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Journals / Turkish Journal of Chemistry / 2007 / Cilt: 31 - Sayı: 4

Benzimidazolylidene Carbene Ligated Palladium Catalysis of the Heck Reaction in Aqueous Media

İsmail ÖZDEMİR
Yetkin GÖK
Nevin GÜRBÜZ
Bekir ÇETİNKAYA
Pages
397–402
Publication Date
2007-04-01
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The in situ prepared 3-component system, Pd(OAc)2 / 1,3-dialkylbenzimidazolium chlorides (LHX = 1a-g) and Cs2CO3, catalyzes quantitatively the Heck coupling of aryl bromides under mild conditions in aqueous media.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:A highly effective, easy to handle and environmentally benign process for a palladium mediated Heck reaction was developed.
📊
Key Findings & Data:A highly effective, easy to handle and environmentally benign process for a palladium mediated Heck reaction was developed.
💡
Conclusion & Impact:The in situ prepared 3-component system, Pd(OAc)2 / 1,3-dialkylbenzimidazolium chlorides (LHX = 1a-g) and Cs2CO3, catalyzes quantitatively the Heck coupling of aryl bromides under mild conditions in aqueous media.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Heck coupling · palladium · benzimidazolin-2-ylidene

Abstract

A highly effective, easy to handle and environmentally benign process for a palladium mediated Heck reaction was developed. The in situ prepared 3-component system, Pd(OAc)2 / 1,3-dialkylbenzimidazolium chlorides (LHX = 1a-g) and Cs2CO3, catalyzes quantitatively the Heck coupling of aryl bromides under mild conditions in aqueous media.

Özet

A highly effective, easy to handle and environmentally benign process for a palladium mediated Heck reaction was developed. The in situ prepared 3-component system, Pd(OAc)2 / 1,3-dialkylbenzimidazolium chlorides (LHX = 1a-g) and Cs2CO3, catalyzes quantitatively the Heck coupling of aryl bromides under mild conditions in aqueous media.

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Cite This Article

ÖZDEMİR, İ., GÖK, Y., GÜRBÜZ, N., ÇETİNKAYA, B. (2007). Benzimidazolylidene Carbene Ligated Palladium Catalysis of the Heck Reaction in Aqueous Media. Turkish Journal of Chemistry, Cilt: 31 - Sayı: 4, 397–402. https://ajindex.com/articles/185471

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