Journals / ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE / 2018 / Cilt: 6 - Sayı: 1

Elimination of Basic Blue 41 ve Basic Red 46 Dyestuffs from Solution by Anionic Polymer Membrane

Basic Blue 41 ve Basic Red 46 Boyar Maddelerinin Çözeltiden Anyonik Polimer Membran ile Giderilmesi

Pages
17–24
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

According to the adsorption isotherms, the adsorption of both dyestuffs on the polymer membrane were fit to the Freundlich isotherm

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Textile wastewaters in industrial wastewaters are attracting attention because of containing a various chemicals and dyestuffs.
📊
Key Findings & Data:Two different basic dyestuffs (Basic Blue 41-BB41 and Basic Red 46-BR46), which are used to dyeing of acrylic fibers were removed from the solution with a sulfonic acid based polymeric membrane adsorbent at different pH, time, temperature and initial dyestuff concentration with 75% to 100% removal percentage range values in this study.
💡
Conclusion & Impact:According to the adsorption isotherms, the adsorption of both dyestuffs on the polymer membrane were fit to the Freundlich isotherm
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Domain Parameters

Abstract

Textile wastewaters in industrial wastewaters are attracting attention because of containing a various chemicals and dyestuffs. When these dyestuffs are discharge to water resources, rivers and seas, the aquatic life and food chain without any treatment are adversely affected. The treatment of industrial wastewater is vital for all living creatures to minimize these harmful effects. Two different basic dyestuffs (Basic Blue 41-BB41 and Basic Red 46-BR46), which are used to dyeing of acrylic fibers were removed from the solution with a sulfonic acid based polymeric membrane adsorbent at different pH, time, temperature and initial dyestuff concentration with 75% to 100% removal percentage range values in this study. The Gibbs free energy (ΔG) values were found to be -5.2 kJ/mol and -5.52 kJ/mol for the BB41 and BR 46 dyes, respectively, at 318 K. According to the adsorption isotherms, the adsorption of both dyestuffs on the polymer membrane were fit to the Freundlich isotherm

Özet

Endüstriyel atık sular içerisinde tekstil atık suları çok çeşitli kimyasallar ve boyar maddeler içermelerinden dolayı dikkat çekmektedirler. Bu boyar maddeleri su kaynaklarına, ırmaklara ve denizlere arıtılmadan bırakıldıklarında suda yaşayan canlılar ve besin zinciri olumsuz etkilenmektedir. Bu zararlı etkilerin en aza indirilmesi için endüstriyel atık suların arıtılması canlılar için hayati önem taşımaktadır. Bu çalışmada, akrilik elyafların boyanmasında kullanılan iki farklı bazik karakterdeki tekstil boyar maddesi (Basic Blue 41-BB41 and Basic Red 46-BR46) farklı pH, süre, sıcaklık ve başlangıç boyar madde konsantrasyonlarında sülfonik asit esaslı polimerik membran ile çözelti ortamından % 75 ile % 100 aralığında boyar madde giderme yüzdesi ile giderildi. Gibbs serbest enerjisi (ΔG) değerleri BB41 ve BR46 boyar maddeleri için 318 K’de sırası ile -5.2 kj/mol ve -5,52 kj/mol olarak bulundu. Adsorpsiyon izotermleri incelendiğinde her iki boyar maddenin polimer membranına adsorpsiyonunun Freundlich izotermine uyduğu tespit edildi

🔖

Cite This Article

ÖZDOĞAN, R., ÇELEBİ, M. (2018). Elimination of Basic Blue 41 ve Basic Red 46 Dyestuffs from Solution by Anionic Polymer Membrane. ACADEMIC PLATFORM-JOURNAL OF ENGINEERING AND SCIENCE, Cilt: 6 - Sayı: 1, 17–24. https://ajindex.com/articles/141969

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (10)

  1. P. M. Roosta M, Ghaedi M, Daneshfar A, Darafarin S, Sahraei R, “Simultaneous ultrasound-assisted removal of sunset yellow and erythrosine by ZnS:Ni nanoparticles loaded on activated carbon: Optimization by central composite design,” Desalin. Water Treat., vol. 52, no. 2, pp. 193–202, 2014.
  2. S. Song, J. Yao, Z. He, J. Qiu, and J. Chen, “Effect of operational parameters on the decolorization of C.I. Reactive Blue 19 in aqueous solution by ozone-enhanced electrocoagulation,” J. Hazard. Mater., vol. 152, no. 1, pp. 204–210, 2008.
  3. M. Celebi, Tekstil Atık Sularında Boyaların Biyobozunma ile Giderilmesi. 2013. [4] Baser İnci Inanıcı Yusuf, Boyar Madde Kimyası. Teknik Eğitim Fakültesi Marmara Üniversitesi, 1990.
  4. Baser İnci Inanıcı Yusuf, Boyar Madde Kimyası. Teknik Eğitim Fakültesi Marmara Üniversitesi, 1990. Q. Husain, “Potential Applications of the Oxidoreductive Enzymes in the Decolorization and Detoxification of Textile and Other Synthetic Dyes from Polluted Water: A Review,” Crit. Rev. Biotechnol., vol. 26, no. 4, pp. 201–221, 2006.
  5. M. Çelebi, Tekstil Atık Sularında Boyaların Biyobozunma ile Giderilmesi, Kısaltılmış Doktora Tezi. İstanbul Sanayi Odası Yayınları, 2013
  6. M. Celebi, M. Altikatoglu, Z. M. Akdeste, and H. Yildirim, “Determination of decolorization properties of Reactive Blue 19 dye using Horseradish Peroxidase enzyme,” Horseradish Peroksidaz enzimi Kullan. React. Blue 19 boyasi{dotless}ni{dotless}n renk giderilmesinin belirlenmesi, vol. 38, pp. 200–206, 2013
  7. M. Celebi, M. Arif, M. Altikatoglu, and H. Yildirim, “Removal of Cationic Dye from Textile Industry Wastewater with Using Enzyme, Fungus and Polymer,” vol. 3, no. 2, pp. 39–45, 2013. S. H. Lin and C. S. Wang, “Treatment of high-strength phenolic wastewater by a new two-step method,” J. Hazard. Mater., vol. 90, no. 2, pp. 205–216, 2002.
  8. M. Al-Aseeri, Q. Bu-Ali, S. Haji, and N. Al-Bastaki, “Removal of Acid Red and sodium chloride mixtures from aqueous solutions using nanofiltration,” Desalination, vol. 206, no. 1–3, pp. 407–413, 2007
  9. F. Harrelkas, A. Paulo, M. M. Alves, L. El Khadir, O. Zahraa, M. N. Pons, and F. P. van der Zee, “Photocatalytic and combined anaerobic-photocatalytic treatment of textile dyes,” Chemosphere, vol. 72, no. 11, pp. 1816–1822, 2008
  10. C. A. Basha, K. V. Selvakumar, H. J. Prabhu, P. Sivashanmugam, and C. W. Lee, “Degradation studies for textile reactive dye by combined electrochemical, microbial and photocatalytic methods,” Sep. Purif. Technol., vol. 79, no. 3, pp. 303–309,