Journals / Turkish Journal of Chemistry / 2008 / Cilt: 32 - Sayı: 1

Hydrogels of Versatile Size and Architecture for Effective Environmental Applications

Pages
113–123
Publication Date
2008-01-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Hydrogel particle sizes were investigated with microscopic methods, such as optical, fluorescence, scanning electron and transmission electron microcopes.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Cationic hydrogels from a positively charged monomer, (3-Acrylamidopropyl)-trimethylammonium chloride (APTMACl), were synthesized as bulk, and micro- and nano-sizes.
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Key Findings & Data:The micron-sized cationic hydrogel particles were very effective in the removal of arsenic from an aqueous environment- 96% of the arsenic was removed in less than 10 min from a 55-ppm aqueous stock solution.
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Conclusion & Impact:Hydrogel particle sizes were investigated with microscopic methods, such as optical, fluorescence, scanning electron and transmission electron microcopes.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Arsenic removal · environmental hydrogels · microgels

Abstract

Cationic hydrogels from a positively charged monomer, (3-Acrylamidopropyl)-trimethylammonium chloride (APTMACl), were synthesized as bulk, and micro- and nano-sizes. These hydrogels were utilized to remove contaminants such as food dyes and an environmentally toxic metal, arsenic. The micro- and nanohydrogels were dispersed in another hydrogel network to design a semi-interpenetrating network (semi-IPN) which was shown to visualize the particles that can be used for absorption purposes. The micron-sized cationic hydrogel particles were very effective in the removal of arsenic from an aqueous environment- 96% of the arsenic was removed in less than 10 min from a 55-ppm aqueous stock solution. Cationic hydrogels ca. 5 nm were also prepared and demonstrated for fluorescein dye absorption in the nanohydrogel-hydrogel semi-IPN. Hydrogel particle sizes were investigated with microscopic methods, such as optical, fluorescence, scanning electron and transmission electron microcopes.

Özet

Cationic hydrogels from a positively charged monomer, (3-Acrylamidopropyl)-trimethylammonium chloride (APTMACl), were synthesized as bulk, and micro- and nano-sizes. These hydrogels were utilized to remove contaminants such as food dyes and an environmentally toxic metal, arsenic. The micro- and nanohydrogels were dispersed in another hydrogel network to design a semi-interpenetrating network (semi-IPN) which was shown to visualize the particles that can be used for absorption purposes. The micron-sized cationic hydrogel particles were very effective in the removal of arsenic from an aqueous environment- 96% of the arsenic was removed in less than 10 min from a 55-ppm aqueous stock solution. Cationic hydrogels ca. 5 nm were also prepared and demonstrated for fluorescein dye absorption in the nanohydrogel-hydrogel semi-IPN. Hydrogel particle sizes were investigated with microscopic methods, such as optical, fluorescence, scanning electron and transmission electron microcopes.

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Cite This Article

SAHINER, N. (2008). Hydrogels of Versatile Size and Architecture for Effective Environmental Applications. Turkish Journal of Chemistry, Cilt: 32 - Sayı: 1, 113–123. https://ajindex.com/articles/217981

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References (21)

  1. C. M. Hassan, F. J. Doyle III, N. A. Peppas, Macromolecules, 30, 6166-73 (1997)
  2. K. S. An seth, A.T. Metters, S. J. Bryan t, P. J. Marten s, J. H. Elisseeff, C. N. Bowman, J. Control Release,, 199-209 (2002).
  3. H. Feil, Y. H. Bae, J. Feijen, S. W. Kim, J. Memb. Sci., 64, 283-294 (1991).
  4. T. Yoshimi, J. P. Gong, Y. Osada, Prog. Polym. Sci, 30,1-9 (2005).
  5. N. A. Peppas, J. Z. Hilt, A. Khademhosseini, R. Langer, Adv. Mater., 18,1345-60 (2006).
  6. J. T. Trevors, G. H. Pollack, Prog. Biophys. & Mole Bio., 89,1-8 (2005).
  7. J. M. Rosiak, F. Yoshii, Nucl. Ins. & Met. Phys. Res. B, NIM B Beam Inter. Mater. & Atoms, 151, 64 (1999).
  8. J. Zhang, N. A. Peppas, Macromolecules, 33,102-107 (2000).
  9. F. Chiellini, F. Petrucci, E. Ranucci, R. Solaro, J. Appl. Polym. Sci., 85, 2729-41 (2002).
  10. Y. Isikver, D. Saraydin, N. Sahiner, Polym. Bull., 47, 71-79 (2001). E. Rodr´ıguez, I. Katime, J. Appl. Polym Sci., 90, 530-536 (2003). H Ka¸sg¨oz, S. ¨Ozg¨um¨u¸s, M. Orbay, J. Macromol. Sci, Part A: Pure & Appl. Chem., A42, 1287-98 (2005).
  11. S. Tu, Q. L. Ma, E.G. MacDonald, B. Bondada, Environ. & Exp. Botany, 51,121-131 (2004).
  12. M. J. DeMarco, A. K. SenGupta, J. E. Greenleaf, Water Research, 37,164-176 (2003).
  13. E. O. Jr Kartinen, C. J. Martin, Desalination, 103,79-88 (1995).
  14. K. Vaaramaa, J. Lehto, Desalination, 155,157-170 (2003).
  15. M. J. Haron, W. M. Z. Wan Yunus, N. L. Yong, S. Tokunaga, Chemosphere, 39, 2459-2466, (1999).
  16. P.M. Styles, M. Chanda, G. L. Rempel, Reactive & Functional Polymers, 31,89-102, (1996).
  17. P. Bouillot, B. Vincet, Colloid Polym. Sci., 278, 74-79 (2000).
  18. N. Sahiner, M. Singh, Polymer, 48, 2827-34 (2007).
  19. N. Sahiner, W. T. Godbey, G. L. McPherson, V. T. John, Colloid Polym. Sci., 284, 1121-29 (2006).
  20. N. Sahiner, Colloid Polym. Sci., 285, 413-421 (2007).
  21. S. Bang, M. Patel, L. Lippincot, X. Meng, Chemosphere, 60, 389-397 (2005).