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Journals / Journal of Scientific Reports-A / 2018 / Issue: 041

SYNTHESIS AND CHARACTERIZATION OF PROTON TRANSFER SALT OF PYRIDINE-2,6-DICARBOXYLIC ACID AND ITS Ni(II) AND Cu(II) COMPLEXES

PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU

Nurgün Büyükkıdan0000-0001-6879-9355
Bülent Büyükkıdan0000-0001-9619-3246
Nedime Demir0000-0001-9134-4500
Ceyda Karahan0000-0002-9359-0040
Pages
1–12
Publication Date
2018-12-16
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The structures of the complexes have been suggested according to data obtained from FT-IR, UV-Vis, ICP-OES, magnetic susceptibility and elemental analysis methods. 

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study the proton transfer salt (H 2 Meppz)(Hdipic) 2 ( 1 ) was obtained by the reaction of N -methylpiperazine (Meppz) with pyridine-2,6-dicarboxylic acid (H 2 dipic).
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Key Findings & Data:The metal complexes [Ni(H 2 O) 6 ][Ni(dipic) 2 ].(Meppz).5H 2 O ( 2 ) and (H 2 Meppz)[Cu(dipic) 2 ].2H 2 O ( 3 ) were synthesized by the reaction of proton transfer salt ( 1 ) with Ni(CH 3 COO) 2 .4H 2 O and Cu(CH 3 COO) 2 .2H 2 O.
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Conclusion & Impact:The structures of the complexes have been suggested according to data obtained from FT-IR, UV-Vis, ICP-OES, magnetic susceptibility and elemental analysis methods. 
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Pirazin · piperazin · dikarboksilik asit

Abstract

In this study the proton transfer salt (H 2 Meppz)(Hdipic) 2 ( 1 ) was obtained by the reaction of N -methylpiperazine (Meppz) with pyridine-2,6-dicarboxylic acid (H 2 dipic). The metal complexes [Ni(H 2 O) 6 ][Ni(dipic) 2 ].(Meppz).5H 2 O ( 2 ) and (H 2 Meppz)[Cu(dipic) 2 ].2H 2 O ( 3 ) were synthesized by the reaction of proton transfer salt ( 1 ) with Ni(CH 3 COO) 2 .4H 2 O and Cu(CH 3 COO) 2 .2H 2 O. The structure of proton transfer salt ( 1 )  was characterized by 1 H and 13 C NMR, FT-IR and UV-Vis spectra and elemental analysis techniques. The structures of the complexes have been suggested according to data obtained from FT-IR, UV-Vis, ICP-OES, magnetic susceptibility and elemental analysis methods. 

Özet

Bu çalışmada piridin-2,6-dikarboksilik asitin (H 2 dipic), N -metilpiperazin (Meppz) ile reaksiyonundan proton transfer tuzu (H 2 Meppz)(Hdipic) 2 ( 1 ) elde edilmiştir. Elde edilen proton transfer tuzunun ( 1 ) Ni(CH 3 COO) 2 .4H 2 O ve Cu(CH 3 COO) 2 .H 2 O ile reaksiyonundan ise metal kompleksleri [Ni(H 2 O) 6 ][Ni(dipic) 2 ].(Meppz).5H 2 O ( 2 ) ve (H 2 Meppz)[Cu(dipic) 2 ].2H 2 O ( 3 ) sentezlenmiştir. Proton transfer tuzunun ( 1 ) yapısı FT-IR, 1 H ve 13 C NMR, ve UV-Vis spekroskopileri ve elementel analiz teknikleri ile aydınlatılmıştır. Komplekslerin yapıları ise FT-IR, UV-Vis, ICP-OES, manyetik duyarlılık ve elementel analiz yöntemlerinden elde edilen verilere göre önerilmiştir. 

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Cite This Article

Büyükkıdan, N., Büyükkıdan, B., Demir, N., Karahan, C. (2018). SYNTHESIS AND CHARACTERIZATION OF PROTON TRANSFER SALT OF PYRIDINE-2,6-DICARBOXYLIC ACID AND ITS Ni(II) AND Cu(II) COMPLEXES. Journal of Scientific Reports-A, Issue: 041, 1–12. https://ajindex.com/articles/1512093

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