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Journals / Turkish Journal of Chemistry / 2015 / Cilt: 39 - Sayı: 6

Cross coupling reactions catalyzed by (NHC)Pd(II) complexes

Nevin GÜRBÜZ
Emine Özge KARACA
İsmail ÖZDEMİR
Bekir ÇETİNKAYA
Pages
1115–1157
Publication Date
2015-12-04
DOI
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The syntheses of the precatalysts and the generally accepted reaction mechanisms are also briefly described.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:This review is focused on new developments reported during the last 3 years concerning the catalytic performances of in situ formed or preformed NHC--Pd(II) complexes (NHC: $N$-heterocyclic carbene) for cross-coupling reactions such as Heck--Mizoraki (often shortened to the Heck reaction), Kumada, Negishi, Suzuki--Miyaura (often shortened to the Suzuki reaction), Sonogashira and Hiyama couplings, and the Buchwald--Hartwig aminations, which are extremely powerful in the formation of C--C and C--heteroatom bonds.
📊
Key Findings & Data:Due to the great number of publications and limited space here, we made a special attempt to compile the relevant data in tables, which we hope will serve as a guide for chemists interested in these reactions.
💡
Conclusion & Impact:The syntheses of the precatalysts and the generally accepted reaction mechanisms are also briefly described.
🔬Design:Review & Systematic Survey
📍Scope:Comprehensive Sample
⚙️Variables:$N$-heterocyclic carbene · palladium · cross-coupling reaction

Abstract

This review is focused on new developments reported during the last 3 years concerning the catalytic performances of in situ formed or preformed NHC--Pd(II) complexes (NHC: $N$-heterocyclic carbene) for cross-coupling reactions such as Heck--Mizoraki (often shortened to the Heck reaction), Kumada, Negishi, Suzuki--Miyaura (often shortened to the Suzuki reaction), Sonogashira and Hiyama couplings, and the Buchwald--Hartwig aminations, which are extremely powerful in the formation of C--C and C--heteroatom bonds. Due to the great number of publications and limited space here, we made a special attempt to compile the relevant data in tables, which we hope will serve as a guide for chemists interested in these reactions. The syntheses of the precatalysts and the generally accepted reaction mechanisms are also briefly described.

Özet

This review is focused on new developments reported during the last 3 years concerning the catalytic performances of in situ formed or preformed NHC--Pd(II) complexes (NHC: $N$-heterocyclic carbene) for cross-coupling reactions such as Heck--Mizoraki (often shortened to the Heck reaction), Kumada, Negishi, Suzuki--Miyaura (often shortened to the Suzuki reaction), Sonogashira and Hiyama couplings, and the Buchwald--Hartwig aminations, which are extremely powerful in the formation of C--C and C--heteroatom bonds. Due to the great number of publications and limited space here, we made a special attempt to compile the relevant data in tables, which we hope will serve as a guide for chemists interested in these reactions. The syntheses of the precatalysts and the generally accepted reaction mechanisms are also briefly described.

🔖

Cite This Article

GÜRBÜZ, N., KARACA, E. Ö., ÖZDEMİR, İ., ÇETİNKAYA, B. (2015). Cross coupling reactions catalyzed by (NHC)Pd(II) complexes. Turkish Journal of Chemistry, Cilt: 39 - Sayı: 6, 1115–1157. https://ajindex.com/articles/184606

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