SavedAdd your journal

Journals / Kırklareli Üniversitesi Mühendislik ve Fen Bilimleri Dergisi / 2023 / Cilt: 9 Sayı: 2

Determination and Speciation of Cd(II) and Pb(II) Ions Using Magnetic Solid Phase Extraction By Flame Atomic Absorption Spectroscopy

Alevli Atomik Absorpsiyon Spektroskopisi ile Manyetik Katı Faz Ekstraksiyonu Kullanılarak Cd(II) ve Pb(II) İyonlarının Tayini ve Türlendirilmesi

Nurdan Kurnaz Yetim(KIRKLARELİ ÜNİVERSİTESİ)0000-0001-6227-0346
Elvan Hasanoğlu Özkan(GAZİ ÜNİVERSİTESİ)0000-0001-7338-4015
Nihat Akkurt(Kırklareli Üniversitesi)0000-0002-0781-7983
Cemile Özcan(KIRKLARELİ ÜNİVERSİTESİ)0000-0002-2954-0612
Pages
381–396
Publication Date
2023-12-31
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The novel material of Fe3O4@G2/Npht magnetic dendrimer for separation and pre-concentration of Pb(II) and Cd(II) was used to natural water.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, Pb(II) and Cd(II) ions were determined by Fe3O4@G2/Npht magnetic dendrimers using the solid-phase extraction (SPE) method by flame atomic absorption spectrophotometer (FAAS).
📊
Key Findings & Data:Optimum conditions for heavy metal recovery using Fe3O4@G2/Npht magnetic dendrimer were determined as pH 6.5, 1M HNO3 and 100 mg for Pb(II) and pH 7.5, 1 M HNO3 and 100 mg for Cd(II).
💡
Conclusion & Impact:The novel material of Fe3O4@G2/Npht magnetic dendrimer for separation and pre-concentration of Pb(II) and Cd(II) was used to natural water.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Manyetik dendrimerler · SPE · AAS

Abstract

In this study, Pb(II) and Cd(II) ions were determined by Fe3O4@G2/Npht magnetic dendrimers using the solid-phase extraction (SPE) method by flame atomic absorption spectrophotometer (FAAS). The morphological and chemical properties of magnetic dendrimers were investigated using Fourier Transform Infrared (FTIR) spectroscopy and transmission electron microscopy (TEM) techniques. The magnetic characteristics of the ferromagnetic features of the magnetic nanocomposites were validated by vibrating sample magnetometry (VSM). The heavy metal ion recovery was assessed via flame atomic adsorption spectroscopy (FAAS). To ascertain the ideal adsorption system conditions, the effects of various parameters, including pH, adsorbent dose, adsorbent time, eluent type and amount, etc., were examined. Optimum conditions for heavy metal recovery using Fe3O4@G2/Npht magnetic dendrimer were determined as pH 6.5, 1M HNO3 and 100 mg for Pb(II) and pH 7.5, 1 M HNO3 and 100 mg for Cd(II). The novel material of Fe3O4@G2/Npht magnetic dendrimer for separation and pre-concentration of Pb(II) and Cd(II) was used to natural water.

Özet

Bu çalışmada, Pb(II) ve Cd(II) iyonları Fe3O4@G2/Npht manyetik dendrimerler ile katı faz ekstraksiyon (SPE) yöntemi kullanılarak alevli atomik absorpsiyon spektrofotometresi (AAS) ile tayin edilmiştir. Manyetik dendrimerlerin morfolojik ve kimyasal özellikleri Fourier Transform Infrared (FTIR) spektroskopisi ve transmisyon elektron mikroskobu (TEM) teknikleri kullanılarak incelenmiştir. Manyetik nanokompozitlerin ferromanyetik özelliklerinin manyetik karakteristikleri titreşimli numune manyetometrisi (VSM) ile doğrulanmıştır. Ağır metal iyonlarının geri kazanımı alevli atomik adsorpsiyon spektroskopisi (AAS) ile değerlendirilmiştir. İdeal adsorpsiyon sistemi koşullarını belirlemek için pH, adsorban dozu, adsorban süresi, eluent türü ve miktarı gibi çeşitli parametrelerin etkileri incelenmiştir. Fe3O4@G2/Npht manyetik dendrimer kullanılarak ağır metal geri kazanımı için optimum koşullar Pb(II) için pH 6,5, 1M HNO3 ve 100 mg, Cd(II) için pH 6,5, 1 M HNO3 ve 100 mg olarak belirlenmiştir. Pb(II) ve Cd(II)'nin ayrılması ve ön konsantrasyonu için Fe3O4@G2/Npht manyetik dendrimerden oluşan yeni malzeme doğal suda kullanılmıştır

🔖

Cite This Article

Yetim, N. K., Özkan, E. H., Akkurt, N., Özcan, C. (2023). Determination and Speciation of Cd(II) and Pb(II) Ions Using Magnetic Solid Phase Extraction By Flame Atomic Absorption Spectroscopy. Kırklareli Üniversitesi Mühendislik ve Fen Bilimleri Dergisi, Cilt: 9 Sayı: 2, 381–396. https://doi.org/10.34186/klujes.1380247

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (35)

  1. A. Soegianto, H.I. Wahyuni, B. Yulianto, and L.A. Manaf, “Health risk assessment of metals in mud crab (Scylla serrata) from the East Java Estuaries of Indonesia,” Environ Toxicol Pharmacol., vol. 90, pp. 103810, Feb. 2022. doi: 10.1016/j.etap.2022.103810.
  2. F. Nikfar, S. Sabzalipour, A. Gholami, and A. Nazarpour, “Carcinogenic risk assessment, health endpoint and source identification of heavy metals in Mahshahr, Iran,” Toxin Reviews, vol. 42:1, pp. 132-145, 2023. doi: 10.1080/15569543.2021.2023576
  3. I. Gul, M. Manzoor, N. Hashim, G. M. Shah, S. P. Tariq Waani, M. Shahid, V. Antoniadis, J. Rinklebe, and M. Arshad, “Challenges in microbially and chelate-assisted phytoextraction of cadmium and lead - A review,” Environ Pollut., vol. 287, pp.117667, Oct. 2021. doi: 10.1016/j.envpol.2021.117667.
  4. N. Alahmadi, “Recent progress in photocatalytic removalof environmental pollution hazards in water using nanostructured materials,” Separations., vol. 9, pp. 264, 2022. https://doi.org/10.3390/separations9100264
  5. A.Widyantoro, F. Binazir Maziya, and A. Umar Abidin, “Exposure analysis of lead (Pb) and chromium (Cr) in workplaceworkshop PT. X,” Gac Sanit. vol. 35(S2), pp. S450-S454, 2021. https://doi.org/10.1016/j.gaceta.2021.07.023
  6. R. Jagadeep, R.V. Vignesh, P. Sumanth, V. Sarathi, and M. Govindaraju, “Fabrication of fly-ash based tiles using liquid phase sintering technology,” Materials Today-Proceedings., vol. 46, pp.7224-7229, Sep. 2021. DOI10.1016/j.matpr.2020.12.348
  7. A. A. Gouda, and W. A. Zordok, “Solid-phase extraction method for preconcentration of cadmium and lead in environmental samples using multiwalled carbon nanotubes,” Turk J Chem., vol. 42, pp. 1018-1031, 2018. doi:10.3906/kim-1711-90
  8. O. Acar, “Evaluation of cadmium, lead, copper, iron and zinc in Turkish dietary vegetable oils and olives using electrothermal and flame atomic absorption spectrometry,” Grasas Y Aceites., vol. 63:4, pp. 383-393, Oct.-Dec. 2012. doi10.3989/gya.047512
  9. E. A. Berberoğlu, E. Hasanoğlu Özkan, N. Kurnaz Yetim, C. Özcan, “Utilizing NiO nanoflowers for lead measurement in real samples,” Journal of Materials and Electronic Devices, vol. 3, pp. 13-18, 2023.
  10. M. Khan, R. Alosmanov, K. Wolski, S. Zapotoczny, and M. Soylak, “Magnetic adsorbent decorated with poly(n-isopropylacrylamide) (pnipam) brushes for the vortex-assisted solid phase extraction (vaspe) of lead in water, cigarettes and soil with high-resolution continuum source flame atomic absorption spectrometry (Hr-Cs FAAS)
  11. Ş. Korkmaz, N. Kurnaz Yetim, E. Hasanoğlu Özkan, and C. Özcan, “Magnetic solid phase extraction of Co3O4@Fe3O4 nanoflowers for the enrichment of Cr6+ ions,” Current Topics in Analytical Chem., Dec. 2023.
  12. D.N. Karaman, H. Serbest, Y. Kilinç, R. Demirel, and S. Bakirdere, “Trace cadmium determination in lake water matrix by flame atomic absorption spectrometry after manganese ferrite magnetic nanoparticles-based dispersive solid phase extraction,” Clean-Soil Air Water.,vol. 5:9, July 2023. DOI10.1002/clen.202200186
  13. R.O.Hassan, H.O. Othman, D.S. Ali, F. O. Abdullah, and D. A. Darwesh, “Assessment of the health risk posed by toxic metals in commonly consumed legume brands in Erbil, Iraq,” Journal of Food Composition and Analysis., vol. 120, pp. 105282, July 2023. https://doi.org/10.1016/j.jfca.2023.105282
  14. HJ. Li, S. Ding, and J. Yuan, “Extraction of humic acids from lignite and its use as a biochar activator,” ACS Omega., vol. 8:13, pp. 12206-12216, Apr. 2023. DOI10.1021/acsomega.2c08192
  15. L. M. Costa, F. A. Borges, M.H.D. Cavalcanti, A.C. do Lago, C.R.T. Tarley, G.D.L. Martins, and E. C. Figueiredo, “Direct magnetic sorbent sampling flame atomic absorption spectrometry (DMSS-FAAS) for highly sensitive determination of trace metals,” Analytica Chimica Acta.,vol. 1251, pp. 340709, Apr. 2023. DOI10.1016/j.aca.2022.340709
  16. P. Punia, M. K. Bharti, R. Dhar, P. Thakur, and A. Thakur, “Recent advances in detection and removal of heavy metals from contaminated water,” Chembioeng Reviews., vol. 9:4, pp. 351-369, Aug 2022. doi10.1002/cben.202100053
  17. D. D. Mai, T. H. Bui, V. H. Pham, T. H. Bui, T. K. Pham, D. C. Nguyen, and T. L. Nguyen, “Simultaneous adsorption of heavy metals on mesoporous reduced graphene oxide/γ-Fe2O3 nanocomposites,” Journal of porous materials., vol. 29:6, pp. 1947-1956, Dec. 2022. doi10.1007/s10934-022-01306-1
  18. C.Y. Suo, D. D. Xu, R.F. Yuan, and B. H. Zhou, “Synchronous removal of Cd(II), Pb(II), and Cu(II) by coagulation in the presence of polymeric ferric sulfate,” Desalination and Water Treat., vol. 195, pp. 421-434, Aug. 2020. doi10.5004/dwt.2020.25928
  19. G.S.S. Sunder, S. Adhikari, A. Rohanifar, A. Poudel, and J.R. Kirchhoff, “Evolution of environmentally friendly strategies for metal extraction,” Separations., vol. 7:1, Apr. 2020. DOI10.3390/separations7010004
  20. M.W. Alam, M. M. Rahman, M. S. Bhuyan, V. Senapathi, S. Y. Chung, S. Karthikeyan, S. Sekar, H. E. Elzain, and A. A. Nadiri, “Inferences on metal pollution in the natural spawning zone of Bangladesh river and pollution management strategies,” Environmental Monitoring and Assessment., vol. 195:1, pp.56, Jan 2023. doi10.1007/s10661-022-10544-4
  21. A. A. Gouda, R. El Sheikh, A. O. Youssef, N. Gouda,W. Gamil, and H.A. Khadrajy, “Preconcentration and separation of Cd(II), Co(II), Cu(II), Ni(II), and Pb(II) in environmental samples on cellulose nitrate membrane filter prior to their flame atomic absorption spectroscopy determinations,” International Journal of Environmental Analytical Chemistry, vol. 103:2, pp. 364-377, Dec. 2020. doi10.1080/03067319.2020.1858070
  22. D. G. Kim, R.J.S. Palacios, and S.O. Ko, “Characterization of sludge generated by electrocoagulation for the removal of heavy metals,” Desalination and Water Treatment., vol. 52: 4-6, pp. 909-919, May 2014. doi10.1080/19443994.2013.826776
  23. M. Soylak, H. E. Hassan Ahmed, and A. N. Coban, “Micro-solid phase extraction of cobalt at trace levels as 1-nitroso-2-naphthol chelates on magnetic date palm fiber-WSe2 (mDPF@WSe2) nanocomposite from food, tobacco, and water samples,” Journal of Food Composition and Analysis., vol. 125, pp.105716, Jan. 2024. https://doi.org/10.1016/j.jfca.2023.105716
  24. O.C. Bodur, E. Hasanoğlu Özkan, O. Çolak, H. Arslan, N. Sarı, A. Dişli, and F. Arslan, “Preparation of acetylcholine biosensor for the diagnosis of Alzheimer's disease,” J. Mol. Struc., vol. 1223:129168, Jan. 2021. https://doi.org/10.1016/j.molstruc.2020.129168.
  25. F. Arslan, H. Koçak, O. C. Bodur, E. Hasanoğlu Özkan, B. Arslan, and N. Sarı, “Novel tyrosinase-based bisphenol-A biosensor for the determination of bisphenol-A in bracket adhesive in orthodontics,” Macedonian Journal of Chemistry and Chemical Eng., vol. 41:2, Dec. 2022. https://dx.doi.org/10.20450/mjcce.2022.2585
  26. N. Kurnaz Yetim, E. Hasanoğlu Özkan, and M.M. Koç, “Evaluation of dye removal performance of magnetic dendrimers with immobilized HRP enzyme,” Jmed., vol. 3:1, pp. 6-12. Aug. 2023.
  27. E. Hasanoğlu Özkan, and N. Sarı, “Use of immobilized novel dendritic molecules as a marker for the detection of Glucose in artificial urine,” Journal of Mol. Struct.,vol. 1201: 127134. Feb. 2020. https://doi.org/10.1016/j.molstruc.2019.127134.
  28. N. Kurnaz Yetim, and N. Sarı, “Preparation of ferrocene core dendrimers and immobilization of AChE for detection of diclofop-methyl herbicide,” Maced. J. Chem. Chem. Eng.vol. 38:2, pp. 215-225, 2019. https://doi.org/10.20450/mjcce.2019.1878
  29. N. Kurnaz Yetim, M.M. Koç, and D. Nartop, “Magnetic dendrimer-encapsulated metal nanoparticles (Au, Ag): effect of dendrimerization on catalytic reduction of 4-nitrophenol,” J Iran Chem Soc., vol. 19, pp. 2569-2580, 2022. https://doi.org/10.1007/s13738-021-02476-6
  30. N. Kurnaz Yetim, F. Kurşun Baysak, M. M. Koç, and D. Nartop, “Synthesis and characterization of Au and Bi2O3 decorated Fe3O4@PAMAM dendrimer nanocomposites for medical applications,” J. Nanostructure Chem., vol. 11, pp. 589-599, Feb. 2021. https://doi.org/10.1007/s40097-021-00386-w
  31. N. Kurnaz Yetim, E. Hasanoğlu Özkan, N. Akkurt, and M.M. Koç,. “Catalytic performance of Fe3O4@G2-PAMAM/MoO3 magnetic nanocomposites for degradation of 4-NP to 4-AP,” J. mater. electron. device.vol. 3, pp. 1-6, 2022.
  32. N. Kurnaz Yetim, E. Hasanoğlu Özkan, and M.M. Koç, “Investigation of catalytic behaviour of WO3 doped magnetic dendrimers,” Kırklareli University Journal of Engineering and Science., vol. 8:2, pp. 229-242, Dec. 2022. https://doi.org/10.34186/klujes.1187397
  33. E. A. Berberoğlu, M.M. Koç, N. Kurnaz Yetim, and C. Özcan, “Highly efficient ZnO nanoflowers for the removal of highly toxic aqueous Pb(II) and Cr(VI),” J Iran. Chem. Soc., vol. 20, pp. 2821-2830, Aug. 2023. https://doi.org/10.1007/s13738-023-02878-8
  34. E. A. Berberoğlu, M.M. Koç, N. Kurnaz Yetim, and C. Özcan, “Sonochemical removal of highly toxic aqueous Cd2+ and Cr6+ ions using dandelion-like Co3O4 nanoflowers,” Open Journal of Nano., vol. 8:1, pp. 36-49. DOI: 10.56171/ojn.1192105
  35. N. Kurnaz Yetim, and E. Hasanoğlu Özkan, ”Synthesis of Au-doped magnetic nanocomposites: structural, magnetic, and catalytic properties,” J Mater Sci: Mater Electron., vol. 32, pp. 24766-24774, 2021. https://doi.org/10.1007/s10854-021-06922-2