Batch and Bulk Removal and Recovery of a Hazardous, Water- Soluble Azo Dye Metanil Yellow by Adsorption Over Waste Materials (bottom ash and de-oiled soya). Journal Hazardous Materials, 151/2-3: 821-32
  7. Allen S.J., Mckay G., Porter J.F., 2004. Adsorption Isotherm Models for Basic Dye Adsorption by Peat in Single and Binary Component Systems. Journal of Colloid and Interface Science, 280( 2): 322 333
  8. Hamdaoui O, Naffrechoux E. 2007. Modeling of Adsorption Isotherms of Phenol and Chlorophenols onto Granular Activated Carbon. Part II. Models with more than Two Parameters. J Hazard Mater. 147(1-2):401-11
  9. Kinniburgh D. G., 1986. General Purpose Adsorption Isotherms, Environ. Sci. Technol., 20 (9), pp 895-904
  10. Aksu, A., Sag, Y., Nourbakhsh, M., Kutsal. T., 1993. Atıksulardaki Bakır, Krom ve Kurşun İyonlarının Çeşitli Mikroorganizmalarla Adsorplanarak Giderilmesinin Karşılaştırmalı Olarak İncelenmesi, Turkish Journal Of Engineering & Environmental Sciences, 19: 285-293
  11. Guptaa Susmita Sen, Krishna G. Bhattacharyya, 2011. Kinetics of Adsorption of Metal Ions on Inorganic Materials: A review. Advances in Colloid and Interface Science. 162(1–2):39-58
  12. Benefield, L. D., Judkins, J. F., Weand, B. L., 1982. Process Chemistry for Water and Wastewater Treatment. Prentice-Hall, Inc, Englewood Cliffs, New Jersey
  13. Chiou, M.-S., Li, H.-Y., 2002. Equilibrium And Kinetic Modeling of Adso