Based on the results obtained, it highlights the potential of green-synthesized ZnO@TiO2 nanocomposite as a promising material for analytical applications.
📌 3 Key Takeaways
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Objective & Hypothesis:In this work, we present a facile and efficient approach for the green synthesis of ZnO@TiO2 bimetallic oxide nanoparticles by exploiting the potential of Cinnamomum verum bark extract as a biogenic reducing agent.
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Key Findings & Data:The synthesized nanoparticles were subjected to a comprehensive characterization process comprising various spectroscopic techniques.
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Conclusion & Impact:Based on the results obtained, it highlights the potential of green-synthesized ZnO@TiO2 nanocomposite as a promising material for analytical applications.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Cinnamomum verum · ZnO@TiO2 nanocomposite · ZnO NP
Abstract
In this work, we present a facile and efficient approach for the green synthesis of ZnO@TiO2 bimetallic oxide nanoparticles by exploiting the potential of Cinnamomum verum bark extract as a biogenic reducing agent. The synthesized nanoparticles were subjected to a comprehensive characterization process comprising various spectroscopic techniques. These techniques include X-ray diffraction analysis, Fourier transform infrared spectroscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy. Based on the results obtained, it highlights the potential of green-synthesized ZnO@TiO2 nanocomposite as a promising material for analytical applications.
Keleşoğlu, G. S., Özdinçer, M., Dalmaz, A., Zenkin, K., Durmuş, S. (2023). Green synthesis and structural characterization of ZnO nanoparticle and ZnO@TiO2 nanocomposite by Cinnamomum verum bark extract. Turkish Journal of Analytical Chemistry, Cilt: 5 Sayı: 2, 118–123. https://doi.org/10.51435/turkjac.1395817
1] L. Krishnia, P. Thakur, A. Thakur, Synthesis of nanoparticles by physical route, in synthesis and applications of nanoparticles (1. Edition), 2022, Singapore: Springer Nature.
L. Soltys, O. Olkhovyy, T. Tatarchuk, M. Naushad, Green synthesis of metal and metal oxide nanoparticles: principles of green chemistry and raw materials, Magnetochem, 7, 2021, 145.
M. Jamzad, B. Mokhtari, P.S. Mirkhani, Green synthesis of metal nanoparticles mediated by a versatile medicinal plant extract, Chem Pap, 77, 2022, 1457–1467.
D. Gnanasangeetha, M. Suresh, A review on green synthesis of metal and metal oxide nanoparticles, Nat Environ Pollut Technol, 19, 2020, 1789–1800.
M.P. Nikolova, M.S. Chavali, Metal oxide nanoparticles as biomedical materials, Biomimetics, 5, 2020, 27.
J.J. Xu, W.C. Zhang, Y.W. Guo, X.Y. Chen, Y.N. Zhang, Metal nanoparticles as a promising technology in targeted cancer treatment, Drug Deliv, 29, 2022, 664–678.
P. Prasannalakshmi, N. Shanmugam, Fabrication of TiO2/ZnO nanocomposites for solar energy driven photocatalysis, Mater Sci Semicond Process, 61, 2017, 114–124.
N. Geetha, S. Sivaranjani, A. Ayeshamariam, M. Kavin Micheal, D. Saravankkumar, S. A. Fowziya, A.M Uduman Mohideen, M. Jayachandran, ZnO/TiO2 nanocomposites semiconductor for bacterial applications and dye-sensitized solar cell applications, J Adv Microsc Res,13, 2018, 3–11.
G.K. Upadhyay, J.K. Rajput, T.K. Pathak, V. Kumar, L.P. Purohit, Synthesis of ZnO:TiO2 nanocomposites for photocatalyst application in visible light, Vacuum, 160, 2019, 154–163.
M. Özdinçer, S. Durmuş, Fabrication, characterization and corrosion inhibition properties of SCW-based ZnO nanofluids, Chem Eng Commun, 2023, 1–16.
K. Akshaya, A. Rajasekar, S. Rajeshkumar, Antioxidant activity of zinc oxide nanoparticles synthesized using grape seed extract: An in vitro study, Plant Cell Biotechnol. Mol Biol, 21, 2020, 21– 29.
A. Hassanjani-Roshan, M.R. Vaezi, A. Shokuhfar, Z. Rajabali, Synthesis of iron oxide nanoparticles via sonochemical method and their characterization, Particuology, 9, 2011, 95–99.
M. Darroudi, A. Khorsand Zak, M.R. Muhamad, N.M. Huang, M. Hakimi, Green synthesis of colloidal silver nanoparticles by sonochemical method, Mater Lett, 66, 2012, 117–120.
P.V. Rao, S.H. Gan, Cinnamon: A multifaceted medicinal plant, Evid Based Complement Alternat Med, 2014, 2014.
H.H. Phu, K. Pham Van, T.H. Tran, D.T.N. Pham, Extraction, chemical compositions and biological activities of essential oils of Cinnamomum verum cultivated in Vietnam, Process, 10, 2022, 1713.
M.A. Alghuthaymi, A.M. Diab, A.F. Elzahy, K.E. Mazrou, A.A. Tayel, S.H. Moussa, Green biosynthesized selenium nanoparticles by cinnamon extract and their antimicrobial activity and application as edible coatings with nano-chitosan, J Food Qual, 2021, 2021,1–10.
X. Zhu, K. Pathakoti, H.M. Hwang, Green synthesis of titanium dioxide and zinc oxide nanoparticles and their usage for antimicrobial applications and environmental remediation, Keleşoğlu et al. Turk J Anal Chem, 5(2), 2023, 119–123
H. Özcan, A. Dalmaz, M. Özdinçer, K. Zenkin, S. Durmuş, Biosynthesis and characterization of α-FeOOH nanoparticles using Isabella grape (Vitis labrusca L.) extract, Turk J Anal Chem, 5, 2023, 43–49.
F. Mojarrad, A. Asadi, A. Abdolmaleki, S. Mirzaee, S. Zahri, Preparation of cinnamon-coated cerium oxide nanoparticles and evaluation of their anticonvulsant effect in rats, Pharm Chem J, 57, 2023, 648–655.
A. Sameen, S. Fathima, S. Ramlal, S. Kumar, F. Khanum, Nanopackaging of silver using spice extract and their characterization, Sci Technol Arts Res J, 3, 2014, 52–56.
R. Bekem, S. Durmuş, A. Dalmaz, G. Dülger, Agaricus bisporus Ekstraktı Kullanılarak ZnO Nanopartiküllerinin Yeşil Sentezi: Yapısal Karakterizasyonu ve Biyolojik Aktivitelerinin İncelenmesi, DÜBİTED, 11, 2023, 551–562.
S.N. Gençay, S. Durmuş, A. Dalmaz, G. Dülger, Ticari Bal Kullanılarak ZnO Nanopartiküllerinin Yeşil Sentezi, Yapısal Karakterizasyonu ve Biyolojik Aktivitelerinin İncelenmesi, DÜBİTED, 11, 2023, 1437–1445.
T. Bezrodna, G. Puchkovska, V. Shymanovska, J. Baran, H. Ratajczak, IR-analysis of H-bonded H2O on the pure TiO2 surface, J Mol Struct, 700, 2004, 175–181. [24] F.A. Alharthi, A.A. Alghamdi, N. Al-Zaqri, H.S. Alanazi, A.A. Alsyahi, A.E. Marghany, N. Ahmad, Facile one-pot green synthesis of Ag–ZnO nanocomposites using potato peeland their Ag concentration dependent photocatalytic properties, Sci Rep, 10, 2020, 20229.
S. Kumar, D. Arora, A. Dhupar, V. Sharma, J.K. Sharma, S.K. Sharma, A. Gaur, Structural and optical properties of polycrystalline ZnO nanopowder synthesized by direct precipitation technique, J Nano-Electron Phys, 12, 2020, 04027-1- 04027–5.
R. Nawaz, H. Ullah, A.A.J. Ghanim, M. Irfan, M. Anjum, S. Rahman, S. Ullah, Z.A. Baki, V. Kumar Oad, Green synthesis of ZnO and black TiO2 materials and their application in photodegradation of organic pollutants, ACS Omega, 8, 2023, 36076–36087.
D. Negrea, E. David, V. Malinovschi, S. Moga, C. Ducu, X-ray analysis of spent catalysts and recovered metals, Environ Eng Manag J, 9, 2010, 1235–1241.
D. Ramírez-Ortega, A.M. Meléndez, P. Acevedo-Peña, I. González, R. Arroyo, Semiconducting properties of ZnO/TiO2 composites by electrochemical measurements and their relationship with photocatalytic activity, Electrochim Acta, 140, 2014, 541–549.
A. Hossain, Y. Abdallah, M.A. Ali, M.M.I. Masum, B. Li, G. Sun, Y. Meng, Y. Weng, Q. An, Lemon-fruit-based green synthesis of zinc oxide nanoparticles and titanium dioxide nanoparticles against soft rot bacterial pathogen Dickeya dadantii, Biomol, 9, 2019, 863.
M. Zamani, M. Rostami, M. Aghajanzadeh, H. Kheiri Manjili, K. Rostamizadeh, H. Danafar, Mesoporous titanium dioxide@zinc oxide–graphene oxide nanocarriers for colon-specific drug delivery, J Mater Sci, 53, 2018, 1634–1645.