Journals / Hacettepe Journal of Biology and Chemistry / 2018 / Cilt: 46 - Sayı: 2

Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure as Efficient Peroxidase Mimic

Pages
159–167
Publication Date
2018-06-03
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Finally, the M-GO-AgNPs nano-structure obtained by sonochemical technique, a green chemistry synthesis technique, has been found to be suitable for use as an electrochemical sensor matrix.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:I n this work, platinum (Pt), titanium (Ti) and silver (Ag) doped graphene oxide (GO) nanostructures were synthesized by using sonochemical technique, a relatively new technique in nanomaterial synthesis, and characterized in detail.
📊
Key Findings & Data:In addition, a multilayer graphene oxide-silver nanoparticles (M-GOAgNPs) nano-structure was synthesized in this study for the first time, and it’s electrochemical performance was compared with GO-AgNPs.
💡
Conclusion & Impact:Finally, the M-GO-AgNPs nano-structure obtained by sonochemical technique, a green chemistry synthesis technique, has been found to be suitable for use as an electrochemical sensor matrix.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Graphene oxide · silver · platinum

Abstract

I n this work, platinum (Pt), titanium (Ti) and silver (Ag) doped graphene oxide (GO) nanostructures were synthesized by using sonochemical technique, a relatively new technique in nanomaterial synthesis, and characterized in detail. The synthesized nanomaterials were characterized utilizing transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). TEM images and XPS spectras showed that the dopping process was successful. In addition, a multilayer graphene oxide-silver nanoparticles (M-GOAgNPs) nano-structure was synthesized in this study for the first time, and it’s electrochemical performance was compared with GO-AgNPs. As a result of electrochemical study, the rate constants of the GO-AgNPs and M-GO-AgNPs modified electrodes were found as ksanodic= 6.62 s-1 and ksanodic= 6.78 s-1, respectively. Finally, the M-GO-AgNPs nano-structure obtained by sonochemical technique, a green chemistry synthesis technique, has been found to be suitable for use as an electrochemical sensor matrix.

🔖

Cite This Article

DERKUS, B., BOZKURT, P. A. (2018). Multilayer Graphene Oxide-Silver Nanoparticle Nanostructure as Efficient Peroxidase Mimic. Hacettepe Journal of Biology and Chemistry, Cilt: 46 - Sayı: 2, 159–167. https://ajindex.com/articles/255647

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (12)

  1. J. Liu, X. Bo, Z. Zhao, L. Guo, Highly exposed Pt nanoparticles supported on porous graphene for electrochemical detection of hydrogen peroxide in living cells, Biosens. Bioelectron., 74 (2015) 71-77.
  2. Z. Liu, Y. Guo, C. Dong, A high performance nonenzymatic electrochemical glucose sensor based on polyvinylpyrrolidone–graphene nanosheets–nickel nanoparticles–chitosan nanocomposite, Talanta, 137 (2015) 87-93.
  3. G. Giovannetti, P.A. Khomyakov, G. Brocks, V.M. Karpan, J. van den Brink, and P.J. Kelly, Doping Graphene With Metal Contacts, Phys. Rev. Let., 101 (2008) 268031-268034.
  4. B. Uchoa, C.Y. Lin, and A.H. Castro Neto, Tailoring graphene with metals on top, Phys. Rev. B, 77 (2008) 035421-035425.
  5. G.M. Scheuermann, L. Rumi, P. Steurer, W. Bannwarth, R. Mulhaupt, Palladium nanoparticles on graphite oxide and its functionalized graphene derivatives as highly active catalysts for the Suzuki−Miyaura coupling reaction, J. Am. Chem. Soc., 131, 2009, 8262- 8270. Y. Li, L. Tang, J. Li, Preparation and electrochemical performance for methanol oxidation of pt/graphene nanocomposites, Electrochem. Commun., 11 (2009) 846–849.
  6. T. Maiyalagan, X. Dong, P. Chen, X. Wang, Electrodeposited Pt on three-dimensional interconnected graphene as a free-standing electrode for fuel cell application, J. Mater. Chem., 22 (2012) 5286-5290.
  7. K.S. Suslick, Ultrasound: Its chemical, physical and biological effects, VCH Verlagsgesellschaft, Weinheim, Germany, 1988.
  8. B. Neppolian, C. Wang, Muthupandian Ashokkumar. Sonochemically synthesized mono and bimetallic Au– Ag reduced graphene oxide based nanocomposites with enhanced catalytic activity, Ultrason. Sonochem., 21 (2014) 1948-1953.
  9. B. Neppolian, A. Bruno, C.L. Bianchi, M. Ashokkumar, Graphene oxide based Pt–TiO2 photocatalyst: Ultrasound assisted synthesis, characterization and catalytic efficiency, Ultrason. Sonochem., 19 (2012) 9-15.
  10. S. Zhu, J. Guo, J. Dong, Zn Cui, T. Lu, C. Zhu, D. Zhang, J. Ma, Sonochemical fabrication of Fe3O4 nanoparticles on reduced graphene oxide for biosensors, Ultrason. Sonochem., 20 (2013) 872-880.
  11. L. Zhu, J.D. Chung, W.C. Oh, Rapid sonochemical synthesis of novel PbSe–graphene–TiO2 composite sonocatalysts with enhanced on decolorization performance and generation of ROS, Ultrason. Sonochem., 27 (2015) 252-261.
  12. M. Giovanni, H.L. Poh, A. Ambrosi, G. Zhao, Z. Sofer, F. Sanek, B. Khezri, R.D. Webster and M. Pumera, Noble metal (Pd, Ru, Rh, Pt, Au, Ag) doped graphene hybrids for electrocatalysis, Nanoscale, 4 (2012) 500